1988 Compilation of Elemental Concentration Data for USGS Basalt BCR-1

Concentration data on up to 82 individual constituents in USGS Basalt BCR-1 have been collected from 1395 journal articles and technical reports. These data are summarized in consensus (mean) values with uncertainties expressed as ± one standard deviation. Mean values are also calculated as a function of analytical procedure and all raw data are given in the tables. Recommended values are proposed based upon data criteria used by NIST (National Institute of Standards and Technology, formerly the National Bureau of Standards or NBS).     

Complete chemical analyses of metamorphic hornblendes: implications for normalizations,calculated H2O activities,and thermobarometry

Twenty-two hornblendes separated from amphibolites and granulites of the Grenville Orogen of Ontario have been quantitatively analyzed for major and minor elements by electron microprobe, for FeO/Fe₂O₃ by wet chemistry, and for H₂O by manometric measurement as H₂. Hornblende formulae were calculated on the basis of 24O+OH+Cl+F. Most samples are magnesio-hornblendes, ferroan pargasitic hornblendes and ferroan hastingsitic hornblendes, with weight fractions of Fe³⁺/(Fe²⁺+Fe³⁺) ranging from 0.15 to 0.50. An oxy-amphibole component of 0–25 mol%, with an average value of 17 mol%, is obtained for these complete analyses. When compared with structural formulae determined solely from microprobe data, normalization based on 13=Si+Ti+Al+Fe+Mn+Mg cations provides the best approximation to hornblende formulae calculated from the complete analyses. Less satisfactory agreement is obtained from a normalization scheme based on 15=Si+Ti+Al+Fe+Mn+Mg+Ca, while worst agreement is obtained from normalization to 23 oxygens assuming all Fe is Fe²⁺. No normalization scheme based on microprobe data alone consistently replicates the measured FeO, Fe₂O₃, and H₂O; accurate determination of these values requires complete chemical analysies. Ionic solution models previously have been proposed to evaluate the activity of Ca₂Mg₅Si₈ O₂₂(OH)₂(a _Trem) in hornblende for use in equilibria that constrain the activity of H₂O (a _{H 2}O) in igneous and metamorphic rocks. Application of ionic models to typical hornblendes produces low a _Trem (usually<0.01), consequetly yielding extremely low a _{H 2}O. If an oxy-amphibole component is present, the calculated a _Trem and H₂O is further reduced. An oxy-amphibole component of 25% reduces the calculated H₂O activity and that of any hydroxyl-amphibole component by 50% below that calculated with simplified assumptions regarding X _OH in the hydroxyl site (i.e., X _OH=1, or X _OH=1–X _Cl–X _f). Thus, methods of amphibole normalizations appear to have a substantial effect on calculated amphibole and H₂O activites. Before quantitative hornblende thermobarometry can be calibrated and applied, the amounts of FeO, Fe₂O₃ and H₂O must be measured in order to fully characterize hornblende solid solutions.Contribution No. 478 from the Mineralogical Laboratory, University of Michigan     

地面对晴空大气热辐射结构的影响

本文利用1987年美国FIFE资料及1986年6月TIPMEX资料,并利用大气长、短波一维辐射传输数值模式,计算了晴空大气状态下地面辐射参数(地面热辐射温度、地表反照率等)对大气长波冷却率、短波加热率廓线的影响。结果表明,地球表面对大气边界层内的热辐射结构影响很大,特别是在高原地区这种影响尤其显著。     

GENERALISATION ET OPTIMALISATION DE LA METHODE DES DIFFERENCES FINIES POUR LA MODELISATION EN MAGNETO-TELLURIQUE (MT)*

After a brief discussion of MT modeling methods, we expose a particular application of finite elements that may be assimilated to a finite-difference method. The resulting linear equations obtained are similar to the transmission network equations for two-dimensional media. The introduction of resistivity discontinuities is more rigorous than in the usual finite-difference development. The consequence is an improved accuracy. We also present some conclusions about various problems encountered in modeling, such as the choice of network boundary conditions, linear system resolution and the final derivation of apparent resistivity. Application of successive over-relaxation is discussed and we detail rules for mesh design that control result accuracy and iterative convergence.     

Modeling in paleoceanography

The two last decades of research in paleoceanography are characterized by extensive data collection and by the development of numerous hypotheses based on these data. Both the nature of the thermohaline circulation and the nature of the surface circulation during past times are currently being debated. Physical models of the ocean circulation are beginning to play an important role in these debates. The models range from highly simplified mathematical representations intended to illustrate physical principles to three-dimensional time-dependent global models intended to simulate temperature, salinity and flow fields. At the very least such models can be applied to explore the limitations or appropriateness of various assumptions in paleoceanography. At the very best, paleoceanographic data may be used as a verification of simulations of past oceans.     

Héritage et sources des métaux d'après la géochimie isotopique du plomb

Résumé Les galènes et sulfoantimoniures de plomb des filons quartzeux, barytiques et fluorés du Haut-Allier (district de Brioude-Massiac) ont fait l'objet d'analyses isotopiques du plomb. Les résultats montrent l'existence de deux populations de plomb appartenant à chacune des deux phases minéralisatrices reconnues dans la région.La première population (18,108<²⁰⁶Pb/²⁰⁴Pb<18,181) est rapportée à la phase mésothermale permienne. Elle comprend les sulfosels précoces des filons antimonifères ainsi que la galène des filons plombo-stannifères. L'homogénéité isotopique confirme la liaison génétique existant entre ces différents types filoniens et leur appartenance à un même processus métallogénique. Le socle métamorphique régional apparaît comme la source possible du plomb.La relative dispersion des valeurs isotopiques de la seconde population (18,215<²⁰⁶Pb/²⁰⁴Pb<18,472), d'âge liasique, est corrélable avec la situation géographique et géologique des filons. Elle est due à deux phénomènes complémentaires: le lessivage d'un segment crustal comprenant le socle métamorphique avec une participation graduée du granite uranifère de la Margeride et la réassimilation partielle du plomb des filons permiens. Ce dernier phénomène d'héritage métallique se traduit au niveau des paragenèses par la formation de filons à sulfosels dominants.

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Lead isotope analyses are reported for galena and lead sulfosalts from quartz, barite and fluorite vein deposits from the Haut-Allier (Brioude-Massiac district). The data define two lead populations reflecting the two mineralization episodes in this region.The first population (18,108<²⁰⁶Pb/²⁰⁴Pb<18,181) is related to the Permian mesothermal episode. It includes early sulfosalts from antimony veins and galena from lead-stanniferous veins. The Pb isotopic homogeneity confirms the relationship between the different vein types and their formation by a single metallogenic process. The metamorphic basement is the potential source of lead.The second population includes quartz-barite and fluorite veins. It shows much more isotopic variation (18,215<²⁰⁶Pb/²⁰⁴Pb<18,472) correlating with the geographical and geological location of the veins. Because the veins have a contemporaneous age, the isotopic dispersion therefore depends on two complementary phenomena: the leaching of a large volume of crust, including metamorphic basement, with a progressive contribution of the uraniferous granite of Margeride; and the partial remobilization of lead from Permian veins. The latter inheritance phenomena result in the genesis of major lead-sulfosalt vein deposits.

     

Effects of temperature-dependent material properties and radioactive heat production on simple basin subsidence models

The effects of applying laboratory-derived material parameters to simple thermal basin subsidence models are examined. The temperature-dependent properties of thermal conductivity, specific heat and the coefficient of thermal expansion are considered, as well as conductivity contrasts between the crust and mantle and lithosphere-scale radiogenic heat production. The effects of conductivity and radioactivity are complementary, and can be predicted from the way in which they influence the initial and final steady-state geothermal gradient. A convex-up initial gradient, such as is generated by the conductivity and radioactivity functions and is also assumed to be the case based on independent evidence, will lead to more initial subsidence than in a simple constant-parameter model. The final subsidence will also be greater in the modified model, due to the fact that the stretching event will result in a lithospheric column which is intrinsically cooler than in the pre-deformation case. Because the coefficient of thermal expansion rises with increasing temperature, including its temperature dependence will result in a model with substantially less initial subsidence than one with a constant value. When these parameters are combined into a single model, the initial subsidence is approximately 15–20% less than in the constant-parameter model if radioactivity is not included, and 10% less if it is, while the final subsidence is about 5% greater without radioactivity and 7–9% greater with radioactivity included. Depending on the magnitude of extension, these effects can translate into differences of tens to hundreds of meters when compared to the constant-parameter model.     

Autoxidation of N(III), S(IV), and other Species in Frozen Solution – A Possible Pathway for Enhanced Chemical Transformation in Freezing Systems

The chemistry of glycolaldehyde (hydroxyacetaldehyde) relevant to the troposphere has been investigated using UV absorption spectrometry and FTIR absorption spectrometry in an environmental chamber. Quantitative UV absorption spectra have been obtained for the first time. The UV spectrum peaks at 277 nm with a maximum cross section of (5.5± 0.7)×10^–20 cm² molecule^–1. Studies of the ultraviolet photolysis of glycolaldehyde ( = 285 ± 25 nm) indicated that the overall quantum yield is > 0.5 in one bar of air, with the major products being CH₂OH and HCO radicals. Rate coefficients for the reactions of Cl atoms and OH radicals with glycolaldehyde have been determined to be (7.6± 1.5)×10^–11 and (1.1± 0.3)×10^–11 cm³ molecule^–1 s^–1, respectively, in good agreement with the only previous study. The lifetime of glycolaldehyde in the atmosphere is about 1.0 day for reaction with OH, and > 2.5 days for photolysis, although both wet and dry deposition should also be considered in future modeling studies.