Climate of the past millennium inferred from varved proglacial lake sediments on northeast Baffin Island,Arctic Canada

This study uses ^239+240Pu-dated varved sediments from Big Round Lake, a proglacial lake on northeast Baffin Island, Arctic Canada to generate a 1000-year-long, annual-resolution record of past climate. Varve thickness is positively correlated with July–August–September temperature measured at Clyde River, 70 km to the north of the lake (r = 0.46, p < 0.001). We therefore interpret the variability and trends in varve thickness to partially represent summer temperature. The coolest Little Ice Age temperatures occurred in this record from 1575 to 1760 AD and were approximately 1.5°C cooler than today (average from 1995 to 2005 AD) and 0.2°C cooler than the last millennium (average from 1000 to 2000 AD). Pre-twentieth-century warmth occurred during two intervals, 970–1150 AD and 1375–1575 AD; temperatures were approximately 1.2°C cooler than today, but 0.1°C warmer than the last millennium. The Big Round Lake varve-thickness record contains features similar to that reconstructed elsewhere in the eastern Canadian Arctic. This high-resolution quantitative record expands our understanding of arctic climate during the past millennium.

Volcanic history, geologic analysis and map of the Prometheus Patera region on Io

Data from Jupiter's moon Io returned by the Galileo spacecraft have been used to create a geologic map of Prometheus Patera, its associated flow field, and nearby features. We have identified the location of the vent that fed the Prometheus flow field during the Galileo epoch in the north-eastern portion of the main Prometheus flow field. This vent is the probable source of a small sulphur-rich plume. Previous studies suggested that the vent may be atop a tectonic fault but we find that the vent is offset from the putative fault. It is plausible that, in the past, magma exploited the fault to reach the surface at Prometheus Patera, but subsequent magma cooling in the conduit could have caused an obstruction preventing further eruptions from providing significant contributions to the Prometheus flow field. We also speculate on how a new Prometheus plumbing system may be fed by mafic magmas after melt stalls in magma reservoirs during its ascent through the lithosphere from the mantle.     

New light on a dark subject: comment

In their article, “New light on a dark subject: On the use of fluorescence data to deduce redox states of natural organic matter,” Macalady and Walton-Day (2009) subjected natural organic matter (NOM) samples to oxidation, reduction, and photochemical transformation. Fluorescence spectra were obtained on samples, which were diluted “to bring maximum uvvisible absorbance values below 1.0.” The spectra were fit to the Cory and McKnight (2005) parallel factor analysis (PARAFAC) model, and consistent variation in the redox state of quinone-like moieties was not detected. Based on these results they concluded that fitting fluorescence spectra to the Cory and McKnight (2005) PARAFAC model to obtain information about the redox state of quinone-like moieties in NOM is problematic. Recognizing that collection and correction of fluorescence spectra requires consideration of many factors, we investigated the potential for inner-filter effects to obscure the ability of fluorescence spectroscopy to quantify the redox state of quinone-like moieties. We collected fluorescence spectra on Pony Lake and Suwannee River fulvic acid standards that were diluted to cover a range of absorbance wavelengths, and fit these spectra to the Cory and McKnight (2005) PARAFAC model. Our results suggest that, in order for the commonly used inner-filter correction to effectively remove inner-filter effects, samples should be diluted such that the absorbance at 254 nm is less than 0.3 prior to the collection of fluorescence spectra. This finding indicates that inner-filter effects may have obscured changes in the redox signature of fluorescence spectra of the highly absorbing samples studied by Macalady and Walton-Day (2009).     

DOM characteristics along the continuum from river to receiving basin: a comparison of freshwater and saline transects

The chemical characteristics of bulk (sterile-filtered) and high molecular-weight dissolved organic matter (HMW DOM) were analyzed for freshwater (St. Louis River, Minnesota to Lake Superior) and saline (Elizabeth River, Virginia to Chesapeake Bay) river-to-receiving basin transects. Dissolved organic carbon concentrations and UV–Visible spectroscopy of bulk DOM demonstrated a reduction in organic carbon, colored DOM and aromatic compounds downstream in both transects. The proportion of DOM recoverable via ultrafiltration as HMW material also decreased downstream in both transects, although there was an offset in recoveries between the transects that may be explained by the effects of ionic strength and/or differences in ultrafiltration technique. The analysis of HMW DOM by Fourier transform infrared spectroscopy illustrated similar trends between transects, with a general shift from aromatic/carboxylic compounds nearshore to aliphatic/carbohydrate materials offshore. The parallel changes observed along saline and freshwater transects imply that similar processes play significant roles in the down-gradient alteration of DOM and that ionic strength or pH changes cause second-order effects.     

The Effectiveness of Arsenic Remediation from Groundwater in a Private Home

Private wells are the source of drinking water for approximately 15% of households in the United States, but these wells are not regulated or monitored by government agencies. The well waters can contain arsenic, a known carcinogen that occurs in groundwater throughout the nation at concentrations that can exceed the Maximum Contaminant Level defined by the U.S. Environmental Protection Agency (10 ppb). In order to reduce arsenic exposure, homeowners can either rely on bottled water for drinking or install in-house water treatment systems for arsenic removal. Here, we document the arsenic levels associated with these options. We examined 24 different major bottled water brands and found that all have arsenic levels <1.5 parts per billion (ppb), and more than half have levels below our measurement detection limit of 0.005 ppb. For in-house treatment systems, we examined the performance of arsenic removal by point-of-use reverse osmosis filtration, and by whole-house and point-of-use filters containing granulated ferric oxide. Our results show that long-term (2 years) filtration with granulated ferric oxide reduced arsenic in well water from an initial concentration of 4 to 9 ppb down to <0.005 ppb, validating this technology as an effective form of arsenic remediation for private homes.     

P-T conditions of earliest Late Cretaceous metamorphism in the Western Sonobari Complex,northwestern Mexico: tectonic implications

The Western Sonobari Complex in northwestern Mexico consists of metamorphosed rocks mostly derived from Palaeozoic (?) sedimentary and Mesozoic igneous protoliths. Rocks of this complex display amphibolite facies orogenic metamorphism, pervasive foliation, migmatization, and four folding phases. These features are ascribed to a contractional tectonic event with NNW–SSE shortening direction, which caused thrusting, thickening of the crust, and sinking of the lithological units. U–Pb geochronology of migmatitic leucosome bands indicates that peak metamorphic conditions were reached between ~93 and 89 Ma. Post-tectonic Late Cretaceous peraluminous aplite-pegmatite dikes transect the metamorphic foliation. Traditional thermobarometry in the metamorphic rocks yields average pressures and temperatures of 9.0–7.1 kbar and 745–663°C, typical of intermediate P/T Barrovian metamorphism. On the basis of its age and contractional character, the thickening event originating the metamorphism may be related to collision of the Alisitos island arc against crustal blocks of Mexico. Thermobarometric data of post-tectonic intrusives including Late Cretaceous granodiorite and Eocene gabbro indicate emplacement within an overthickened crust, while P-T conditions of post-tectonic dikes point towards an almost isothermal decompression path along the amphibolite facies field. Rock units of similar age and metamorphic character are discontinuously exposed from the Islas Marias offshore the Nayarit coast to the Peninsular Ranges batholith of Baja California, and even extend north into the Sierra Nevada batholith and the Sevier hinterland. This extensive belt of Barrovian metamorphic rocks thus provides a record of middle Cretaceous shortening and crustal thickening related to arc-continent collision followed by subduction resuming.     

Wood-mediated geomorphic effects of a jökulhlaup in the Wind River Mountains, Wyoming

A jökulhlaup burst from the head of Grasshopper Glacier in Wyoming's Wind River Mountains during early September 2003. Five reaches with distinct sedimentation patterns were delineated along the Dinwoody Creek drainage. This paper focuses on a portion of the jökulhlaup route where erosion of the forested banks created 16 large logjams spaced at longitudinal intervals of tens to hundreds of meters. Aggradation within the main channel upstream from each logjam created local sediment wedges, and the jams facilitated overbank deposition during the jökulhlaup. Field surveys during 2004 and 2006 documented logjam characteristics and associated erosional and depositional features, as well as initial modification of the logjams and flood deposits within the normal seasonal high-flow channel. Overbank deposits have not been altered by flows occurring since 2003. Field measurements supported three hypotheses that (i) logjams present along the forested portions of the jökulhlaup route are larger and more closely spaced than those along adjacent, otherwise comparable stream channels that have not recently experienced a jökulhlaup; (ii) logjams are not randomly located along the jökulhlaup route, but instead reflect specific conditions of channel and valley geometry and flood hydraulics; and (iii) the presence of logjams facilitated significant erosional and depositional effects. This paper documents a sequence of events in which outburst floodwaters enhance bank erosion and recruitment of wood into the channel, and thus the formation of large logjams. These logjams sufficiently deflect flow to create substantial overbank deposition in areas of the valley bottom not commonly accessed by normal snowmelt peak discharges, and through this process promote valley-bottom aggradation and sediment storage. Changes in the occurrence of glacier outburst floods thus have the potential to alter the rate and magnitude of valley-bottom dynamics in these environments, which is particularly relevant given predictions of worldwide global warming and glacial retreat. Processes observed at this field site likely occur in other forested catchments with headwater glaciers.     

Effects of building materials on UHF ranging signals

Positioning and tracking inside buildings using wireless location methods has recently received considerable attention. One method is the estimation of the time of arrival of satellite or terrestrial-based radio frequency signals in order to produce ranges from the transmitter to the receiver. This paper investigates the effect of walls made of various construction materials on the penetration of ranging signals. In the tests conducted, a GPS pseudo-satellite transmits a pseudorandom noise code at a carrier frequency of 1.57542 GHz. After penetrating walls made of plywood, gyprock and cinder blocks, the signal is received by a GPS receiver which measures the carrier phase and the pseudorange between the transmitter and receiver using code correlation. Compared to measurements obtained with no walls present, the effect on the measurements is determined. The results indicate that the carrier phase measurement is superior to the pseudorange in terms of noise, stability, and the magnitude of the effect of the walls on the range obtained. Ranges based on the carrier phase only change by a few centimeters. Given that the integer number of cycles of the phase can be determined and phase lock is maintained, the carrier phase measurement shows considerable promise for indoor ranging.     

Palaeotemperature determinations for the 1.8-ka Taupo ignimbrite,New Zealand,and implications for the emplacement history of a high-velocity pyroclastic flow

Palaeomagnetic data from lithic clasts collected at 46 sites within layers 1 and 2 of the 1.8-ka Taupo ignimbrite, New Zealand, have been used to determine the palaeotemperatures and thermal structure of the deposit on its emplacement. Equilibrium temperatures from sites less than 30–40 km from vent are 150–300 °C, whereas at greater distances site equilibrium temperatures increase up to 400–500 °C. This variation is seen in both layer 1 and 2 deposits, with values for layer 1 being somewhat cooler, and with its increase in temperature occurring at a greater distance from vent. A temperature maximum at ~50 km from vent coincides with a zone of pink thermal-oxidation colouration of pumices previously inferred to reflect higher emplacement temperatures. Additional palaeomagnetic data collected by us and others from pumice clasts show comparable temperature variations, but these temperature estimates are shown here to be due to a chemical remanence and unreliable for accurate temperature estimates. Cooler temperatures in proximal parts of the ignimbrite are consistent with admixture of >20% cold lithic clasts at source and interaction with the pre-eruption Lake Taupo. The similar, but offset, increases in equilibrium temperatures for medial and distal layers 1 and 2 are consistent with both layers being deposited from the same flow. However, any proximal deposits left by the later, hotter material must have been subsequently eroded, or be so thin that our collection failed to sample them. Radial asymmetries in equilibrium temperatures as well as other physical parameters suggest that the deposit emplacement temperature is primarily determined at source, rather than by interaction with air during transport. These data support previous interpretations that a concentrated basal flow played a dominant role in emplacement and deposition of the Taupo ignimbrite.Editorial responsibility: T. Druitt