Total hydrocarbons,polycyclic aromatic hydrocarbons and synthetic organic compounds in the Hard shell clam, Mercenaria mercenaria, purchased at commercial seafood stores

An analytical method for the determination of polycyclic aromatic h hydrocarbons (PAHs) and substituted benzotriazoles in clams was developed using a combination of silica gel and Sephadex chromatography to isolate these compounds from large concentrations of polyolefinic hydrocarbons. The concentrations of total hydrocarbons, PAHs and substituted benzotriazoles were measured in hard shell clams (Mercenaria mercenaria) purchased from Rhode Island seafood stores. The levels of total hydrocarbons, PAHs and substituted benzotriazoles in these clams were generally higher than the concentrations found in clams collected from a lower Narragansett Bay control location. The significance of these findings on the health of consumers is unknown at this time because human health standards or alert levels for these compounds in seafoods have not been established. However, this study illustrates that contaminants entering Narragansett Bay from a variety of sources may eventually make their way to commercial outlets.     

Adjusted Daily Rainfall and Snowfall Data for Canada

This article documents how Environment and Climate Change Canada’s Adjusted Daily Rainfall and Snowfall (AdjDlyRS) dataset was developed. The adjustments include (i) conversion of ruler measurements of snowfall to its water equivalent using a previously developed snow water equivalent (SWE) ratio map for Canada; (ii) corrections for gauge-related issues including undercatch and evaporation caused by wind effects and gauge-specific wetting loss, as well as for trace precipitation amounts, using previously developed procedures for Canada. Various data flags (e.g., accumulation flags) were also treated. This dataset contains all Canadian stations reporting daily rainfall and snowfall for which we have metadata to implement the adjustments. The length of the data record varies from one station to another, starting as early as 1840. The results show that the original unadjusted total precipitation data in Environment and Climate Change Canada’s digital archive underestimate the total precipitation in northeastern Canada by more than 25% and by about 10–15% in most of southern Canada. Such large underestimates make the original data unsuitable for water availability and/or balance studies or for numerical model validation, among many other applications. The use of the assumed 10:1 SWE ratio for the archived total precipitation data is the primary cause of the underestimate, which is most severe in northeastern Canada. The trace correction adds 5–20% to precipitation values in northern Canada but less than 5% in southern Canada. The gauge-related corrections do not show an organized spatial pattern but add 5–10% to the precipitation at 312 stations. Long runs (≥3 months) of miscoded missing values were also identified and corrected.

The latest version of the AdjDlyRS dataset is available from the Canadian Open Data Portal; currently it is version 2016, which contains 3346 stations and covers the period from station inception to February 2016. This dataset is suitable for producing gridded precipitation datasets, as well as other applications.     

Geochemical and tectonic implications of igneous rocks from ODP leg 114, sub-antarctic South Atlantic

Igneous rocks recovered from three major tectonic features of the sub-antarctic South Atlantic Ocean during ODP Leg 114 have a range of compositions: Northeast Georgia Rise, basalt to andesite; Meteor Rise, basalt to trachyte; spreading center in the West South Atlantic Basin, MORB-like basalt. Major and trace element as well as Sr and Nd isotopic data clearly indicate that all rocks share the enriched elemental and isotopic signatures typical of both hotspot and mid-ocean ridge volcanism in the southern ocean basins. Data for the Northeast Georgia and Meteor Rises also suggest the influence of older, continental lithosphere.     

Physiological responses to copper in giant clams: a comparison of two methods in revealing effects on photosynthesis in zooxanthellae

In the present work physiological responses to a short term, sub-lethal exposure to copper (5 microg Cu2 l(-1) were studied on two species of giant clams, Tridacna gigas and Hippopus hippopus. All giant clams (fam. Tridacnidae) maintain a symbiotic relationship with photo-synthesising microalgae (zooxanthellae) and the phytotoxic effects of this copper concentration were approached with two different end points: changes in oxygen production and maximal quantum yield (Fv/Fm). Additionally we measured respiration, whereby Pg:R ratios could be calculated for the system (algae and clam) and used as an indicator of stress. Cu accumulation was only determined for T. gigas and showed significantly higher tissue concentrations in exposed specimens (11.3 microg Cu g(-1) dry wt) compared to the controls (4.2 microg Cu g(-1)). Both species displayed significantly reduced Pg:R ratios due to exposure, mainly explained by lowered gross production. No indication of stress was shown in the fluorescence measurements and possible explanations are discussed in the paper. We propose that inhibitions in the slow kinetics of photosynthesis were not captured by this fluorescence parameter. Accordingly we suggest that measurements of maximum fluorescence yield should be accompanied by complementary parameters when studying pollutants with unclear phytotoxic mechanisms.     

The influence of snow cover on ground freeze-thaw frequency,intensity, and duration: An experimental study conducted in coastal northern Sweden

The impact of snow cover on seasonal ground frost and freeze-thaw processes is not yet fully understood. The authors therefore examined how snow cover affects seasonal ground frost in a coastal setting in northern Sweden. Air and soil temperatures were recorded in a paired-plot experiment, both with and without snow cover, during the frost season 2012–2013. The frequency, duration, and intensity of the freeze-thaw cycles during the frost season were calculated. The results showed that the freeze-thaw frequency was 57% higher at the soil surface and the intensity 10 °C colder in the spring of 2013, when the ground lacked snow cover. Furthermore, the duration of the seasonal freeze-thaw cycle was 30 days longer on average in cases where there was natural snow accumulation. The correlation between air and ground surface temperatures weakened with increased snow-cover depth. The authors conclude that continued increases in air temperature and decreases in snow in coastal northern Sweden might alter freeze-thaw cycles and thus affect natural and human systems such as geomorphology, ecology, spatial planning, transport, and forestry.     

The stratigraphic and paleoenvironmental setting of Aptian OAE black shale deposits in the Pieniny Klippen Belt, Slovak Western Carpathians

During the Jurassic and Cretaceous, the Pieniny Klippen Belt units of the Outer Western Carpathians were situated on the edge of the Paleoeuropean shelf rimming the northermost margin of the Mediterranean Tethys. During the late early Aptian humid event, Lower Cretaceous pelagic carbonate (Maiolica) sedimentation was interrupted by terrigenous input as a consequence of the first major mid-Cretaceous climate perturbations. The fluctuation of radiolarian abundance indicated an expansion of the oxygen-minimum zone due to upwelling conditions and salinity changes. Foraminifera, radiolarians, non-calcareous dinocysts, and calcareous nannofossils encountered in the West Carpathian Rochovica section enable a comparison of the black shales of the upper lower Aptian Koňhora Formation with the well-known Selli Event. Subsequent anoxia patterns (depositional, productive, and stagnant) have taken part in the depositional regime. Early Aptian climate perturbations both in the Outer Western Carpathians, Swiss Prealps (situated in a similar position on the distal southern edge of the former Paleoeuropean shelf) and/or in other parts of the world are traceable with sedimentological, biological, and chemical proxies.     

Distribution and population structure of deep‐dwelling red coral in the Northwest Mediterranean

Commercially harvested since ancient times, the highly valuable red coral Corallium rubrum (Linnaeus, 1758) is an octocoral endemic to the Mediterranean Sea and adjacent Eastern Atlantic Ocean, where it occurs on rocky bottoms over a wide bathymetric range. Current knowledge is restricted to its shallow populations (15–50 m depth), with comparably little attention given to the deeper populations (50–200 m) that are nowadays the main target of exploitation. In this study, red coral distribution and population structure were assessed in three historically exploited areas (Amalfi, Ischia Island and Elba Island) in the Tyrrhenian Sea (Western Mediterranean Sea) between 50 and 130 m depth by means of ROV during a cruise carried out in the summer of 2010. Red coral populations showed a maximum patch frequency of 0.20 ± 0.04 SD patches·m^?1 and a density ranging between 28 and 204 colonies·m^?2, with a fairly continuous bathymetric distribution. The highest red coral densities in the investigated areas were found on cliffs and boulders mainly exposed to the east, at the greatest depth, and characterized by medium percentage sediment cover. The study populations contained a high percentage (46% on average) of harvestable colonies (>7 mm basal diameter). Moreover, some colonies with fifth‐order branches were also observed, highlighting the probable older age of some components of these populations. The Ischia population showed the highest colony occupancy, density and size, suggesting a better conservation status than the populations at the other study locations. These results indicate that deep dwelling red coral populations in non‐stressed or less‐harvested areas may diverge from the inverse size‐density relationship previously observed in red coral populations with increasing depth.     

Evidence of early deglaciation (18 000 cal a bp) and a postglacial relative sea‐level curve from southern Karmøy,south‐west Norway

Based on six consistent radiocarbon dates from the isolation basins Grødheimsvatnet and Kringlemyr, we estimate a minimum deglaciation age for southern Karmøy, an island in outer Boknafjorden (south‐west Norway), of around 18 000 calibrated years before present (18k cal a bp ). We use microscopic phytoplankton, macrofossils, lithostratigraphic evidence and X‐ray fluorescence data to identify the isolation contacts in the basins, and date them to 17.52–17.18k cal a bp in Grødheimsvatnet [15.57 m above present mean sea level (MSL)] and 16.19–15.80k cal a bp in Kringlemyr (11.99 m above MSL). Combining these data with previous studies, we construct a relative sea‐level (RSL) curve from 18k cal a bp until the present, which is ~3 ka longer than any previous RSL reconstruction from southern Norway. Following deglaciation, southern Karmøy has experienced a net emergence of around 16–19 m, although with significant RSL fluctuations. This includes two RSL minima well below present MSL around ~13.8 and ~10k cal a bp , and two maxima that culminated around 5–7 m above MSL during the Younger Dryas and early to mid‐Holocene, respectively. Considering eustatic sea level and modelled gravitational deformation of the geoid, we estimate a net postglacial isostatic uplift of ~120 m. © 2019 John Wiley & Sons, Ltd     

Seasonal variations in groundwater upwelling zones in a Danish lowland stream analyzed using Distributed Temperature Sensing (DTS)

The distribution of groundwater inflows in a stream reach plays a major role in controlling the stream temperature, a vital component shaping the riverine ecosystem. In this study, the Distributed Temperature Sensing (DTS) system was installed in a small Danish lowland stream, Elverdamsåen, to assess the seasonal dynamics of groundwater inflow zones using high spatial (1 m) and temporal (3 minutes) resolution of water temperature measurements. Four simple criteria consisting of 30 min average temperature at 16:00, mean and standard deviation of diurnal temperatures, and the day–night temperature difference were applied to three DTS datasets representing stream temperature responses to the variable meteorological and hydrological conditions prevailing in summer, winter and spring. The standard deviation criterion was useful to identify groundwater discharge zones in summer and spring conditions, while the mean temperature criterion was better for the winter conditions. In total, 20 interactions were identified from the DTS datasets representing summer, 16 in winter and 19 in spring, albeit with only two interactions contributing in all three seasons. Higher baseflow to streamflow ratio, antecedent precipitation and presence of fractured clayey till in the stream reach were deemed as the vital factors causing apparent seasonal variation in the locations of upwelling zones, prompting use of DTS not only in preconceived scenarios of large diurnal temperature change but rather a long‐term deployment covering variable meteorological and hydrological scenarios. Copyright © 2012 John Wiley & Sons, Ltd.