Infrared imaging spectroscopy with micron resolution of Sutter's Mill meteorite grains

Synchrotron‐based Fourier transform infrared spectroscopy and Raman spectroscopy are applied with submicrometer spatial resolution to multiple grains of Sutter's Mill meteorite, a regolith breccia with CM1 and CM2 lithologies. The Raman and infrared active functional groups reveal the nature and distribution of organic and mineral components and confirm that SM12 reached higher metamorphism temperatures than SM2. The spatial distributions of carbonates and organic matter are negatively correlated. The spatial distributions of aliphatic organic matter and OH relative to the distributions of silicates in SM2 differ from those in SM12, supporting a hypothesis that the parent body of Sutter's Mill is a combination of multiple bodies with different origins. The high aliphatic CH₂/CH₃ ratios determined from band intensities for SM2 and SM12 grains are similar to those of IDPs and less altered carbonaceous chondrites, and they are significantly higher than those in other CM chondrites and diffuse ISM objects.     

Oxygen isotope and chemical compositions of magnetite and olivine in the anomalous CK3 Watson 002 and ungrouped Asuka‐881595 carbonaceous chondrites: Effects of parent body metamorphism

We report in situ O isotope and chemical compositions of magnetite and olivine in chondrules of the carbonaceous chondrites Watson‐002 (anomalous CK3) and Asuka (A)‐881595 (ungrouped C3). Magnetite in Watson‐002 occurs as inclusion‐free subhedral grains and rounded inclusion‐bearing porous grains replacing Fe,Ni‐metal. In A‐881595, magnetite is almost entirely inclusion‐free and coexists with Ni‐rich sulfide and less abundant Ni‐poor metal. Oxygen isotope compositions of chondrule olivine in both meteorites plot along carbonaceous chondrite anhydrous mineral (CCAM) line with a slope of approximately 1 and show a range of Δ¹⁷O values (from approximately ?3 to ?6‰). One chondrule from each sample was found to contain O isotopically heterogeneous olivine, probably relict grains. Oxygen isotope compositions of magnetite in A‐881595 plot along a mass‐dependent fractionation line with a slope of 0.5 and show a range of Δ¹⁷O values from ?2.4‰ to ?1.1‰. Oxygen isotope compositions of magnetite in Watson‐002 cluster near the CCAM line and a Δ¹⁷O value of ?4.0‰ to ?2.9‰. These observations indicate that magnetite and chondrule olivine are in O isotope disequilibrium, and, therefore, not cogenetic. We infer that magnetite in CK chondrites formed by the oxidation of pre‐existing metal grains by an aqueous fluid during parent body alteration, in agreement with previous studies. The differences in Δ¹⁷O values of magnetite between Watson‐002 and A‐881595 can be attributed to their different thermal histories: the former experienced a higher degree of thermal metamorphism that led to the O isotope exchange between magnetite and adjacent silicates.     

Microstructure,metamorphism, thermochronology and P-T-t-deformation history of the Port aux Basques gneisses,south-west Newfoundland,Canada*

Abstract The Port aux Basques gneisses comprise three lithostratigraphic units separated by major fault zones: the Grand Bay Complex; the Port aux Basques Complex; and the Harbor le Cou Group. A similar regionally developed polyphase history of penetrative deformation characterizes each of these units. Thickening during D1 produced rare recumbent folds (F1) and an axial planar schistosity (S1), overprinted by D2 recumbent folds (F2), and transposed during development of a locally penetrative, differentiated crenulation cleavage (S2). In western sectors of the area, D2 was associated with NW-directed reverse shearing. The NE-trending structural grain reflects D3 transpression, partitioned into dextral transcurrent movement along major shear zones and development of upright-to-steeply inclined, periclinal folds (F3) and a variably penetrative schistosity (S3). Amphibolite facies metamorphism increases in grade from west to east across the area. Microstructures, including porphyroblast-matrix foliation relations and internal textural unconformities in garnet, indicate episodic porphyroblast nucleation and growth, which reflect a prograde traverse sequentially across univariant reactions during syntectonic metamorphism. Garnet, kyanite and staurolite porphyroblasts are wrapped by the S2 foliation, but each may contain trails of inclusions that define S1; commonly these trails preserve early stages of S2 crenulation cleavage development. Progressive and sequential reaction out of kyanite, staurolite and muscovite in favour of sillimanite, garnet, biotite and K-feldspar, and the development of an increasing volume of anatectic migmatite in south-eastern sectors of the area record syn- to late-D2 peak metamorphic conditions. Microstructural relationships and petrogenetic grid considerations indicate clockwise trajectories in P-T space for units of the Port aux Basques gneisses. Peak metamorphic conditions are estimated to have been 620–650° C at ≤8kbar in the west and 700–750° C at ≤8 kbar in the east. Titanite from an upper amphibolite facies calc-silicate gneiss yields U-Pb ages of c. 420 Ma, interpreted to date cooling shortly after the thermal peak in these gneisses. Variable D3 strain was associated with some recrystallization of hornblende and micas. ⁴⁰Ar/³⁹Ar hornblende plateau isotope correlation ages range from c. 419 to c. 393 Ma, from east to west across the area, and are interpreted to record cooling through c. 500° C coeval with or soon after D3 deformation. The range in ages may record the effects of heterogeneous D3 deformation and differential uplift from south-east to north-west associated with displacement on major shear zones. ⁴⁰Ar/³⁹Ar muscovite plateau ages cluster at c. 390 Ma, and date cooling through c. 375° C during regional exhumation. Cooling rates are moderate to fast and may indicate a component of tectonic exhumation. The Port aux Basques gneisses are a product of Silurian collisional tectonics. The higher grade of metamorphism in comparison with adjacent areas of the Canadian Appalachians is interpreted to reflect greater thickening due to juxtaposition of the St Lawrence promontory (Laurentian margin) with the Cabot promontory (Avalonian margin) during closure of the Iapetus Ocean.     

NIGHTGLOW: an instrument to measure the Earth’s nighttime ultraviolet glow—results from the first engineering flight

We have designed and built an instrument to measure and monitor the “nightglow” of the Earth’s atmosphere in the near ultraviolet (NUV). In this paper we describe the design of this instrument, called NIGHTGLOW. NIGHTGLOW is designed to be flown from a high altitude research balloon, and circumnavigate the globe. NIGHTGLOW is a NASA, University of Utah, and New Mexico State University project. A test flight took place from Palestine, Texas on July 5, 2000, lasting about 8 h. The instrument performed well and landed safely in Stiles, Texas with little damage. The resulting measurements of the NUV nightglow are compared with previous measurements from sounding rockets and balloons.     

Radiating dike swarms on Venus: evidence for emplacement at zones of neutral buoyancy

Theoretical calculations of extrusive volcanic degassing on Venus yield atmospheric pressure-related rock density profiles consistent with the formation of magma neutral buoyancy zones and magma reservoirs at different depths as a function of altitude (Head and Wilson, J. geophys. Res. 97, 3877, 1992). Global analysis of radiating dike swarms interpreted to originate at magma reservoirs show that their distribution matches these predictions across approximately 90% of the planet's surface; only those highland regions whose elevations exceed 6053 km appear anomalous. The distribution of the large volcano population (extrusive reservoir products) (Keddie and Head, Planet. Space Sci. 42, 455, 1994) has yielded similar results. Comparison between the dike swarm (intrusive) and large volcano (extrusive) populations suggests that neutral buoyancy plays an important role in governing volcanic processes near the venusian surface and that the depth to the level of neutral buoyancy increases systematically at altitudes above 6051 km.     

40Ar‐39Ar studies of whole rock nakhlites: Evidence for the timing of formation and aqueous alteration on Mars

Abstract— 20–25 mg whole rock samples of the nakhlites Lafayette and Nakhla have been analyzed via the ⁴⁰Ar‐³⁹Ar technique, in part to verify their formation ages, but primarily, in an attempt to determine the timing of aqueous alteration in these martian meteorites. As in previous studies, plateaus in apparent age are observed at about 1300 Ma (1322 ± 10 for Lafayette, 1332 ± 10 and 1323 ± 11 for Nakhla), presumably corresponding to crystallization ages. The plateaus are not entirely flat, perhaps reflecting the effects of recoil during creation of ³⁹Ar in the nuclear irradiation. The first 5–20% of the K‐derived Ar released from all three samples give apparent ages <1300 Ma. Coupled with the fact that chronometric isotopic studies of nakhlites typically show some disturbance, we believe the low temperature pattern represents more recent (than 1300 Ma) formation of martian aqueous alteration products such as iddingsite. No low temperature plateaus are observed. This is consistent with petrographic evidence for multiple formation events, although the lack of low temperature plateaus is far from conclusive. On the other hand, if there was a single time of alteration, we believe that it will be difficult, if not impossible, to determine it using the K‐Ar system.     

Lewis Cliff 86360: An Antarctic L-chondrite with a terrestrial age of 2.35 million years

Abstract— We measured the concentrations of the cosmogenic radionuclides ¹⁰Be (half-life = 1.51 × 10⁶ a), ²⁶Al (7.05 × 10⁵ a) and ³⁶Cl (3.01 × 10⁵ a) in Lewis Cliff (LEW) 86360, an L-chondrite from the Lewis Cliff stranding area, East Antarctica. In addition, the concentrations and isotopic compositions of He, Ne and Ar were measured. The combined results yield a terrestrial age of 2.35 ± 0.15 Ma. Only one other stony meteorite with a similar terrestrial age (～2 Ma) is known from the Allan Hills stranding area (ALH 88019), whereas all previously dated stony meteorites from Antarctica are younger than 1 Ma. We argue that LEW 86360 spent most of its terrestrial residence time deep inside the ice, near the base of the glacier, where ice flow rates are much lower than at the surface. The terrestrial ages of LEW 86360 and ALH 88019 are consistent with existing hypotheses concerning the stability and persistence of the East Antarctic ice sheet.     

The profile and polarization of the coronal Lα line

We calculate the profile and polarization of the Lα line in the solar corona. Coronal temperature variation, solar wind and other non-thermal motions have been taken into account. Because of the relatively low atomic weight of hydrogen the profile of the Lα line is a sensitive indicator of the coronal temperature. The line polarization contains relatively little information except for strong magnetic fields (> 70 G).