A mineral magnetic and scaled-chrysophyte paleolimnological study of two northeastern Pennsylvania lakes: records of fly ash deposition, land-use change, and paleorainfall variation

A combined mineral magnetic and scaled chrysophyte study of lake sediments from Lake Lacawac and Lake Giles in northeastern Pennsylvania was conducted to determine the effects of land-use and sediment source changes on the variation of pH, conductivity, and alkalinity inferred from biotic changes. Ten 30–40 cm long gravity cores were collected from Lake Lacawac and three from Lake Giles. Isothermal remanent magnetizations (IRMs) were given to the lake sediments in a 1.3 T magnetic field to measure magnetic mineral concentration variations. IRM acquisition experiments were conducted to identify magnetic mineralogy. The bedrock, soils and a peat bog on the shores of Lake Lacawac were also sampled for magnetic analysis to determine possible lake sediment sources. The top 10 cm of sediment collected from Lakes Lacawac and Giles was two to four times more magnetic than deeper sediment. ²¹⁰Pb dating suggests that this intensity increase commenced circa 1900. SEM images of magnetic extracts from the highly magnetic sediments indicates the presence of magnetic fly ash microspheres from fossil fuel burning electric power generation plants. The similarity in magnetic coercivity in the top 8 cm lake sediments and in the peat bog supports an atmospheric source for some of the magnetic minerals in the youngest lake sediments. The highly magnetic sediments also contain an antiferromagnetic mineral in two cores closest to Lake Lacawacs southeastern shore. This magnetic mineral is only present deep in the soil profile and would suggest erosion and significant land-use changes in the Lacawac watershed as another cause for the high magnetic intensities (concentrations) in the top 10 cm of the lake sediments. The most significant changes in the scaled chrysophyte flora occurred immediately above the 10 cm level and were used to infer a doubling of the specific conductivity between circa 1910 and 1929. These variations also support land-use changes in the Lacawac catchment at this time. A similar shift in the scaled chrysophte flora was not observed in the top of Lake Giles, however, distinct changes were found in the deeper sections of the core coupled with a smaller peak in magnetic concentration. Fourier analysis of the ²¹⁰Pb-dated lake sediment magnetics indicates the presence of a 50 year period, low amplitude variation in the Lake Lacawac, Lake Giles, and Lake Waynewood (Lott et al., 1994) magnetic concentration records. After removal of the land-use/fly ash magnetic concentration peak by Gaussian filtering, the 50 year variation correlates strongly from lake to lake even though the lakes are in different watersheds separated by up to 30 km. When this magnetic variation is compared with Gaussian-filtered rainfall variations observed in New York City and Philadelphia over the past 120–250 years there is a strong correlation suggesting that magnetic concentration variations can record regional rainfall variations with an approximately 50 year period. This result indicates that magnetics could be used to document regional variations in climatic change.     

On azimuthal eigenwavenumbers associated with Laplace's tidal equations

Laplace's tidal equations for the case of an ocean of constant depth bounded by meridians were considered by two authors at a specific frequency as an eigenvalue problem in the azimuthal wavenumber. A finite spectrum of eigenwavenumbers was found. That eigenvalue problem is re-examined by means of asymptotic techniques and numerical integration of the governing equation of the problem. At low frequencies a formula connecting the frequency and the number of eigensolutions is established. It is shown that at a given frequency the spectrum of eigenwavenumbers is wider than that reported, but (for this type of solution) the meridional boundary conditions are satisfied approximately only for the case of very low frequencies.     

Insights into syndepositional fault movement in a foreland basin; trends in seismites of the Upper Cretaceous,Wahweap Formation,Kaiparowits Basin,Utah, USA

The Upper Cretaceous Wahweap Formation accumulated in the active Cordilleran foreland basin of Utah. Soft‐sediment deformation structures are abundant in the capping sandstone member of the Wahweap Formation. By comparing with well‐established criteria, a seismogenic origin was determined for the majority of structures, which places these soft‐sediment deformation features in a class of sedimentary features referred to as seismites. A systematic study of the seismite trends included their vertical and horizontal distribution and a semi‐quantitative intensity analysis using a scale from 1 to 5 that is based on magnitude, sedimentary structure type, and the predominance of inferred process of hydroplastic deformation, liquefaction or fluidization. In addition, orientations of soft‐sediment fold axes were recorded. Construction of a northwest‐to‐southeast stratigraphic and seismite intensity cross‐section demonstrates: (1) reduction in stratigraphic thickness and percentage of conglomerates to the southeast, (2) the presence of lower seismite, middle nonseismite, and upper seismite zones within the capping sandstone (permitting subdivision of the capping sandstone member), and (3) elimination of the nonseismite zone and amalgamation of the lower and upper seismite zones to the southeast. Regional isoseismal contour maps generated from the semi‐quantitative analysis indicate a decrease in overall intensity from northwest to southeast in the upper and lower seismic zones and in sandstone within 5 m stratigraphically of the contact between the upper and capping sandstone members. In addition, cumulative seismite fold orientations support a west–northwest direction towards regional epicentres. Isoseismal maps are used to distinguish the effects of intrabasinal normal faulting from those of regional orogenic thrusting. Thus, this study demonstrates the utility of mapping seismites to separate the importance of regional vs. local tectonic activity influencing foreland basin sedimentation by identifying patterns that delineate palaeoepicentres associated with specific local intrabasinal normal faults vs. regional trends in soft‐sediment deformation related to Sevier belt earthquakes.     

Geochemical constraints on the Palaeocene–Miocene evolution of eastern Azerbaijan,with implications for the South Caspian basin and eastern Paratethys

Fine‐grained Palaeogene–early Neogene strata of the South Caspian basin, specifically the Oligocene–Lower Miocene Maikop Series, are responsible for the bulk of hydrocarbon generation in the region. Despite the magnitude of oil and gas currently attributed to the source interval offshore, geochemical evaluation of 376 outcrop samples from the northern edge of the Kura basin (onshore eastern Azerbaijan) indicates that depositional conditions in these proximal strata along the basin margins were dominantly oxic to mildly suboxic/anoxic throughout three major depositional stages: the Palaeocene–Eocene, Oligocene–early Middle Miocene and late Middle–Late Miocene. Palaeocene–Eocene samples have low average total organic carbon (TOC) values (0.3%), with higher total inorganic carbon (TIC) values (average=2.6%), extremely low sulphur content (0.2%) and relatively high detrital input as indicated by Fe/Al and Ti/Al ratios. C–S–Fe associations, along with relatively lower concentrations of redox‐sensitive trace elements (e.g. V, Ni, Mo, U) indicate dominantly oxic environments of deposition during much of the Palaeocene–Eocene. A pronounced geochemical shift occurred near the Eocene–Oligocene boundary, and continued through the Early Miocene. Specifically, this interval is characterized by a distinct increase in TOC (ranging from 0.1 to 6.3% with an average of 1.5%), C–S–Fe associations that reveal an abrupt relative increase of carbon and sulphur with respect to iron‐dominated Palaeocene–Eocene samples, and higher concentrations of redox‐sensitive trace metals. These changes suggest that a shift away from unrestricted marine conditions and towards more variable salinity conditions occurred coincident with the initial collision of the Arabian plate and partial closure of the Paratethys ocean. Despite periodic basin restriction, the majority of Upper Eocene–Lower Miocene strata in the northern Kura basin record oxic to slightly dysoxic conditions.     

Spatial Pair-Copula Modeling of Grade in Ore Bodies: A Case Study

A real-world mining application of pair-copulas is presented to model the spatial distribution of metal grade in an ore body. Inaccurate estimation of metal grade in an ore reserve can lead to failure of a mining project. Conventional kriged models are the most commonly used models for estimating grade and other spatial variables. However, kriged models use the variogram or covariance function, which produces a single average value to represent the spatial dependence for a given distance. Kriged models also assume linear spatial dependence. In the application, spatial pair-copulas are used to appropriately model the non-linear spatial dependence present in the data. The spatial pair-copula model is adopted over other copula-based spatial models since it is better able to capture complex spatial dependence structures. The performance of the pair-copula model is shown to be favorable compared to a conventional lognormal kriged model.     

CHARACTERIZATION OF THE EFFECT OF PEAK SHIFTS ON THE PERFORMANCE OF THE KALMAN FILTER IN MULTICOMPONENT ANALYSES

The effect of peak shifts on the performance of a Kalman filter multicomponent analysis algorithm hasbeen investigated.A series of Gaussian test systems were employed to characterize the concentrationestimation errors and the morphology of the on-line residuals(the innovations sequence).Both forwardand reverse filters were used in the generation of the innovations sequences.It was found that thedifference between the forward and reverse innovations sequences gave an accurate indication of thedirection and magnitude of the peak shift.A series of overlapped two-component systems were alsoinvestigated.Again,a correlation between the difference innovations and the degree of the responseshift was observed.The behavior of the Katman filter in fitting the shifted fluorescence emissionspectrum of benzo[a]pyrene was also examined.The response for henzo[a]pyrene in cyclohexanesolution was compared to that obtained on the surface of a reversed phase thin layer chromatographyplate.A red shift of 4 nm was detected for the surface spectrum by observing the difference innovationssequence.This approach holds promise for correction of response shifts in multicomponent systems.     

Assessing the applicability of OpenStreetMap data to assist the validation of land use/land cover maps

The validation of land use/land cover (LULC) maps is usually performed using a reference database consisting of a sample of points or regions to which the ‘real’ class is assigned. This assignment is usually performed by specialists using photointerpretation (PI) of high-resolution imagery and/or field visits, which are time consuming and expensive processes. The aim of this article is to assess if the data available in the collaborative project OpenStreetMap (OSM) may be used as a source of data to assist the creation of these reference databases, reducing the time spent and costs associated with their generation. For this aim, two case studies were used, where the validation of the Global Monitoring for Environment and Security Urban Atlas (UA) was performed. The used methodology requires the harmonization of the data available in OSM with the UA nomenclature, and the subsequent creation of a LULC map from the OSM data. This map was then compared to UA to assess the similarity of the regions mapped in both. To test the usefulness of OSM data to assess the accuracy of UA, a sample of points was created and two reference databases generated, one assigning the data extracted automatically from OSM to the points where these data were available, and PI for the remaining points, and the other using only PI. The accuracy assessment of UA for the two case studies was then made building confusion matrixes and computing accuracy indicators. The results showed that for the two study areas, only low percentages of points had to be photo interpreted in the first reference database (respectively, 12% and 2% for the two study areas), decreasing the work load considerably. The results obtained with both reference databases are comparable for level 1 classes. For level 2 classes, worse results were obtained for some classes, showing that the OSM data used are not enough to create reliable reference data.     

Integrated provenance record of a forearc basin modified by slab‐window magmatism: detrital‐ zircon geochronology and sandstone compositions of the Paleogene Arkose Ridge Formation,south‐central Alaska

This study presents an integrated provenance record for ancient forearc strata in southern Alaska. Paleocene–Eocene sedimentary and volcanic strata >2000 m thick in the southern Talkeetna Mountains record nonmarine sediment accumulation in a remnant forearc basin. In these strata, igneous detritus dominates conglomerate and sandstone detrital modes, including plutonic and volcanic clasts, plagioclase feldspar, and monocrystalline quartz. Volcanic detritus is more abundant and increases upsection in eastern sandstone and conglomerate. U‐Pb ages of >1600 detrital zircons from 19 sandstone samples document three main populations: 60–48 Ma (late Paleocene–Eocene; 14% of all grains), 85–60 Ma (late Cretaceous–early Paleocene; 64%) and 200–100 Ma (Jurassic–Early Cretaceous; 11%). Eastern sections exhibit the broadest distribution of detrital ages, including a principal population of late Paleocene–Eocene ages. In contrast, central and western sections yield mainly late Cretaceous–early Paleocene detrital ages. Collectively, our results permit reconstruction of individual fluvial drainages oriented transverse to a dissected arc. Specifically, new data suggest: (1) Detritus was eroded from volcanic‐plutonic sources exposed along the arcward margin of the sampled forearc basin fill, primarily Jurassic–Paleocene magmatic‐arc plutons and spatially limited late Paleocene–Eocene volcanic centers; (2) Eastern deposystems received higher proportions of juvenile volcanic detritus through time from late Paleocene–Eocene volcanic centers, consistent with emplacement of a slab window beneath the northeastern part of the basin during spreading‐ridge subduction; (3) Western deposystems transported volcanic‐plutonic detritus from Jurassic–Paleocene remnant arc plutons and local eruptive centers that flanked the northwestern part of the basin; (4) Diagnostic evidence of sediment derivation from accretionary‐prism strata exposed trenchward of the basin fill is lacking. Our results provide geologic evidence for latest Cretaceous–early Paleocene exhumation of arc plutons and marine forearc strata followed by nonmarine sediment accumulation and slab‐window magmatism. This inferred history supports models that invoke spreading‐ridge subduction beneath southern Alaska during Paleogene time, providing a framework for understanding a mature continental‐arc/forearc‐basin system modified by ridge subduction. Conventional provenance models predict reduced input of volcanic detritus to forearc basins during progressive exhumation of the volcanic edifice and increasing exposure of subvolcanic plutons. In contrast, our results show that forearc basins influenced by ridge subduction may record localized increases in juvenile volcanic detritus during late‐stage evolution in response to accumulation of volcanic sequences formed from slab‐window eruptive centers.