Impact of Gas Adsorption Induced Coal Matrix Damage on the Evolution of Coal Permeability

It has been widely reported that coal permeability can change from reduction to enhancement due to gas adsorption even under the constant effective stress condition, which is apparently inconsistent with the classic theoretical solutions. This study addresses this inconsistency through explicit simulations of the dynamic interactions between coal matrix swelling/shrinking induced damage and fracture aperture alteration, and translations of these interactions to permeability evolution under the constant effective stress condition. We develop a coupled coal–gas interaction model that incorporates the material heterogeneity and damage evolution of coal, which allows us to couple the progressive development of damage zone with gas adsorption processes within the coal matrix. For the case of constant effective stress, coal permeability changes from reduction to enhancement while the damage zone within the coal matrix develops from the fracture wall to further inside the matrix. As the peak Langmuir strain is approached, the decrease of permeability halts and permeability increases with pressure. The transition of permeability reduction to permeability enhancement during gas adsorption, which may be closely related to the damage zone development in coal matrix, is controlled by coal heterogeneity, external boundary condition, and adsorption-induced swelling.     

Thermal evolution of an extensional detachment as constrained by organic metamorphic data and thermal modeling: Graz Paleozoic Nappe Complex (Eastern Alps)

Following Early Cretaceous nappe stacking, the Eastern Alps were affected by late-orogenic extension during the Late Cretaceous. In the eastern segment of this range, a Late Cretaceous detachment separates a very low- to low-grade metamorphic cover (Graz Paleozoic Nappe Complex, GPNC) above a low- to high-grade metamorphic basement. Synchronously, the Kainach Gosau Basin (KGB) collapsed and subsided on top of the section.Metamorphism of organic material within this section has been investigated using vitrinite reflectance data and Raman spectra of extracted carbonaceous material. In the southern part of the GPNC, vitrinite reflectance indicates a decrease in organic maturity towards the stratigraphic youngest unit. The remaining part of the GPNC is characterized by an aureole of elevated vitrinite reflectance values and Raman R2 ratios that parallels the margins of the GPNC. Vitrinite reflectance in the KGB shows a steep coalification gradient and increases significantly towards the western basin margin. The observed stratigraphic trend in the southern GPNC is a result of deep Paleozoic to Early Cretaceous burial. This maturity pattern was overprinted along the margins by advective heat and convective fluids during Late Cretaceous to Paleogene exhumation of basement rocks.During shearing, the fault zone was heated up to ca. 500 °C. This overprint is explained by a two-dimensional thermal model with a ramp-flat fault geometry and a slip rate of 1 to 1.5 cm/year during 5 Ma fault movement. The collapse basin above the detachment subsided in a thermal regime which was characterized by relaxing isotherms.     

First Data on the Isotopic Age of Zircons from Rocks of the Roseta Ultramafic Massif,Southern Margin of the São Francisco Craton (Brazil)

Doklady Earth Sciences - The results of isotope U–Pb dating of zircons from lherzolite and vein olivine orthopyroxenite composing the Roseta ultramafic massif are presented. The zircons...     

Transport and retention of suspended particulate matter and bacteria in the Humber-Ouse Estuary, United Kingdom, and their relationship to hypoxia and anoxia

Data are presented on dissolved oxygen (DO) concentrations and their relationship to salinity, suspended particulate matter (SPM), concentrations, and the turbidity maximum in the Humber-Ouse Estuary, United Kingdom, during summer 1995. Measurements in the upper Humber during March 1995 showed DO in the range 82% to 87% of saturation. Suspended particulate matter concentrations were <5000 mg l^?1 and salinity was in the range 0.5 to 12. In contrast, a pronounced DO sag occurred in the upper reaches of the Ouse during medium and spring tide, summer conditions. The DO minimum was essentially an anoxic level and was associated with the location of the turbidity maximum, at salinities between about 0.4 and 1.5. SPM concentrations at 1 m beneath the surface reached 25,000 mg l^?1 in the turbidity maximum, between about 20 km and 40 km from the tidal limit. Suspended particulate matter concentrations were much lower at neap tides, although dense suspensions of SPM (>60,000 mg l^?1) occurred within 1 m of the bed in the turbidity maximum region. A spring-neap record showed a dramatic and tidally controlled decrease in DO at very low salinities as the tides progressed from neaps to springs. An anchor station located down-channel of the turbidity maximum showed that about 95% of the variance in DO, which varied from 28% at low-water slack to 67% at high-water slack, could be explained in terms of salinity variation. At the up-channel margins of the turbidity maximum, DO increased from zero (anoxia) near high water to 60% near low water slack, in contrast to the behavior down-channel of the turbidity maximum. About 82% of the variance in DO could be explained in terms of salinity variations alone. Only 43% of the DO variance could be explained in terms of SPM alone. Up-channel of the turbidity maximum, SPM concentrations were relatively low (<3000 mg l^?1) and DO levels varied from 48% of saturation near high water to 83% near low water slack. About 76% of the variance in DO could be explained in terms of salinity variations alone. Within the turbidity maximum region, DO varied from <2% saturation on the early flood and late ebb and maximized around 7% at high water slack. About 63% of the variance in DO could be explained in terms of salinity variation alone. This increased to 70% when suspended particulate matter was taken into account. Only 29% of the DO variance could be explained in terms of suspended particulate matter alone. Because bacteria were likely to have been the cause of the observed reduction in DO, the numbers of bacteria, both free-living and attached to particles, were measured in the turbidity maximum region. Numbers of free-living bacteria were low and most of the bacteria were attached to sediment particles. There was a linear correlation between total bacterial number and suspended particulate matter concentration, suggesting that the strong DO demand was exerted locally as a result of bacterial activity associated with increased suspended particulate matter concentrations. An order of magnitude analysis of DO consumption within the Ouse’s turbidity maximum, based on the premise that DO depletion was directly related to suspended particulate matter concentrations and that DO addition was due to reaeration, indicates that complete deoxygenation could have occurred with an oxygen depletion rate of ～0.01 mg DO h^?1/g suspended particulate matter during the residence time of waters within the turbidity maximum (～7 d). This rate was sufficiently fast that anoxic to aerobic conditions were able to develop a spring-neap periodicity within the turbidity maximum, but too slow to generate substantial intratidal fluctuations in DO. This is in accordance with the observations, which show that relatively little of the intratidal variance in DO could be explained in terms of suspended particulate matter fluctuations, whereas most of the variance could be explained in terms of salinity, which behaved as a surrogate measure for the proximity of the turbidity maximum.     

Observations of the structure and evolution of solar flares with a soft X-ray telescope

132 soft X-ray flare events have been observed with The Aerospace Corporation/Marshall Space Flight Center S-056 X-ray telescope that was part of the ATM complement of instruments aboard Skylab. Analyses of these data are reported in this paper. The observations are summarized and a detailed discussion of the X-ray flare structures is presented. The data indicated that soft X-rays emitted by a flare come primarily from an intense well-defined core surrounded by a region of fainter, more diffuse emission. Loop structures are found to constitute a fundamental characteristic of flare cores and arcades of loops are found to play a more important role in the flare phenomena than previously thought. Size distributions of these core features are presented and a classification scheme describing the brightest flare X-ray features is proposed. The data show no correlations between the size of core features and: (1) the peak X-ray intensity, as indicated by detectors on the SOLRAD satellite; (2) the rise time of the X-ray flare event, or (3) the presence of a nonthermal X-ray component. An analysis of flare evolution indicates evidence for preliminary heating and energy release prior to the main phase of the flare. Core features are found to be remarkably stable and retain their shape throughout a flare. Most changes in the overall configuration seem to be the result of the appearance, disappearance or change in brightness of individual features, rather than the restructuring or re-orientation of these features. Brief comparisons with several theories are presented.     

Effects of compressibility on driving zonal flow in gas giants

The banded structures observed on the surfaces of the gas giants are associated with strong zonal winds alternating in direction with latitude. We use three-dimensional numerical simulations of compressible convection in the anelastic approximation to explore the properties of zonal winds in rapidly rotating spherical shells. Since the model is restricted to the electrically insulating outer envelope, we therefore neglect magnetic effects.A systematic parametric study for various density scaleheights and Rayleigh numbers allows to explore the dependence of convection and zonal jets on these parameters and to derive scaling laws.While the density stratification affects the local flow amplitude and the convective scales, global quantities and zonal jets properties remain fairly independent of the density stratification. The zonal jets are maintained by Reynolds stresses, which rely on the correlation between zonal and cylindrically radial flow components. The gradual loss of this correlation with increasing supercriticality hampers all our simulations and explains why the additional compressional source of vorticity hardly affects zonal flows.All these common features may explain why previous Boussinesq models were already successful in reproducing the morphology of zonal jets in gas giants.     

Formation and failure of volcanic debris dams in the Chakachatna River valley associated with eruptions of the Spurr volcanic complex, Alaska

The formation of lahars and a debris avalanche during Holocene eruptions of the Spurr volcanic complex in south-central Alaska have led to the development of volcanic debris dams in the Chakachatna River valley. Debris dams composed of lahar and debris-avalanche deposits formed at least five times in the last 8000–10,000 years and most recently during eruptions of Crater Peak vent in 1953 and 1992. Water impounded by a large debris avalanche of early Holocene (?) age may have destabilized an upstream glacier-dammed lake causing a catastrophic flood on the Chakachatna River. A large alluvial fan just downstream of the debris-avalanche deposit is strewn with boulders and blocks and is probably the deposit generated by this flood. Application of a physically based dam-break model yields estimates of peak discharge (Q_p) attained during failure of the debris-avalanche dam in the range 10⁴<Q_p<10⁶ m³ s⁻¹ for plausible breach erosion rates of 10–100 m h⁻¹. Smaller, short-lived, lahar dams that formed during historical eruptions in 1953, and 1992, impounded smaller lakes in the upper Chakachatna River valley and peak flows attained during failure of these volcanic debris dams were in the range 10³<Q_p<10⁴ m³ s⁻¹ for plausible breach erosion rates.Volcanic debris dams have formed at other volcanoes in the Cook Inlet region, Aleutian arc, and Wrangell Mountains but apparently did not fail rapidly or result in large or catastrophic outflows. Steep valley topography and frequent eruptions at volcanoes in this region make for significant hazards associated with the formation and failure of volcanic debris dams.     

Martian rampart crater ejecta: Experiments and analysis of melt-water interaction

Viking images of Martian craters with rampart-bordered ejecta deposits reveal distinct impact ejecta morphology when compared to that associated with similar-sized craters on the Moon and Mercury. Topographic control of distribution, lobate and terraced margins, cross-cutting relationships, and multiple stratigraphic units are evidence for ejecta emplacement by surface flowage. It is suggested that target water explosively vaporized during impact alters initial ballistic trajectories of ejecta and produces surging flow emplacement. The dispersal of particulates during a series of controlled steam explosions generated by interaction of a thermite melt with water has been experimentally modeled. Preliminary results indicate that the mass ratio of water to melt and confining pressure control the degree of melt fragmentation (ejecta particle size) and the energy and mode of melt-ejecta dispersal. Study of terrestrial, lobate, volcanic ejecta produced by steam-blast explosions reveals that particle size and vapor to clast volume ratio are primary parameters characterizing the emplacement mechanism and deposit morphology. Martian crater ramparts are formed when ejecta surges lose fluidizing vapors and transported particles are deposited en masse. This deposition results from flow yield strength increasing above shear stress due to interparticle friction.