Investigation of the Flow Structure in Step-Up Street Canyons—Mean Flow and Turbulence Statistics

A step-up street canyon is a characteristic urban element composed of two buildings in which the height of the upwind building ( $H_\mathrm{u}$ ) is less than the height of the downwind building ( $H_\mathrm{d}$ ). Here, the effect of canyon geometry on the flow structure in isolated step-up street canyons is investigated through isothermal wind-tunnel measurements. The measurements were acquired along the vertical symmetry plane of model buildings using two-dimensional particle image velocimetry (PIV) for normal approach flow. The building-height ratios considered were: $H_\mathrm{d}/ H_\mathrm{u} \approx 3$ , and $H_\mathrm{d}/ H_\mathrm{u} \approx 1.67$ . For each building-height ratio, the along-wind lengths (L) of the upwind and downwind buildings, and the street-canyon width (S) were kept constant, with $L \approx S$ . The cross-wind widths (W) of the upwind and downwind buildings were varied uniformly from $W/S \approx 1$ through $W/S \approx 4$ , in increments of $W/S \approx 1$ . The objective of the work was to characterize the changes in the flow structure in step-up canyons as a function of W/S, for fixed L, S, and $H_\mathrm{d}/H_\mathrm{u}$ values. The results indicate that the in-canyon flow structure does not vary significantly for $H_\mathrm{d}/H_\mathrm{u} \approx 3$ for the W/S values considered. Qualitatively, for $H_\mathrm{d}/H_\mathrm{u} \approx 3$ , the upwind building behaves as an obstacle in the upwind cavity of the downwind building. In contrast, the flow patterns observed for the $H_\mathrm{d}/H_\mathrm{u} \approx 1.67$ configurations are unique and counter-intuitive, and depend strongly on building width (W/S). For $W/S \approx 1$ and $W/S \approx 2$ , the effect of lateral flow into the canyon is so prominent that even the mean flow patterns are highly ambiguous. For $W/S \approx 3$ and 4, the flow along the vertical symmetry plane is more shielded from the lateral flow, and hence a stable counter-rotating vortex pair is observed in the canyon. In addition to these qualitative features, a quantitative analysis of the mean flow field and turbulence stress field is presented.     

Isolation of 12 microsatellite markers following a pyrosequencing procedure and cross-priming in two invasive cryptic species, Alexandrium catenella (group IV) and A. tamarense (group III) (Dinophyceae)

Alexandrium catenella (group IV) and Alexandrium tamarense (group III) (Dinophyceae) are two cryptic invasive phytoplankton species belonging to the A. tamarense species complex. Their worldwide spread is favored by the human activities, transportation and climate change. In order to describe their diversity in the Mediterranean Sea and understand their settlements and maintenances in this area, new microsatellite markers were developed based on Thau lagoon (France) samples of A. catenella and A. tamarense strains. In this study twelve new microsatellite markers are proposed. Five of these microsatellite markers show amplifications on A. tamarense and ten on A. catenella. Three of these 12 microsatellite markers allowed amplifications on both cryptic species. Finally, the haplotypic diversity ranged from 0.000 to 0.791 and 0.000 to 0.942 for A. catenella and A. tamarense respectively.     

地面对晴空大气热辐射结构的影响

本文利用1987年美国FIFE资料及1986年6月TIPMEX资料,并利用大气长、短波一维辐射传输数值模式,计算了晴空大气状态下地面辐射参数(地面热辐射温度、地表反照率等)对大气长波冷却率、短波加热率廓线的影响。结果表明,地球表面对大气边界层内的热辐射结构影响很大,特别是在高原地区这种影响尤其显著。     

ENSO anomalies over the Western United States: present and future patterns in regional climate simulations

Surface temperature, precipitation, specific humidity and wind anomalies associated with the warm and cold phases of ENSO simulated by WRF and HadRM are examined for the present and future decades. WRF is driven by ECHAM5 and CCSM3, respectively, and HadRM is driven by HadCM3. For the current decades, all simulations show some capability in resolving the observed warm-dry and cool-wet teleconnection patterns over the PNW and the Southwest U.S. for warm and cold ENSO. Differences in the regional simulations originate primarily from the respective driving fields. For the future decades, the warm-dry and cool-wet teleconnection patterns in association with ENSO are still represented in ECHAM5-WRF and HadRM. However, there are indications of changes in the ENSO teleconnection patterns for CCSM3-WRF in the future, with wet anomalies dominating in the PNW and the Southwest U.S. for both warm and cold ENSO, in contrast to the canonical patterns of precipitation anomalies. Interaction of anomalous wind flow with local terrain plays a critical role in the generation of anomalous precipitation over the western U.S. Anomalous dry conditions are always associated with anomalous airflow that runs parallel to local mountains and wet conditions with airflow that runs perpendicular to local mountains. Future changes in temperature and precipitation associated with the ENSO events in the regional simulations indicate varying responses depending on the variables examined as well as depending on the phase of ENSO.     

Global change and the intensification of agriculture in the tropics

Bridging understanding of local environmental change with regional and global patterns of land-use and land-cover change (LUCC) remains a key goal and challenge for our understanding of global environmental change. This meta-analysis attempts to bridge local and regional scales of LUCC by demonstrating the ways in which previously published case studies can be compared and used for a broader regional synthesis in the tropics. In addition to providing results from a meta-analysis, this paper suggests ways to make future case studies more widely comparable.     

Carbonyl products of the gas phase reaction of ozone with 1,1-disubstituted alkenes

Carbonyl products have been identified and their formation yields measured in experiments involving the gas phase reaction of ozone with 1,1-disubstituted alkenes at ambient T and p=1 atm. of air. Sufficient cyclohexane was added to scavenge the hydroxyl radical in order to minimize OH-alkene and OH-carbonyl reactions. Formation yields (carbonyl formed/ozone reacted) of primary carbonyls were close to the value of 1.0 that is consistent with the mechanism: O₃+R₁R₂C=CH₂ (HCHO+R₁R₂COO)+(1–)(R₁COR₂+H₂COO) where formaldehyde and the ketone R₁ COR₂ are the primary carbonyls and R₁R₂COO and H₂COO are the corresponding biradicals. Measured values of were 0.58–0.82 and indicate modest preferential formation of formaldehyde and the disubstituted biradical as compared to the ketone and the biradical H₂COO. Carbonyls other than the primary carbonyls were identified. Their formation is discussed in terms of subsequent reactions of the disubstituted biradicals R₁R₂COO. Similarities and differences between disubstituted and monosubstituted biradicals are outlined.     

Inverted-polarity electrical structures in thunderstorms in the Severe Thunderstorm Electrification and Precipitation Study (STEPS)

Balloon-borne electric field soundings and lightning mapping data have been analyzed for three of the storms that occurred in the Severe Thunderstorm Electrification and Precipitation Study field program in 2000 to determine if the storms had inverted-polarity electrical structures. The polarities of all or some of the vertically stacked charge regions in such storms are opposite to the polarities observed at comparable heights in normal storms. Analyses compared the charge structures inferred from electric field soundings in the storms with charges inferred from three-dimensional lightning mapping data. Charge structures were inferred from electric field profiles by combining the one-dimensional approximation of Gauss's law with additional information from three-dimensional patterns in the electric field vectors. The three different ways of inferring the charge structure in the storms were found to complement each other and to be consistent overall. Charge deposition by lightning possibly occurred and increased the charge complexity of one of the storms.Many of the cloud flashes in each case were inverted-polarity flashes. Two storms produced ground flash activity comprised predominantly of positive ground flashes. One storm, which was an isolated thunderstorm, produced inverted-polarity cloud flashes, but no flashes to ground. The positive and negative thunderstorm charge regions were found at altitudes where, respectively, negative and positive charge would be found in normal-polarity storms. Thus, we conclude that these storms had anomalous and inverted-polarity electrical structures. Collectively, these three cases (along with the limited cases in the refereed literature) provide additional evidence that thunderstorms can have inverted-polarity electrical structures.     

Autoxidation of N(III), S(IV), and other Species in Frozen Solution – A Possible Pathway for Enhanced Chemical Transformation in Freezing Systems

The chemistry of glycolaldehyde (hydroxyacetaldehyde) relevant to the troposphere has been investigated using UV absorption spectrometry and FTIR absorption spectrometry in an environmental chamber. Quantitative UV absorption spectra have been obtained for the first time. The UV spectrum peaks at 277 nm with a maximum cross section of (5.5± 0.7)×10^–20 cm² molecule^–1. Studies of the ultraviolet photolysis of glycolaldehyde ( = 285 ± 25 nm) indicated that the overall quantum yield is > 0.5 in one bar of air, with the major products being CH₂OH and HCO radicals. Rate coefficients for the reactions of Cl atoms and OH radicals with glycolaldehyde have been determined to be (7.6± 1.5)×10^–11 and (1.1± 0.3)×10^–11 cm³ molecule^–1 s^–1, respectively, in good agreement with the only previous study. The lifetime of glycolaldehyde in the atmosphere is about 1.0 day for reaction with OH, and > 2.5 days for photolysis, although both wet and dry deposition should also be considered in future modeling studies.     

Effects of mesoscale sea-surface temperature fronts on the marine atmospheric boundary layer

A numerical modelling study is presented focusing on the effects of mesoscale sea-surface temperature (SST) variability on surface fluxes and the marine atmospheric boundary-layer structure. A basic scenario is examined having two regions of SST anomaly with alternating warm/cold or cold/warm water regions. Conditions upstream from the anomaly region have SST values equal to the ambient atmosphere temperature, creating an upstream neutrally stratified boundary layer. Downstream from the anomaly region the SST is also set to the ambient atmosphere value. When the warm anomaly is upstream from the cold anomaly, the downstream boundary layer exhibits a more complex structure because of convective forcing and mixed layer deepening upstream from the cold anomaly. An internal boundary layer forms over the cold anomaly in this case, generating two distinct layers over the downstream region. When the cold anomaly is upstream from the warm anomaly, mixing over the warm anomaly quickly destroys the shallow cold layer, yielding a more uniform downstream boundary-layer vertical structure compared with the warm-to- cold case. Analysis of the momentum budget indicates that turbulent momentum flux divergence dominates the velocity field tendency, with pressure forcing accounting for only about 20% of the changes in momentum. Parameterization of surface fluxes and boundary-layer structure at these scales would be very difficult because of their dependence on subgrid-scale SST spatial order. Simulations of similar flow over smaller scale fronts (<5 km) suggest that small-scale SST variability might be parameterized in mesoscale models by relating the effective heat flux to the strength of the SST variance.     

Validating a rapid-update satellite precipitation analysis across telescoping space and time scales

In order to properly utilize remotely sensed precipitation estimates in hydrometeorological applications, knowledge of the accuracy of the estimates are needed. However, relatively few ground validation networks operate with the necessary spatial density and time-resolution required for validation of high-resolution precipitation products (HRPP) generated at fine space and time scales (e.g., hourly accumulations produced on a 0.25° spatial scale). In this article, we examine over-land validation statistics for an operationally designed, meteorological satellite-based global rainfall analysis that blends intermittent passive microwave-derived rainfall estimates aboard a variety of low Earth-orbiting satellite platforms with sub-hourly time sampling capabilities of visible and infrared imagers aboard operational geostationary platforms. The validation dataset is comprised of raingauge data collected from the dense, nearly homogeneous, 1-min reporting Automated Weather Station (network of the Korean Meteorological Administration during the June to August 2000 summer monsoon season. The space-time RMS error, mean bias, and correlation matrices were computed using various time windows for the gauge averaging, centered about the satellite observation time. For ±10 min time window, a correlation of 0.6 was achieved at 0.1° spatial scale by averaging more than 3 days; coarsening the spatial scale to 1.8° produced the same correlation by averaging over 1 h. Finer than approximately 24-h and 1° time and space scales, respectively, a rapid decay of the error statistics was obtained by trading-off either spatial or time resolution. Beyond a daily time scale, the blended estimates were nearly unbiased and with an RMS error of no worse than 1 mm day^?1.