Extraterrestrial amino acids and L‐enantiomeric excesses in the CM2 carbonaceous chondrites Aguas Zarcas and Murchison

The abundances, distributions, enantiomeric ratios, and carbon isotopic compositions of amino acids in two fragments of the Aguas Zarcas CM2 type carbonaceous chondrite fall and a fragment of the CM2 Murchison meteorite were determined via liquid chromatography time‐of‐flight mass spectrometry and gas chromatography isotope ratio mass spectrometry. A suite of two‐ to six‐carbon aliphatic primary amino acids was identified in the Aguas Zarcas and Murchison meteorites with abundances ranging from ~0.1 to 158 nmol/g. The high relative abundances of α‐amino acids found in these meteorites are consistent with a Strecker‐cyanohydrin synthesis on these meteorite parent bodies. Amino acid enantiomeric and carbon isotopic measurements in both fragments of the Aguas Zarcas meteorites indicate that both samples experienced some terrestrial protein amino acid contamination after their fall to Earth. In contrast, similar measurements of alanine in Murchison revealed that this common protein amino acid was both racemic (D ≈ L) and heavily enriched in ¹³C, indicating no measurable terrestrial alanine contamination of this meteorite. Carbon isotope measurements of two rare non‐proteinogenic amino acids in the Aguas Zarcas and Murchison meteorites, α‐aminoisobutyric acid and D‐ and L‐isovaline, also fall well outside the typical terrestrial range, confirming they are extraterrestrial in origin. The detections of non‐terrestrial L‐isovaline excesses of ~10–15% in both the Aguas Zarcas and Murchison meteorites, and non‐terrestrial L‐glutamic acid excesses in Murchison of ~16–40% are consistent with preferential enrichment of circularly polarized light generated L‐amino acid excesses of conglomerate enantiopure crystals during parent body aqueous alteration and provide evidence of an early solar system formation bias toward L‐amino acids prior to the origin of life.     

Effect of stiffness variability on the response of isolated structures

Results are presented of an investigation, the objective of which was to determine the relationship between the stiffness variability of the bearings of an isolation system and the response variability of the structure. The system is modeled as a rigid, rectangular structure that is free to translate and rotate. The isolation system consists of N isolation bearings arranged in a rectangular pattern, each with a stiffness k_i that is an independent, normally distributed, random variable. Response spectrum analysis is used to obtain the analytical solution for the structure response. Approximate closed‐form expressions are obtained for the variance of the centreline displacement, rotation, corner displacement and base shear, that are in terms of the variability of the isolator stiffness, aspect ratio of the structure, and the number and layout of isolation bearings. Results show that the standard deviation of the centreline displacement and base shear decrease with increasing number of isolation bearings, and are independent of the aspect ratio and layout of isolators, and in all cases are less than 1/4 the standard deviation of the isolator stiffness. The standard deviation of the corner displacement is a function of all of the system parameters, and is bounded below by the standard deviation of the centreline displacement and above by the standard deviation of a bar aligned perpendicular to the direction of ground motion with m isolation bearings distributed along the length. The approximate expressions are shown to be in good agreement with the results of Monte Carlo simulations. The results should be of use to designers of isolated structures and manufacturers of isolation systems, in assessing the significance of stiffness variability on the response of the isolated structure. Copyright © 2000 John Wiley & Sons, Ltd.     

Sonication of bacteria, phytoplankton and zooplankton: Application to treatment of ballast water

We investigated the effect of high power ultrasound, at a frequency of 19 kHz, on the survival of bacteria, phytoplankton and zooplankton, in order to obtain estimates of effective exposure times and energy densities that could be applied to design of ultrasonic treatment systems for ballast water. Efficacy of ultrasonic treatment varied with the size of the test organism. Zooplankton required only 3-9s of exposure time and 6-19 J/mL of ultrasonic energy to realize a 90% reduction in survival. In contrast, decimal reduction times for bacteria and phytoplankton ranged from 1 to 22 min, and decimal reduction energy densities from 31 to 1240 J/mL. Our results suggest that stand-alone ultrasonic treatment systems for ballast water, operating at 19-20 kHz, may be effective for planktonic organisms >100 microm in size, but smaller planktonic organisms such as phytoplankton and bacteria will require treatment by an additional or alternative system.     

Fluid-Rock Interaction in the Granulites of Madagascar and Lithospheric-Scale Transfer of Fluids

The nature of synmetamorphic fluids and their flow is examined in the granulitic lower crust of Madagascar, part of a Precambrian crustal-scale network of vertical ductile shear zones. Based on three independent data sets - field and satellite mapping, C-, O- and H-isotope geochemistry and gravimetry - this crust is divided into three zones: outside of shear zones, minor shear zones (<140 km long and 7 km wide), and major shear zones (>350 km long and 20–35 km wide). The major shear zones are rooted in and are controlled by the mantle. They tapped mantle-derived CO₂ with carbon fluxes of the same order of magnitude as oceanic ridge degassing. One major shear zone shows abundant phlogopite-diopside-apatite-calcite mineralizations (a well known paragenesis in mantle metasomatism) due to mantle-fluid infiltration and their interaction with the crust. Carbonatitic magmas possibly collected in the major shear zones at the base of the crust and may be the source for CO₂ upwellings as well as other metasomatic agents. Small-scale minor shear zones were controlled by crustal deformation processes and focused crustally-derived H₂O-rich fluids. Pervasive fluid circulation was restricted to the vicinity (< 100 m) of synmetamorphic plutons. Fluid absent conditions dominate everywhere else. Mantle-CO₂ flushing is not required for granulite genesis but is a consequence of the high associated heat flux. Fluid transfer at the mantle/crust interface is controlled by the tectonic setting and the associated geothermal gradient. The C- and O- isotope systematics of metamorphosed carbonates sampled on a regional scale within a known petrological and structural framework are shown to be of great help to identify the distribution of major fluid-rock interaction processes associated with plate tectonics.     

Evolution and petroleum geology of Amlia and Amukta intra-arc summit basins, Aleutian Ridge

Amlia and Amukta Basins are the largest of many intra-arc basins formed in late Cenozoic time along the crest of the Aleutian Arc. Both basins are grabens filled with 2–5 km of arc-derived sediment. A complex system of normal faults deformed the basinal strata. Although initial deposits of late Micocene age may be non-marine in origin, by early Pliocene time, most of the basinfill consisted of pelagic and hemipelagic debris and terrigenous turbidite deposits derived from wavebase and subaerial erosion of the arc's crestal areas. Late Cenozoic volcanism along the arc commenced during or shortly after initial subsidence and greatly contributed to active deposition in Amlia and Amukta Basins.Two groups of normal faults occur: major boundary faults common to both basins and ‘intra-basin’ faults that arise primarily from arc-parallel extension of the arc. The most significant boundary fault, Amlia-Amukta fault, is a south-dipping growth fault striking parallel to the trend of the arc. Displacement across this fault forms a large half-graben that is separated into the two depocentres of Amlia and Amukta Basins by the formation of a late Cenozoic volcanic centre, Seguam Island. Faults of the second group reflect regional deformation of the arc and offset the basement floor as well as the overlying basinal section. Intra-basin faults in Amlia Basin are predominantly aligned normal to the trend of the arc, thereby indicating arc-parallel extension. Those in Amukta basin are aligned in multiple orientations and probably indicate a more complex mechanism of faulting. Displacement across intra-basin faults is attributed to tectonic subsidence of the massif, aided by depositional loading within the basins. In addition, most intra-basin faults are listric and are associated with high growth rates.Although, the hydrocarbon potential of Amlia and Amukta Basins is difficult to assess based on existing data, regional considerations imply that an adequate thermal history conducive to hydrocarbon generation has prevailed during the past 6-5 my. The possibility for source rocks existing in the lower sections of the basins is suggested by exposures of middle and upper Miocene carbonaceous mudstone on nearby Atka Island and the implication that euxinic conditions may have prevailed during the initial formation of the basins. Large structures have evolved to trap migrating hydrocarbons, but questions remain concerning the preservation of primary porosity in a sedimentary section rich in reactive volcaniclastic debris.     

Simulating flood events at the Twin Ports of Duluth-Superior using a linked hydrologic-hydrodynamic framework

Ocean Dynamics - Generally, ports in the North American Great Lakes are not supported with navigational guidance (water level, water temperature, currents, ice) by NOAA’s Great Lakes...     

Field evidence for the influence of weathering on rock erodibility and channel form in bedrock rivers

Erosion processes in bedrock‐floored rivers shape channel cross‐sectional geometry and the broader landscape. However, the influence of weathering on channel slope and geometry is not well understood. Weathering can produce variation in rock erodibility within channel cross‐sections. Recent numerical modeling results suggest that weathering may preferentially weaken rock on channel banks relative to the thalweg, strongly influencing channel form. Here, we present the first quantitative field study of differential weathering across channel cross‐sections. We hypothesize that average cross‐section erosion rate controls the magnitude of this contrast in weathering between the banks and the thalweg. Erosion rate, in turn, is moderated by the extent to which weathering processes increase bedrock erodibility. We test these hypotheses on tributaries to the Potomac River, Virginia, with inferred erosion rates from ~0.1 m/kyr to >0.8 m/kyr, with higher rates in knickpoints spawned by the migratory Great Falls knickzone. We selected nine channel cross‐sections on three tributaries spanning the full range of erosion rates, and at multiple flow heights we measured (1) rock compressive strength using a Schmidt hammer, (2) rock surface roughness using a contour gage combined with automated photograph analysis, and (3) crack density (crack length/area) at three cross‐sections on one channel. All cross‐sections showed significant (p < 0.01 for strength, p < 0.05 for roughness) increases in weathering by at least one metric with height above the thalweg. These results, assuming that the weathered state of rock is a proxy for erodibility, indicate that rock erodibility varies inversely with bedrock inundation frequency. Differences in weathering between the thalweg and the channel margins tend to decrease as inferred erosion rates increase, leading to variations in channel form related to the interplay of weathering and erosion rate. This observation is consistent with numerical modeling that predicts a strong influence of weathering‐related erodibility on channel morphology. Copyright © 2017 John Wiley & Sons, Ltd.     

Dynamics and fluxes of organic carbon and nitrogen in two Guiana Shield river basins impacted by deforestation and mining activities

Deforestation and mining activities have proven to be very damaging to rivers because these activities disturb the environmental characteristics of rivers. Thus, the concentrations of dissolved organic carbon (DOC), particulate organic carbon (POC), particulate nitrogen (PN), and Chlorophyll‐a (Chl‐a) were measured monthly during 2 hydrological years in the Maroni and Oyapock Rivers to assess the dynamics and fluxes of organic carbon and nitrogen in these 2 Guiana Shield basins, which have been strongly (Maroni) and weakly (Oyapock) impacted by deforestation and mining activities. The 2‐year time series show that DOC, POC, PN, and Chl‐a concentrations vary seasonally with discharge in both rivers, indicating a hydrologically dominated control. Temporal patterns of DOC, POC, and PN indicate that these variables show maximum concentrations in rising waters due to the yield of organic matter and nitrogen accumulated in soils, which are incorporated into the rivers during rainfall. However, the Chl‐a concentrations were at a maximum during low‐water stages. The C/N and C/Chl‐a ratios also showed a seasonal trend, with lower values during the low water periods due to an increase in algal biomass. During high water, the POC in both rivers is the result of terrestrial organic matter, whereas during low‐water autochthonous organic matter can reach up to 34% of the POC. The mean annual fluxes of TOC and PN were higher (4.56 × 10⁵ tonC year^?1 and 1.77 × 10⁴ tonN year^?1, respectively) in the Maroni River than those (1.84 × 10⁵ tonC year^?1 and 0.54 × 10⁴ tonN year^?1, respectively) in the Oyapock River. However, the specific fluxes of DOC, POC, and PN from both basins were nearly the same. Although gold mining activities are performed in both basins, there is no conclusive evidence regarding the impact of these activities on the dynamics of organic matter and particulate nitrogen in the Maroni and Oyapock Rivers.     

Three‐dimensional receiver deghosting of seismic streamer data using L1 inversion and redundant extended radon dictionary

In this paper, we propose a novel three‐dimensional receiver deghosting algorithm that is capable of deghosting both horizontal and slanted streamer data in a theoretically consistent manner. Our algorithm honours wave propagation phenomena in a true three‐dimensional sense and frames the three‐dimensional receiver deghosting problem as a Lasso problem. The ultimate goal is to minimise the mismatch between the actual measurements and the simulated wavefield with an L1 constraint applied in the extended Radon space to handle the underdetermined nature of this problem. We successfully demonstrate our algorithm on a modified three‐dimensional EAGE/SEG Overthrust model and a Red Sea marine dataset.     

Modeling the ice-attenuated waves in the Great Lakes

Ocean Dynamics - A partly coupled wave-ice model with the ability to resolve ice-induced attenuation on waves was developed using the Finite-Volume Community Ocean Model (FVCOM) framework and...