Cobalt zoning in microscopic pyrite from Kamoto,Republic of the Congo (Kinshasa)

The Kamoto deposit consists of two stratiform orebodies separated by a barren sedimentary unit. It is a copper and cobalt deposit, the main features of which are summarized in the first part of the paper. Above the upper orebody, dolostone beds are found, where pyrite is the only sulfide mineral. This pyrite was investigated with the help of a microprobe: all idiomorphic grains were found to be surrounded by a well-defined rim, where the cobalt content reaches 4%; framboidal grains were also found to be heterogeneous with respect to cobalt. The distribution of nickel and copper is described. These observations afford one more evidence that post-depositional events played an important role in the Mine Series of Katanga, especially with regard to heavy metals geochemistry.

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Resume Le gisement de Kamoto est constitué de deux corps minéralisés stratiformes séparés par une unité sédimentaire stérile. C'est un gisement de cuivre et de cobalt dont les principales caractéristiques sont brièvement résumées. Audessus du corps minéralisé supérieur, on trouve des couches de dolomie, où la pyrite est le seul sulfure présent. Cette pyrite a été étudiée à l'aide d'une microsonde: tous les grains idiomorphes y sont entourés d'une bordure bien nette, où la teneur en cobalt atteint 4%; les grains d'apparence framboïdale sont également hétérogènes au point de vue de leur teneur en cobalt. La distribution du nickel et du cuivre est décrite. Ces observations apportent um témoignage supplémentaire de l'importance des événements postérieurs au dépôt dans la «Série des Mines» katangaise, tout spécialement en ce qui concerne la géochimie des métaux lourds. Elles démontrent que le «système» constitué par la roche sédimentaire est resté ouvert pendant un certain temps après la sédimentation.

     

Numerical analyses of deformability tests in jointed rock — “Joint Perturbation” and “No Tension” Finite Element solutions

SummaryNumerical Analyses of Deformability Tests in Jointed Rock — Joint Perturbation and No Tension Finite Element Solutions Sound design of structures in or upon rock requires a thorough knowledge of the rock mass deformability. Field test data interpretation has generally relied upon analytical or Finite Element linear elastic solutions. However, when testing in jointed rock, these can no longer be readily used since the medium cannot resist the tension induced upon loading. Accordingly, other solutions are required. If the discontinuities of the rock mass can all be mapped and their surface properties determined, the Finite Element model will use a Joint Perturbation solution where the joint elements have variable stiffnesses to account for movements along the fractures. If the discontinuities cannot be satisfactorily mapped, a global approach is provided by a No Tension analysis of the stress transfer type. The two techniques are compared in the case of bore hole jack deformability tests and found to agree remarkably well, indicating an appreciable difference from results of linear elasticity.

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ZusammenfassungNumerische Analyse von Verformungsversuchen in geklüfteten Fels — Lösungen mittels Kluft-Perturbation und No Tension Analysis auf Grund der Methode der Finiten Elemente Der Entwurf von Bauwerken in oder auf Fels erfordert eine genaue Kenntnis des Formänderungsverhaltens der Felsmasse. Im allgemeinen basiert die Interpretation der Ergebnisse von Feldversuchen auf den Lösungen des zugehörigen Randwertproblems der linearen Elastostatik mittels klassischer analytischer Methoden oder der Methode der Finiten Elemente. Wenn die Versuche aber in geklüftetem Fels durchgeführt werden, müssen die theoretischen Methoden modifiziert werden, da das Medium keine Zugspannungen aufnehmen kann. Zwei Fälle können unterschieden werden. Erstens: die Kluftflächen der Felsmasse können geometrisch erfaßt und ihre Oberflächeneigenschaften können bestimmt werden; in diesem Falle kann die Finite-Elemente-Lösung eine Kluft-Perturbations-Methode verwenden, in welcher spezielle Kluft-Elemente verschiedener Steifigkeiten normal und tangential zu den Kluftflächen die Bewegungen entlang derselben bestimmen. Zweitens: die Diskontinuitäten der Felsmasse können nicht hinreichend beschrieben werden; für diesen Fall ist vorgekehrt durch die Finite-Element-Analyse vom Typ der Spannungsumlagerung unter Ausschaltung der Zugspannungen (No Tension Analysis), um das globale Verhalten der geklüfteten Felsmasse zu erfassen. Die Lösungen dieser beiden Methoden wurden für den Fall der Bohrloch-Verformungs-Tests verglichen; der Vergleich zeigt ausgezeichnete Übereinstimmung, im Gegensatz zu den Lösungen als lineares Elastizitätsproblem.

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RésuméLa méthode des Eléments Finis appliquée aux résultats d'essais de vérins cylindriques dans les roches fissurées — solutions dites Joint Pertubé et Sans Traction La construction de structures sur ou dans des roches nécessite une connaissance approfendie de la déformabilité du massif rocheux. L'analyse des résultats d'essais en place se fait généralement à l'aide de solutions analytiques ou par Eléments Finis, qui supposent une élasticité linéaire du milieu. De fait, dans les roches fissurées, ces solutions sont inadéquates puisque le milieu ne peut résister aux sollicitations de traction. Il s'agit donc d'utiliser d'autres méthodes d'analyse. Lors qu'il est possible de déterminer la géométrie et les propriétés de toutes les discontinuités, l'on pourra utiliser une solution par Eléments Finis, dite Joint Perturbé dans laquelle la rigidité de surface du joint (ou fissure) peut varier lorsque des movements prennent place au niveau du joint. Si cela est impossible, il faudra utiliser une approche globale dite Sans Traction qui redistribue les contraintes de traction et les dissipe. On compare ces deux types de solutions dans le cas des essais de vérins cylindriques unidirectionnels. Leurs résultats sont identiques et ont nettement différents de ceux obtenus avec une solution élastique linéaire.

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Research supported by the National Aeronautics and Space Administration — Contract NAS 8-21432.

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With 8 Figures     

Les derniers stades de la cristallisation du filon à fluorite et barytine de Chavaniac (Haute-Loire,France) d'après des études d'inclusions fluides et solides

Résumé L'étude des inclusions fluides des minéraux de fin de cristallisation (principalement fluorite et barytine) du filon de Chavaniac, montre une diminution de la température et de la salinité. La fluorite a commencé à se déposer vers 140°C±10°C dans une solution renfermant 20% en poids en équivalents NaCl. La température de formation de la barytine était de 40°C au plus et les solutions diluées renfermaient parfois en émulsion des hydrocarbures liquides. On a pu établir des relations entre succession paragénétique, phases de fracturation, et les résultats précédents.

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Fluid inclusion studies in end-crystallisation minerals from Chavaniac mine (mainly fluorite and baryte) show that temperature and salinity fell during crystallisation. Crystallisation of fluorite began at around 140°C±10°C, in a solution containing about 20% NaCl. The temperature of formation of baryte never exceeded 40°C and the dilute solutions sometimes contained emulsified hydrocarbons. Relations have been established between paragenetic succession, fracture phases, and the above results.

     

Shortage in the midst of plenty: Labour strategies in four Central and Eastern European cities

Labour shortage was an integral feature of the communist system of economic management and one that seemed most unlikely to persist in the face of systemic transformation. A casual examination of the unemployment rates that have emerged throughout most of Central and Eastern Europe (CEE) during the course of the past decade might suggest that this early assumption was correct. However, within the region the aggregate rate of joblessness, as well as the behaviour of national output, mask the fact that certain, major urban centres appear to have weathered well the storms caused by exposure to western markets and stringent fiscal and monetary policies. In these centres transformation has meant, to a greater or lesser degree, industrial modernisation and this begs the question of whether the human capital portfolios of the inherited labour force match up to the requirements of the new environment. This paper examines the meaning of the concept of labour shortage and presents the findings from a survey of employers in four leading cities of three major CEE economies designed to elicit if, and how, manpower requirements are being met in the present climate. The results indicate that, somewhat paradoxically, labour shortage persists in the more flexible markets of the post-communist era and that firms do not expect the situation to change radically in the near future. This revised version was published online in July 2006 with corrections to the Cover Date.     

Potential of the VLTI for linking stellar frames to ICRF

The question of positioning the optical counterparts of the ICRF quasars is outlined in the perspective of future space astrometry missions, which ultimately will bring a new realization of the ICRS in the optical range. Ground-based interferometry with a dual-field observing mode (PRIMA/VLTI),together with the missions DIVA and FAME, will have a key role in building an extragalactic reference frame in the optical/near-IR range with about the same accuracy as that of the present (VLBI) primary frame. This revised version was published online in July 2006 with corrections to the Cover Date.     

Fishing for diatoms: fish gut analysis reveals water quality changes over a 75-year period

Defining the reference state of some perturbed streams and rivers is challenging since their non-altered state is undocumented. Despite the near-absence of pristine sites in highly anthropogenic areas, information about aquatic communities that existed prior to human disturbance can be obtained from historic sources. Sediment coring is commonly used in paleolimnology to estimate past environmental conditions of lakes, but this technique is often not appropriate for studies of lotic systems. An alternative is to use diatom assemblages present in the guts of fish that were captured in the streams prior to significant human disturbance. The purpose of the present study was to evaluate the biological integrity of several streams in Ontario and Québec during the early twentieth century based on “paleo” diatom assemblages extracted from the guts of fish stored in museums. The Eastern Canadian diatom index (IDEC: Indice Diatomées de l’Est du Canada) was used to evaluate the biological status of “paleo” and “modern” diatom assemblages. The IDEC shows the position of diatom assemblages on a general pollution gradient. The comparison of IDEC values calculated for the 1925–1948 and the 2003–2007 periods showed that several streams were severely polluted in the early 1900s. In general, present water quality has declined compared to the early 1900s. The biological integrity of only three of the 22 sites has increased. IDEC values were not influenced by the species of fish studied.     

Hydrological characterization of dammed rivers in the NW Mediterranean region

Water scarcity and climatic variability in the Mediterranean region have traditionally required the construction of dams to guarantee water supply for irrigation, industrial and urban uses and hydropower production. Reservoirs affect the hydrology of the river downstream, but the magnitude and persistence of these effects are still poorly unknown. Understanding the magnitude of these effects is the objective of this paper, in which we analyse the flow regimes of twelve rivers located in the NW Mediterranean region. Different temporal scales (daily, monthly and annual) are used for the analysis and also to estimate flow variables associated with flow magnitude, frequency, duration and variability. It is shown that dams alter the hydrological regime of most of the studied rivers, with special influence on monthly flows and flood magnitude and frequency. The most altered rivers (Muga and Siurana, NE Iberian Peninsula) experience a complete overturn in their flow regime with, for instance, flood reduction reaching up to 76% for the 2‐year flood event. Other rivers showed lower changes in hydrology (e.g. Orb and Têt). Annual runoff showed a pattern of decrease in all the studied rivers (regulated and non‐regulated) indicating that besides dams (i.e. reservoir evaporation), other factors likely affect water yield. A general recovery downstream from dams is also observed at all temporal scales, mainly because of the inflow from tributaries. Although dams have a clear impact on the hydrology of Mediterranean rivers, water withdrawals and diversions for irrigation and other consumptive uses also affected the hydrological patterns. Copyright © 2015 John Wiley & Sons, Ltd.     

L'analogie des moyennes mensuelles du niveau de la Méditerranée

Résumé Dans l'article est examinée la question de l'analogie du niveau moyen mensuel de la mer pour un nombre de stations marégraphiques sur les côtes italiennes ct françaises de la Méditerranean. On peut constater que la variation de la quantité de l'eau dans la mer est le facteur principal à ce rapport, mais qu'on doit aussi tenir compte de la distance reciproque entre les stations, de l'influence de la force de Coriolis et de l'effet des éléments météorologiques.

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Summary In the paper it is studied the question of the analogy between the average monthly sea-levels for a few tide gauge stations on the Italian and French coasts of the Mediterranean. It could be established that the variation of the water amount in the sea is the principal factor in this regard, but that the distance between the stations, the influence of the Coriolis force and the effect of meteorological elements must be considered, too.

     

On a global expansion of the disturbing function in the planar elliptic restricted three-body problem

Starting with a simple Taylor-based expansion of the inverse of the distance between two bodies, we are able to obtain a series expansion of the disturbing function of the three-body problem (planar elliptic case) which is valid for all points of the phase space outside the immediate vicinity of the collision points. In particular, the expansion is valid for very high values of the eccentricity of the perturbed body. Furthermore, in the case of an interior mean-motion resonant configuration, the above-mentioned expression is easily averaged with respect to the synodic period, yielding once again a global expansion of (R) valid for very high eccentricities.Comparisons between these results and the numerically computed exact function are presented for various resonances and values of the eccentricity. Maximum errors are determined in each case and their origin is established. Lastly, we discuss the applicability of the present expansion to practical problems.     

60Fe–60Ni systematics in the eucrite parent body: A case study of Bouvante and Juvinas

Eucrites are basaltic meteorites that cooled rapidly but are in many instances thermally metamorphosed and impact brecciated. The exact timing of these events remains unclear. In this study, Ni isotopic compositions and Fe/Ni elemental ratios are presented for two non-cumulate eucrites, Bouvante and Juvinas, including mineral separates from the latter. The samples are characterized by variable, well-resolved ⁶⁰Ni-excesses consistent with the former presence of live ⁶⁰Fe (t_1/2 = 2.62 Ma) at the time of eucrite crystallization. A significant fraction of Ni with a terrestrial-like composition appears to be surface correlated. This Ni may be the product of terrestrial contamination or was introduced by a chondritic impactor during brecciation. Altogether, the data provide evidence for a complex and probably multi-stage history of Fe and/or Ni redistribution, which impedes the interpretation of the chronological data.