Phosphate in Angra dos Reis: Structure and composition of the Ca3(PO4)2 minerals

Extraterrestrial calcium phosphates (“whitlockites”) have the anhydrous β-Ca₃(PO₄)₂ structure, which is different from that of hydrous terrestrial whitlockite. This has been confirmed by X-ray refinement of the structure of a phosphate from the achondrite Angra dos Reis. In the β-Ca₃(PO₄)₂ structure, there is one crystallographic site, Ca(IIA), which is half-occupied by calcium, and which seems to have an energetically unfavorable configuration; natural phosphates with this configuration (including Angra dos Reis) have composition Ca₁₉(Mg,Fe)₂(PO₄)₁₄. Stability of the structure is probably increased by substitution of Na for Ca in Ca(IIA) giving composition Ca₁₈ (Mg,Fe)₂Na₂(PO₄)₁₄, which occurs in chondrites; by vacancy of Ca(IIA), with rare earths and yttrium substituting for calcium in other sites for charge balance, giving composition Ca₁₆(Y,RE)₂(Mg,Fe)₂(PO₄)₁₄, found in lunar rocks; or by replacing Ca with hydrogen, giving composition Ca₁₈(Mg,Fe)₂H₂(PO₄)₁₄, which is terrestrial whitlockite. Lack of the favorable substitutions of Na, (Y, RE) or H in Angra dos Reis phosphate implies that these elements were relatively scarce in its environment of formation.     

Regional climate model projections for the State of Washington

Global climate models do not have sufficient spatial resolution to represent the atmospheric and land surface processes that determine the unique regional climate of the State of Washington. Regional climate models explicitly simulate the interactions between the large-scale weather patterns simulated by a global model and the local terrain. We have performed two 100-year regional climate simulations using the Weather Research and Forecasting (WRF) model developed at the National Center for Atmospheric Research (NCAR). One simulation is forced by the NCAR Community Climate System Model version 3 (CCSM3) and the second is forced by a simulation of the Max Plank Institute, Hamburg, global model (ECHAM5). The mesoscale simulations produce regional changes in snow cover, cloudiness, and circulation patterns associated with interactions between the large-scale climate change and the regional topography and land-water contrasts. These changes substantially alter the temperature and precipitation trends over the region relative to the global model result or statistical downscaling. To illustrate this effect, we analyze the changes from the current climate (1970–1999) to the mid twenty-first century (2030–2059). Changes in seasonal-mean temperature, precipitation, and snowpack are presented. Several climatological indices of extreme daily weather are also presented: precipitation intensity, fraction of precipitation occurring in extreme daily events, heat wave frequency, growing season length, and frequency of warm nights. Despite somewhat different changes in seasonal precipitation and temperature from the two regional simulations, consistent results for changes in snowpack and extreme precipitation are found in both simulations.     

Preparing for climate change in Washington State

Climate change is expected to bring potentially significant changes to Washington State’s natural, institutional, cultural, and economic landscape. Addressing climate change impacts will require a sustained commitment to integrating climate information into the day-to-day governance and management of infrastructure, programs, and services that may be affected by climate change. This paper discusses fundamental concepts for planning for climate change and identifies options for adapting to the climate impacts evaluated in the Washington Climate Change Impacts Assessment. Additionally, the paper highlights potential avenues for increasing flexibility in the policies and regulations used to govern human and natural systems in Washington.     

Water Resources Implications of Global Warming: A U.S. Regional Perspective

The implications of global warming for the performance of six U.S. water resource systems are evaluated. The six case study sites represent a range of geographic and hydrologic, as well as institutional and social settings. Large, multi-reservoir systems (Columbia River, Missouri River, Apalachicola-Chatahoochee-Flint (ACF) Rivers), small, one or two reservoir systems (Tacoma and Boston) and medium size systems (Savannah River) are represented. The river basins range from mountainous to low relief and semi-humid to semi-arid, and the system operational purposes range from predominantly municipal to broadly multi-purpose. The studies inferred, using a chain of climate downscaling, hydrologic and water resources systems models, the sensitivity of six water resources systems to changes in precipitation, temperature and solar radiation. The climate change scenarios used in this study are based on results from transient climate change experiments performed with coupled ocean-atmosphere General Circulation Models (GCMs) for the 1995 Intergovernmental Panel on Climate Change (IPCC) assessment. An earlier doubled-CO₂ scenario from one of the GCMs was also used in the evaluation. The GCM scenarios were transferred to the local level using a simple downscaling approach that scales local weather variables by fixed monthly ratios (for precipitation) and fixed monthly shifts (for temperature). For those river basins where snow plays an important role in the current climate hydrology (Tacoma, Columbia, Missouri and, to a lesser extent, Boston) changes in temperature result in important changes in seasonal streamflow hydrographs. In these systems, spring snowmelt peaks are reduced and winter flows increase, on average. Changes in precipitation are generally reflected in the annual total runoff volumes more than in the seasonal shape of the hydrographs. In the Savannah and ACF systems, where snow plays a minor hydrological role, changes in hydrological response are linked more directly to temperature and precipitation changes. Effects on system performance varied from system to system, from GCM to GCM, and for each system operating objective (such as hydropower production, municipal and industrial supply, flood control, recreation, navigation and instream flow protection). Effects were generally smaller for the transient scenarios than for the doubled CO₂ scenario. In terms of streamflow, one of the transient scenarios tended to have increases at most sites, while another tended to have decreases at most sites. The third showed no general consistency over the six sites. Generally, the water resource system performance effects were determined by the hydrologic changes and the amount of buffering provided by the system's storage capacity. The effects of demand growth and other plausible future operational considerations were evaluated as well. For most sites, the effects of these non-climatic effects on future system performance would about equal or exceed the effects of climate change over system planning horizons.     

Investigation of the Flow Structure in Step-Up Street Canyons—Mean Flow and Turbulence Statistics

A step-up street canyon is a characteristic urban element composed of two buildings in which the height of the upwind building ( $H_\mathrm{u}$ ) is less than the height of the downwind building ( $H_\mathrm{d}$ ). Here, the effect of canyon geometry on the flow structure in isolated step-up street canyons is investigated through isothermal wind-tunnel measurements. The measurements were acquired along the vertical symmetry plane of model buildings using two-dimensional particle image velocimetry (PIV) for normal approach flow. The building-height ratios considered were: $H_\mathrm{d}/ H_\mathrm{u} \approx 3$ , and $H_\mathrm{d}/ H_\mathrm{u} \approx 1.67$ . For each building-height ratio, the along-wind lengths (L) of the upwind and downwind buildings, and the street-canyon width (S) were kept constant, with $L \approx S$ . The cross-wind widths (W) of the upwind and downwind buildings were varied uniformly from $W/S \approx 1$ through $W/S \approx 4$ , in increments of $W/S \approx 1$ . The objective of the work was to characterize the changes in the flow structure in step-up canyons as a function of W/S, for fixed L, S, and $H_\mathrm{d}/H_\mathrm{u}$ values. The results indicate that the in-canyon flow structure does not vary significantly for $H_\mathrm{d}/H_\mathrm{u} \approx 3$ for the W/S values considered. Qualitatively, for $H_\mathrm{d}/H_\mathrm{u} \approx 3$ , the upwind building behaves as an obstacle in the upwind cavity of the downwind building. In contrast, the flow patterns observed for the $H_\mathrm{d}/H_\mathrm{u} \approx 1.67$ configurations are unique and counter-intuitive, and depend strongly on building width (W/S). For $W/S \approx 1$ and $W/S \approx 2$ , the effect of lateral flow into the canyon is so prominent that even the mean flow patterns are highly ambiguous. For $W/S \approx 3$ and 4, the flow along the vertical symmetry plane is more shielded from the lateral flow, and hence a stable counter-rotating vortex pair is observed in the canyon. In addition to these qualitative features, a quantitative analysis of the mean flow field and turbulence stress field is presented.     

Isolation of 12 microsatellite markers following a pyrosequencing procedure and cross-priming in two invasive cryptic species, Alexandrium catenella (group IV) and A. tamarense (group III) (Dinophyceae)

Alexandrium catenella (group IV) and Alexandrium tamarense (group III) (Dinophyceae) are two cryptic invasive phytoplankton species belonging to the A. tamarense species complex. Their worldwide spread is favored by the human activities, transportation and climate change. In order to describe their diversity in the Mediterranean Sea and understand their settlements and maintenances in this area, new microsatellite markers were developed based on Thau lagoon (France) samples of A. catenella and A. tamarense strains. In this study twelve new microsatellite markers are proposed. Five of these microsatellite markers show amplifications on A. tamarense and ten on A. catenella. Three of these 12 microsatellite markers allowed amplifications on both cryptic species. Finally, the haplotypic diversity ranged from 0.000 to 0.791 and 0.000 to 0.942 for A. catenella and A. tamarense respectively.     

Inverted-polarity electrical structures in thunderstorms in the Severe Thunderstorm Electrification and Precipitation Study (STEPS)

Balloon-borne electric field soundings and lightning mapping data have been analyzed for three of the storms that occurred in the Severe Thunderstorm Electrification and Precipitation Study field program in 2000 to determine if the storms had inverted-polarity electrical structures. The polarities of all or some of the vertically stacked charge regions in such storms are opposite to the polarities observed at comparable heights in normal storms. Analyses compared the charge structures inferred from electric field soundings in the storms with charges inferred from three-dimensional lightning mapping data. Charge structures were inferred from electric field profiles by combining the one-dimensional approximation of Gauss's law with additional information from three-dimensional patterns in the electric field vectors. The three different ways of inferring the charge structure in the storms were found to complement each other and to be consistent overall. Charge deposition by lightning possibly occurred and increased the charge complexity of one of the storms.Many of the cloud flashes in each case were inverted-polarity flashes. Two storms produced ground flash activity comprised predominantly of positive ground flashes. One storm, which was an isolated thunderstorm, produced inverted-polarity cloud flashes, but no flashes to ground. The positive and negative thunderstorm charge regions were found at altitudes where, respectively, negative and positive charge would be found in normal-polarity storms. Thus, we conclude that these storms had anomalous and inverted-polarity electrical structures. Collectively, these three cases (along with the limited cases in the refereed literature) provide additional evidence that thunderstorms can have inverted-polarity electrical structures.     

Transnational linkages and the spillover of environment-efficiency into developing countries

Arguments about the “positive” influence of growing transnational linkages have typically focused on their role in diffusing environmentally superior innovations which help to raise countries’ environment-efficiency. The present article empirically tests these claims by examining whether developing countries’ linkages with more CO₂- and SO₂-efficient economies contribute to domestic improvements in CO₂- and SO₂-efficiency. Our large-N, statistical findings caution against some of the efficiency-oriented optimism voiced by supporters of globalization. Although imports ties with more pollution-efficient countries are found to spillover into improved domestic CO₂- and SO₂-efficiency, neither transnational linkages via exports, inward foreign direct investment (FDI) nor telephone calls appear to have any influence on domestic pollution-efficiency.     

On the Importance of High-Resolution in Large-Scale Ocean Models

Eddying global ocean models are now routinely used for ocean prediction, and the value-added of a better representation of the observed ocean variability and western boundary currents at that resolution is currently being evaluated in climate models. This overview article begins with a brief summary of the impact on ocean model biases of resolving eddies in several global ocean–sea ice numerical simulations. Then, a series of North and Equatorial Atlantic configurations are used to show that an increase of the horizontal resolution from eddy-resolving to submesoscale-enabled together with the inclusion of high-resolution bathymetry and tides significantly improve the models' abilities to represent the observed ocean variability and western boundary currents. However, the computational cost of these simulations is extremely large, and for these simulations to become routine, close collaborations with computer scientists are essential to ensure that numerical codes can take full advantage of the latest computing architecture.     

Mean and Turbulent Flow Statistics in a Trellised Agricultural Canopy

Flow physics is investigated in a two-dimensional trellised agricultural canopy to examine that architecture’s unique signature on turbulent transport. Analysis of meteorological data from an Oregon vineyard demonstrates that the canopy strongly influences the flow by channelling the mean flow into the vine-row direction regardless of the above-canopy wind direction. Additionally, other flow statistics in the canopy sub-layer show a dependance on the difference between the above-canopy wind direction and the vine-row direction. This includes an increase in the canopy displacement height and a decrease in the canopy-top shear length scale as the above-canopy flow rotates from row-parallel towards row-orthogonal. Distinct wind-direction-based variations are also observed in the components of the stress tensor, turbulent kinetic energy budget, and the energy spectra. Although spectral results suggest that sonic anemometry is insufficient for resolving all of the important scales of motion within the canopy, the energy spectra peaks still exhibit dependencies on the canopy and the wind direction. These variations demonstrate that the trellised-canopy’s effect on the flow during periods when the flow is row-aligned is similar to that seen by sparse canopies, and during periods when the flow is row-orthogonal, the effect is similar to that seen by dense canopies.