Phase Equilibria Constraints on the Chemical and Physical Evolution of the Campanian Ignimbrite

The Campanian Ignimbrite is a > 200 km³ trachyte–phonolitepyroclastic deposit that erupted at 39·3 ± 0·1ka within the Campi Flegrei west of Naples, Italy. Here we testthe hypothesis that Campanian Ignimbrite magma was derived byisobaric crystal fractionation of a parental basaltic trachyandesiticmelt that reacted and came into local equilibrium with smallamounts (5–10 wt%) of crustal rock (skarns and foid-syenites)during crystallization. Comparison of observed crystal and magmacompositions with results of phase equilibria assimilation–fractionationsimulations (MELTS) is generally very good. Oxygen fugacitywas approximately buffered along QFM + 1 (where QFM is the quartz–fayalite–magnetitebuffer) during isobaric fractionation at 0·15 GPa ( 6km depth). The parental melt, reconstructed from melt inclusionand host clinopyroxene compositions, is found to be basaltictrachyandesite liquid (51·1 wt% SiO₂, 9·3 wt%MgO, 3 wt% H₂O). A significant feature of phase equilibria simulationsis the existence of a pseudo-invariant temperature, 883 °C,at which the fraction of melt remaining in the system decreasesabruptly from 0·5 to < 0·1. Crystallizationat the pseudo-invariant point leads to abrupt changes in thecomposition, properties (density, dissolved water content),and physical state (viscosity, volume fraction fluid) of meltand magma. A dramatic decrease in melt viscosity (from 1700Pa s to 200 Pa s), coupled with a change in the volume fractionof water in magma (from 0·1 to 0·8) and a dramaticdecrease in melt and magma density acted as a destabilizingeruption trigger. Thermal models suggest a timescale of 200kyr from the beginning of fractionation until eruption, leadingto an apparent rate of evolved magma generation of about 10^–3km³/year. In situ crystallization and crystal settling in density-stratifiedregions, as well as in convectively mixed, less evolved subjacentmagma, operate rapidly enough to match this apparent volumetricrate of evolved magma production. KEY WORDS: assimilation; Campanian Ignimbrite; fractional crystallization; magma dynamics; phase equilibria     

Geology and Metallogenesis of the Sawayaerdun Gold Deposit in the Southwestern Tianshan Mountains, Xinjiang, China

The Sawayaerdun gold deposit, located in Wuqia County, Southwest Tianshan, China, occurs in Upper Silurian and Lower Devonian low‐grade metamorphic carbonaceous turbidites. The orebodies are controlled by a series of NE‐NNE‐trending, brittle–ductile shear zones. Twenty‐four gold mineralized zones have been recognized in the Sawayaerdun ore deposit. Among these, the up to 4‐km‐long and 200‐m wide No. IV mineralized zone is economically the most important. The average gold grade is 1–6 g/t. Gold reserves of the Sawayaerdun deposit have been identified at approximately 37 tonnes and an inferred resource of 123 tonnes. Hydrothermal alteration is characterized by silicification, pyritization, arsenopyritization, sericitization, carbonatization and chloritization. On the basis of field evidence and petrographic analysis, five stages of vein emplacement and hydrothermal mineralization can be distinguished: stage 1, early quartz stage, characterized by the occurrence of quartz veins; stage 2, arsenopyrite–pyrite–quartz stage, characterized by the formation of auriferous quartz veinlets and stockworks; stage 3, polymetallic sulfide quartz stage, characterized by the presence of auriferous polymetallic sulfide quartz veinlets and stockworks; stage 4, antimony–quartz stage, characterized by the formation of stibnite–jamesonite quartz veins; and stage 5, quartz–carbonate vein stage. Stages 2 and 3 represent the main gold mineralization, with stage 4 representing a major antimony mineralization episode in the Sawayaerdun deposit. Two types of fluid inclusion, namely H₂O–NaCl and H₂O–CO₂–NaCl types, have been recognized in quartz and calcite. Aqueous inclusions show a wide range of homogenization temperatures from 125 to 340°C, and can be correlated with the mineralization stage during which the inclusions formed. Similarly, salinities and densities of these fluids range for each stage of mineralization from 2.57 to 22 equivalent wt% NaCl and 0.76 to 1.05 g/cm³, respectively. The ore‐forming fluids thus are representative of a medium‐ to low‐temperature, low‐ to medium‐salinity H₂O–NaCl–CO₂–CH₄–N₂ system. The δ³⁴S_CDT values of sulfides associated with mineralization fall into a narrow range of ?3.0 to +2.6‰ with a mean of +0.1‰. The δ¹³C_PDB values of dolomite and siderite from the Sawayaerdun gold deposit range from ?5.4 to ?0.6‰, possibly reflecting derivation of the carbonate carbon from a mixed magmatic/sedimentary source. Changes in physico‐chemical conditions and composition of the hydrothermal fluids, water–rock exchange and immiscibility of hydrothermal fluids are inferred to have played important roles in the ore‐forming process of the Sawayaerdun gold–antimony deposit.     

New results concerning the pedo- and chronostratigraphy of the loess–palaeosol sequence Attenfeld (Bavaria,Germany) derived from a multi-methodological approach

Loess–palaeosol sequences (LPS) represent important records of palaeoenvironmental dynamics throughout the Quaternary. During the Pleistocene's dry and cold phases, the Danube's riverbed was one of the major sources for loess sediments that built up LPS in southern Germany and southeastern Europe. Surprisingly, studies addressing Bavarian LPS along the Danube River often lack actuality. The Attenfeld site was one of them and is often cited as a typical LPS. Nevertheless, the site's previous interpretations are based on a few empirical data and field observations. Considering the site's closeness to the sediment's source area, the Alps, and the region's importance in Middle and Upper Palaeolithic migrational movements, those former renditions needed an evaluation. Therefore, we applied a multi-proxy approach (including analyses of grain-size distribution, element composition, and sediment colour attributes) combined with optically stimulated luminescence. Based on our findings, we conclude that the Attenfeld site's former interpretations might be too generalised. We identified units that were not mentioned by previous studies (e.g. Early Glacial dark greyish horizon). Field observations, sediment characteristics, and age estimates indicate sediment deposition of the dated units partly before MIS 4, which contrasts with previous interpretations. The results further demonstrate how sensitive LPS are to environmental settings and dynamics.     

Detection of free vertical convection and double-diffusion in groundwater monitoring wells with geophysical borehole measurements

Two algorithms for in-situ detection and identification of vertical free convective and double-diffusive flows in groundwater monitoring wells or boreholes are proposed. With one algorithm the causes (driving forces) and with the other one the effects (convection or double-diffusion) of vertical transport processes can be detected based on geophysical borehole measurements in the water column. Five density-driven flow processes are identified: thermal, solutal, and thermosolutal convection leading to an equalization, as well as saltfingers and diffusive layering leading to an intensification of a vertical density gradient. The occurrence of density-driven transport processes could be proven in many groundwater monitoring wells and boreholes; especially shallow sections of boreholes or groundwater monitoring wells are affected dramatically by such vertical flows. Deep sections are also impaired as the critical threshold for the onset of a density-driven flow is considerably low. In monitoring wells or boreholes, several sections with different types of density-driven vertical flows may exist at the same time. Results from experimental investigations in a medium-scale testing facility with high aspect ratio (height/radius = 19) and from numerical modeling of a water column agree well with paramters of in-situ detected convection cells.     

Overstepping the garnet isograd: a comparison of QuiG barometry and thermodynamic modeling

The consequences of overstepping the garnet isograd reaction have been investigated by comparing the composition of garnet formed at overstepped P–T conditions (the overstep or “OS” model) with the P–T conditions that would be inferred by assuming garnet nucleated in equilibrium with the matrix assemblage at the isograd (the equilibrium or “EQ” model). The garnet nucleus composition formed at overstepped conditions is calculated as the composition that produces the maximum decrease in Gibbs free energy from the equilibrated, garnet-absent, matrix assemblage for the bulk composition under study. Isopleths were then calculated for this garnet nucleus composition assuming equilibrium with the matrix assemblage (the EQ model). Comparison of the actual P–T conditions of nucleation (the OS model) with those inferred from the EQ model reveals considerable discrepancy between the two. In general, the inferred garnet nucleation P–T conditions (the EQ model) are at a lower temperature and higher or lower pressure (depending on the coexisting calcic phase(s)) than the actual (OS model) nucleation conditions. Moreover, the degree of discrepancy increases with the degree of overstepping. Independent estimates of the pressure of nucleation of garnet were made using the Raman shift of quartz inclusions in garnet (quartz-in-garnet or QuiG barometry). To test the validity of this method, an experimental synthesis of garnet containing quartz inclusions was made at 800 °C, 20 kbar, and the measured Raman shift reproduced the synthesis conditions to within 120 bars. Raman band shifts from three natural samples were then used to calculate an isochore along which garnet was presumed to have nucleated. Model calculations were made at several temperatures along this isochore (the OS model), and these P–T conditions were compared to those computed assuming equilibrium nucleation (the EQ model) to estimate the degree of overstepping displayed by these samples. A sample from the garnet isograd in eastern Vermont is consistent with overstepping of around 10 degrees and 0.6 kbar (affinities of around 2 kJ/mole garnet). A sample from the staurolite–kyanite zone in the same terrane requires overstepping of around 50 °C and 2–5 kbar (affinities of around 10–18 kJ/mole garnet). A similar amount of overstepping was inferred for a blueschist sample from Sifnos, Greece. These results indicate that overstepping of garnet nucleation reactions may be common and pronounced in regionally metamorphosed terranes, and that the P–T conditions and paths inferred from garnet zoning studies may be egregiously in error.     

The hydrochemistry of a semi-arid pan basin case study: Sua Pan,Makgadikgadi, Botswana

This study presents results on the fluid and salt chemistry for the Makgadikgadi, a substantial continental basin in the semi-arid Kalahari. The aims of the study are to improve understanding of the hydrology of such a system and to identify the sources of the solutes and the controls on their cycling within pans. Sampling took place against the backdrop of unusually severe flooding as well as significant anthropogenic extraction of subsurface brines. This paper examines in particular the relationship between the chemistry of soil leachates, fresh stream water, salty lake water, surface salts and subsurface brines at Sua Pan, Botswana with the aim of improving the understanding of the system’s hydrology. Occasionally during the short wet season (December–March) surface water enters the saline environment and precipitates mostly calcite and halite, as well as dolomite and traces of other salts associated with the desiccation of the lake. The hypersaline subsurface brine (up to TDS 190,000 mg/L) is homogenous with minor variations due to pumping by BotAsh mine (Botswana Ash (Pty) Ltd.), which extracts 2400 m³ of brine/h from a depth of 38 m. Notable is the decrease in TDS as the pumping rate increases which may be indicative of subsurface recharge by less saline water. Isotope chemistry for Sr (⁸⁷Sr/⁸⁶Sr average 0.722087) and S (δ³⁴S average 34.35) suggests subsurface brines have been subject to a lithological contribution of undetermined origin. Recharge of the subsurface brine from surface water including the Nata River appears to be negligible.     

Sedimentology of the continental end‐Permian extinction event in the Sydney Basin,eastern Australia

Upper Permian to Lower Triassic coastal plain successions of the Sydney Basin in eastern Australia have been investigated in outcrop and continuous drillcores. The purpose of the investigation is to provide an assessment of palaeoenvironmental change at high southern palaeolatitudes in a continental margin context for the late Permian (Lopingian), across the end‐Permian Extinction interval, and into the Early Triassic. These basins were affected by explosive volcanic eruptions during the late Permian and, to a much lesser extent, during the Early Triassic, allowing high‐resolution age determination on the numerous tuff horizons. Palaeobotanical and radiogenic isotope data indicate that the end‐Permian Extinction occurs at the top of the uppermost coal bed, and the Permo‐Triassic boundary either within an immediately overlying mudrock succession or within a succeeding channel sandstone body, depending on locality due to lateral variation. Late Permian depositional environments were initially (during the Wuchiapingian) shallow marine and deltaic, but coastal plain fluvial environments with extensive coal‐forming mires became progressively established during the early late Permian, reflected in numerous preserved coal seams. The fluvial style of coastal plain channel deposits varies geographically. However, apart from the loss of peat‐forming mires, no significant long‐term change in depositional style (grain size, sediment‐body architecture, or sediment dispersal direction) was noted across the end‐Permian Extinction (pinpointed by turnover of the palaeoflora). There is no evidence for immediate aridification across the boundary despite a loss of coal from these successions. Rather, the end‐Permian Extinction marks the base of a long‐term, progressive trend towards better‐drained alluvial conditions into the Early Triassic. Indeed, the floral turnover was immediately followed by a flooding event in basinal depocentres, following which fluvial systems similar to those active prior to the end‐Permian Extinction were re‐established. The age of the floral extinction is constrained to 252.54 ± 0.08 to 252.10 ± 0.06 Ma by a suite of new Chemical Abrasion Isotope Dilution Thermal Ionization Mass Spectrometry U‐Pb ages on zircon grains. Another new age indicates that the return to fluvial sedimentation similar to that before the end‐Permian Extinction occurred in the basal Triassic (prior to 251.51 ± 0.14 Ma). The character of the surface separating coal‐bearing pre‐end‐Permian Extinction from coal‐barren post‐end‐Permian Extinction strata varies across the basins. In basin‐central locations, the contact varies from disconformable, where a fluvial channel body has cut down to the level of the top coal, to conformable where the top coal is overlain by mudrocks and interbedded sandstone–siltstone facies. In basin‐marginal locations, however, the contact is a pronounced erosional disconformity with coarse‐grained alluvial facies overlying older Permian rocks. There is no evidence that the contact is everywhere a disconformity or unconformity.     

Out-of-sequence thrusts and paleogeography of the Rhenodanubian Flysch Belt (Eastern Alps) revisited

The Oberstdorf nappe of the Western and the Laab nappe of the Eastern Rhenodanubian Flysch (ERF) were independently identified as out-of-sequence thrust units by facies studies (Mattern 1999) and zircon analyses (Trautwein et al. 2001a, b, c), respectively. A new look at both areas reveals mutual similarities and new evidence for the out-of-sequence concept. Paleocurrent and heavy mineral data make it possible to reconstruct the sediment influx directions. From the Barremian to the mid-Campanian, the western and eastern basin segments were fed with south-derived garnet and north-derived zircon/”ZTR” (i.e., zircon, tourmaline, and rutile). Because both out-of-sequence units are relatively rich in zircon/ZTR they must have occupied the northernmost basin position. In the Western Rhenodanubian Flysch segment, the Sigiswang nappe occupied the central and the Üntschen nappe the southernmost basin position. In the ERF segment the central basin is represented by the Greifenstein nappe and the southernmost basin by the Kahlenberg nappe. Both out-of-sequence units do not occur in the northernmost and tectonically lowest position in their respective nappe piles as they were thrust over the other nappes. The reconstructed basin positions of the thrust units are suggested by the observation of a gradient in heavy mineral content in the thrust units. This paleogeographic arrangement is least problematic and renders models with differently positioned thrust units, requiring debris-shedding intrabasinal ridges, as unnecessarily complicated. Instead, we suggest that gradual changes in heavy mineral composition existed in across-basin direction. Garnet may stem from the Central Gneiss Complex of the Tauern window and formerly exposed lateral equivalents, all representing the southern Mid-Penninic zone. We assign the Falknis/Tasna nappe and formerly exposed lateral equivalents to the northern Mid-Penninic zone which served as the zircon/ZTR source. Interpreting Ebbing’s (Ph.D. thesis, Freie Universität Berlin, pp 1-143, 2002; Fig. 6.10) density section, we suggest that Mid-Penninic crust exists beneath the Central Gneiss Complex. During the latest Cretaceous much garnet was also N-derived. This may reflect processes related to the consumption of the North Penninic basin.     

Responses to the 2011 floods in Central Thailand: Perpetuating the vulnerability of small and medium enterprises?

Natural Hazards - The 2011 flood was the worst in Thailand in decades. Many of the impacts occurred in the Bangkok Metropolitan Region. The floods negatively affected small and medium enterprises...