Chemical dispersant effectiveness testing: influence of droplet coalescence

Thermodynamic and kinetic investigations were performed to determine the influence of coalescence of chemically dispersed crude oil droplets in saline waters. For the range of pH (4-10) and salinity (10 per thousand, 30 per thousand, 50 per thousand ) values studied, zeta-potential values ranged from -3 to -10 mV. As the interaction potential values calculated using Derjaguin-Landau-Verway-Overbeek (DLVO) theory were negative, the electrostatic barrier did not produce significant resistance to droplet coalescence. Coalescence kinetics of premixed crude oil and chemical dispersant were determined within a range of mean shear rates (Gm = 5, 10, 15, 20 s(-1)) and salinity (10 per thousand, 30 per thousand ) values. Coalescence reaction rates were modeled using Smoluchowski reaction kinetics. Measured collision efficiency values (alpha = 0.25) suggest insignificant resistance to coalescence in shear systems. Experimentally determined dispersant efficiencies (alpha = 0.35) were 10-50% lower than that predicted using a non-interacting droplet model (alpha = 0.0). Unlike other protocols in which the crude oil and dispersant are not premixed, salinity effects were not significant in this protocol. This approach allowed the effects of dispersant-oil contact efficiency eta(contact) to be separated from those of water column transport efficiency (eta(transport)) and coalescence efficiency (eta(coalescence)).     

Command and control cities in global space-economy before and after 2008 geo-economic transition

The global economic downturn caused primarily by the US sub-prime mortgage crisis in 2007 engendered revenue loss of the multinational corporations.Existing studies have yet to depict the detrimental impacts on city’s command and control functions induced by the sub-prime mortgage crisis together with its residual wave of global economic recession on the global spatial economy.Recent and previous studies have produced an ’instant history’ of the global spatial economy before the global economic downturn undermines the global economy in late 2008.However,the waxes and wanes of major cities’ command and control functions on the global economic arena before and after the outbreak of financial crisis and its associated geo-economic transitions are still poorly understood.This paper attempts to contribute a new set of customized data to update and fill in the gap in the literature with the investigation of the command and control functions of cities around the world from 2005 to 2009.Particular attentions are paid to the time-space relationship of the geo-economic transition that can capture the recent historical images of the command and control situation of different cities in the world.     

On the structural age of the Rhoscolyn antiform,Anglesey, North Wales

In the Rhoscolyn area of Anglesey, the late Precambrian interbedded psammites and pelites of the Monian Supergroup are folded into a kilometre‐scale antiform, plunging about 25°NE and with an axial surface dipping about 40°NW. Numerous folds of up to a few tens of metres in wavelength are present on both limbs of this antiform. These smaller‐scale folds also plunge about 25°NE but clearly belong to two separate episodes of folding, and it has become a matter of longstanding controversy as to whether the larger antiform belongs to the first or second of these episodes. Close examination of the cleavage/bedding asymmetries from all the lithologies, however, shows that the large antiform is a second‐generation structure, and that on the gently dipping northwest limb, the sense of cleavage/bedding asymmetry of the earlier cleavage in the psammitic units has been almost uniformly and homogeneously reversed (so that it appears to be axial planar to the antiform), while in the pelitic units the sense of cleavage/bedding asymmetry of the earlier cleavage has been preserved. Many of the small‐scale complexities of the observed cleavage/bedding relationships may be explained by appealing to differences in the timing of the formation of buckling instabilities relative to this reorientation of the early cleavage in the psammites during the second deformation. A first‐order analysis of the finite strains from around the large‐scale antiform shows that the orientation of the first cleavage prior to the second deformation was steeply dipping to the southeast. The second deformation correlates with the southeast‐verging Caledonian deformation affecting the Monian and Ordovician units elsewhere in northwest Anglesey, while the northwest‐verging first deformation event, which is not present in the Ordovician rocks, must have occurred before they were deposited. Copyright © 2004 John Wiley & Sons, Ltd.     

Lifetime of the Hα chromospheric network

Time-lapse photographs of the H chromospheric network were taken at 3-sec intervals with a -Å filter centered at H + 0.65 Å, where the network appears as a system of dark mottles. A nearly continuous sequence of 62 hr duration was made possible by summertime operation of the telescope at Thule Air Base, Greenland, 10° above the Arctic Circle. A quiet region was followed across the center of the disc. The life history of the network, as determined by measurement of the cross-correlation of selected photographs taken at intervals ranging between 3 sec and 29 hr, shows a rather complicated behavior. Initially the correlation falls off quite rapidly, dropping from 0.97 at 3 sec to 0.60 at about 7 min. Thereafter, the decline becomes increasingly more gradual, reaching a value of 0.24 at 4 hr. From this point the correlation falls off quite slowly. A least-squares fit to that portion of the cross-correlation curve for time differences greater than 4 hr yields a mean (1/e) life of 25.0 ± 1.6 hr and a value for twice the half-life of 38.8 ± 4.0 hr. This rate of decline is believed to be characteristic of the lifetime of the chromospheric network. The rapid initial loss of correlation appears to be due to a redistribution of the features, seen in the red wing of the H line, along the network.     

COCORP deep seismic reflection traverses of the U.S. Cordillera

Summary. COCORP seismic reflection traverses of the U.S. Cordillera at 40°N and 48.5°N latitude reveal some fundamental similarities as well as significant differences in reflection patterns. On both traverses, autochthonous crust beneath thin-skinned thrust belts of the eastern part of the Cordillera is unreflective; immediately to the west the Cordilleran interior is very reflective above a flat, prominent reflection Moho. Mesozoic accreted terranes in the western part of the orogen are underlain on both traverses by very complex reflection patterns, in constrast to more easily deciphered patterns beneath areas of Cenozoic accretion. The prominent reflection Moho beneath the orogenic interior on both transects probably evolved through a combination of magmatic and deformational processes during Cenozoic extension. The main differences between the two traverses lie in the reflection patterns of the middle and lower crust in the Cordilleran interior; these differences are probably related to the way Cenozoic extension was accommodated at depth. Laminated middle and lower crust above the reflection Moho in the western Basin and Range (40°N) may be related to magmatism, ductile pure shear and large-scale transposition during Cenozoic extension. By contrast, beneath the eastern Basin and Range (40°N), and the orogenic interior in the NW United States (48.5°N), Cenozoic extension was probably accommodated along dipping deformation zones throughout the crust.     

On the stable stratification of the nocturnal lower troposphere inferred from lidar observations over Pune,India

The nocturnal structure of the lower troposphere is studied using aerosol profile data (50–2800 m AGL) obtained with a bistatic, continuous wave, Argon ion lidar system during October 1986–September 1989 at Pune (18°32 N, 73°51 E, 559m AMSL), India. The top of the nocturnal groundbased inversion is taken as the height above ground where the negative vertical gradient in aerosol concentration first reaches a maximum. During the post-sunset period over this station, this height is as low as 160m and frequently lies around 550m. Greater heights are observed in pre-monsoon months and smaller ones during the southwest monsoon season. Positive vertical gradients in aerosol concentration, indicative of stable/elevated layers, appear frequently around 750m. Temporal variations of aerosol concentration gradients in two adjacent air layers, 920–1000m and 100–1100m, provide evidence that stability increases downward in the early night hours.     

Characterizing aquatic sediment-oil aggregates using in situ instruments

The effects of emulsified crude oil and salinity (15, 30 per thousand ) on the steady state aggregate volume distributions and fractal dimensions were determined for a range of mean velocity gradients, (G(m) =5-50 s(-1)). Aggregation was performed in a 40-L cylindrical tank with a 4-blade paddle mixer. Three-dimensional fractal dimensions (D3) and volume distributions were determined using a procedure integrating data from an electrozone and an in situ light scattering instrument. Two-dimensional fractal dimensions (D2) and derived volume distributions were determined using a recently developed submersible flow cytometer equipped with a digital camera and image analysis software. For latex beads or emulsified crude oil systems, the above listed instruments yielded consistent size distributions and fractal dimensions (D2=1.92 +/- 0.16, D3=2.94 +/- 0.12). Mean volume aggregate diameters determined using the FlowCAM were consistently larger that those determined using the LISST-100 or Coulter Multisizer due to aggregate orientations during measurements. With increasing G(m) values, all colloidal aggregates showed increasing D3 values due to reduced aggregate length. Because of the compactness of all the aggregates (D3 >2), D2 values remained constant at 2. Neither salinity nor sediment type significantly affected D2 values calculated for sediment-crude oil aggregates. However, clay-oil aggregates showed higher D3 values than clay aggregates. This suggests that colloidal oil and mixing shear are the more dominant factors influencing aggregate morphology in nearshore waters. Overall, the data suggests that the analysis methods provide consistent size distribution results. However, because of the shear and salinity of coastal waters, resulting aggregates are too compact to estimate their D3 values using image analysis alone.     

Zonal and meridional air currents in the stratosphere over Europe

Wind observations in the stratosphere above the British isles are treated statistically, with special regard to the variations of zonal and meridional wind components with height and during the year.

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Zusammenfassung Windbeobachtungen aus der Stratosphäre über den Britischen Inseln sind statistisch bearbeitet worden, wobei das Hauptgewicht darauf gelegt wurde, das Verhalten der zonalen und meridionalen Windkomponente im Jahresgang und als Funktion der Höhe zu beschreiben und diskutieren.