Human Health Risk Assessment Model of Organic Pollution in Groundwater: Shijiazhuang Industrial Zone

In this study, a risk-based management model is developed and applied to an industrial zone. The models proposed by the United States Environmental Protection Agency and Han Bing have been improved by adding a residual ratio of volatile organic compounds (VOC) after boiling and deleting the related parameters in half-life. Using this improved model, an integrated process was used to assess human health risk level in the study area. Compared with water quality analysis, the results highlight the importance of applying an integrated approach for decision making on risk levels and water protection. The results of this study demonstrated that: (1) Compared with these permissible level standards in China (GB 3838-2002) and National Primary Drinking Water Regulations of the United States, the residents’ daily life had not been affected by the groundwater in this area (except for relative bad water quality of HB3-4 and HB3-6); (2) The typical detected organic contaminants of all groundwater samples were chloroform, carbon tetrachloride, trichloroethylene and tetrachloroethene, and the pollution sources were mainly industrial sources by preliminary investigations; (3) As for groundwater, the non-carcinogenic risk values of all samples do not exceed the permissible level of 1.0 and the carcinogenic risk values are relatively lower than the permissible level of 1.00E-06 to 1.00E-04; (4) Drinking water pathway of trichloroethylene and tetrachloroethylene mainly contribute to increasing the health risk of residents’ in study areas; (5) In terms of non-carcinogenic risk and carcinogenic risk, the health risk order for drinking water pathway and dermal contact pathway was: drinking water pathway > dermal contact pathway.     

2008年夏季白令海和北冰洋异养浮游细菌丰度与分布特征

利用2008年夏季我国第3次北极科学考察资料,基于流式细胞技术,对白令海北部陆架区的微微型浮游植物丰度、细胞大小(碳含量)、色素浓度的分布特征进行了分析,并对该类群的环境适应性进行了研究。结果表明,微微型浮游植物中仅含聚球藻和真核藻,其丰度范围分别为0.14×106 2.69×106和0.23×106-12.49×106个/dm3。聚球藻的叶绿素a和藻红蛋白含量、微微型真核藻的叶绿素a含量与类群丰度以及微微型真核藻的类胡萝卜素含量与细胞大小间均存在同向变化趋势。两类藻偏向于喜温嗜淡型,更适合在寡营养环境中保持较高的丰度,但能在高营养盐浓度下形成相对较高的碳含量。越接近陆地,细胞越小,丰度越大,碳含量及FL2/FL3越低;所处层位越深、纬度越高,则细胞越大,碳含量及FL2/FL3越高。北极气温升高和径流量的增加有利于陆架区微微型浮游植物类群丰度的增加。     

2008年夏季西北冰洋观测区叶绿素a和初级生产力粒级结构

对2008年夏季在西北冰洋172°～143.6°W的楚科奇海及其北部海区对粒度分级叶绿素a和初级生产力现场观测资料,对观测区的空间分布特征进行了研究.结果表明,观测海区表层叶绿素a浓度为0.013～19.367 μg/dm3,平均值为0.677士2.2661 μg/dm3,次表层水叶绿素a浓度高于其它水层.水柱叶绿素a...     

Analysis of characteristics of time-frequency correlations between runoff, tidal range and salinity in the Changjiang Estuary

Power spectrum and cross-wavelet transform analysis was adopted to study the time-frequency characteristics and multiscale correlations between runoff, tidal range and salinity in the Changjiang Estuary based on the runoff data collected at the Datong Station, the tidal range measured at the Baozhen Station, and the salinity at the Baogang Station from 2008 to 2009. The variations of the salinity showed significant periodicity at scales of 2-3, 7-8, 14-15 and 26-30 d. The correlation between the salinity and the runoff and the tidal range were found to be significantly related to shock at scales of 5-7, 14-15, 26-30 d and 0.5 a. The correlation between the runoff and the salinity was mainly in the same phase, while the correlation between the tidal range and the salinity was in the antiphase. Different frequency bands were related to different degrees, and their relevance increased as the resonance frequency decreased. In addition, changes of the seasonal runoff were obvious. Specifically, a point of discontinuity was reached in early June with a cycle of 7-8 d, which coincided with the periodicity of plum rains in the Changjiang-Huaihe region. High-frequency changes (8-16 d period) of the salinity corresponded to the time domain in January-April 2008, February-April 2009 and October-December 2009 and exhibited an approximately 0.5 a (184 d) long frequency oscillation. Short-period changes were found to be stronger than long-period changes. Cross-wavelet transforms for the salinity, the runoff and the tidal range revealed local features in the time domain, while the significant levels of different periodic oscillations were observed in the frequency domain. The correlation characteristics of the salinity and the runoff were significant in the 80-90 d frequency domain, indicating that the major impact of the runoff on the salinity was reflected in seasonal changes. The tidal range on the small scale of 14-15 and 30-32 d was more obvious than the runoff.     

杭州湾及邻近水域营养盐的时空分布与富营养化特征

利用2006年7月-2007年11月杭州湾及邻近水域春、夏、秋、冬四个季节的调查资料,对其营养盐的分布变化及富营养化特征进行了分析.结果表明:杭州湾及邻近水域营养盐的分布变化和富营养化不仅与湾内河流高DIN、磷、硅的输入直接有关,同时受长江冲淡水的影响十分显著.湾内营养盐的分布变化主要受物理混合作用所控制,浮游生物活动...     

长江口及邻近海域表层水体溶解氧饱和度的季节变化和特征

根据“908”ST04区块调查的夏、冬、春、秋季四个航次和“908”补充调查的8月航次资料对长江口及邻近海区表层水体溶解氧及其饱和度进行了探讨.研究表明东海北部表层水体在夏季和春季以浮游植物光合作用为主要控制过程,特别是7、8月份长江口外、杭州湾外及浙江近海存在大范围的强光合作用区;秋季以有机质氧化分解过程为主,表层溶...     

长江口跨越锋面颗粒磷季节分布变化特征及影响因素

根据2006年夏、冬季以及2007年春、秋季“海监49号”科学考察船的调查数据,分析了长江口跨越锋面区域(31.00°～31.78°N、121.04°～123.99°E)颗粒总磷(PP),颗粒无机磷(PIP),颗粒有机磷(POP)的季节变化和空间分布特征.结果表明,PIP是水体颗粒磷的主要存在形式;受长江径流输沙量的影...     

Fe-ZSM-5分子筛催化降解染料废水的研究

传统的Fenton均相亚铁盐催化剂处理染料废水,具有难以避免的二次污染和亚铁离子流失问题。分子筛催化剂相比传统催化剂具有高效环保的特点,在催化氧化染料废水领域有着良好的前景。本文通过液相离子交换法制备了Fe-ZSM-5非均相分子筛催化剂,替代传统的亚铁盐催化剂,应用X射线衍射对制备的Fe-ZSM-5分子筛催化剂进行表征,表明随离子交换次数的增加,Fe-ZSM-5催化剂负载的铁量上升,且较好地保持了分子筛结构,有利于提高亚铁离子的催化能力。通过实验确定了Fe-ZSM-5催化剂催化反应的最佳温度、pH值、Fe-ZSM-5的用量、反应时间等工艺参数,比较了Fe-ZSM-5催化剂和传统Fenton均相催化剂降解染料废水的脱色率和废水中铁离子的残留量,结果表明Fe-ZSM-5的脱色率达到98.5%,相比于Fenton均相催化剂的脱色率提升约3%;两种催化剂的铁离子残留量差别显著,Fe-ZSM-5催化剂处理的废水中只产生微量的Fe离子,可以认为Fe-ZSM-5非均相分子筛催化剂有效地解决了催化剂损耗和二次污染问题。     

一种台风海面非对称风场的构造方法

针对台风数值预报中由于采用对称模型而导致预报误差的现实，通过引入非对称分布的台风最大风速、最大风速半径等因子，在得到台风报告中7级风和10级风的半径的基础上，利用最佳权系数方案来得到非对称的台风外围风速分布因子，从而对Chan and Williams 1987年提出的切向风廓线方案进行改造，进而得到了台风海面非对称风场的计算式。检验表明，该方法能够描述台风海面风场的非对称分布，具有较好的应用前景。