Application of the QUILF thermobarometer to the peralkaline trachytes and pantellerites of the Eburru volcanic complex, East African Rift, Kenya

The Quaternary Eburru volcanic complex in the south-central Kenya Rift consists of pantelleritic trachytes and pantellerites. The phenocryst assemblage in the trachytes is sanidine + fayalite + ferrohedenbergite + aenigmatite ± quartz ± ilmenite ± magnetite ± pyrrhotite ± pyrite. In the pantellerites, the assemblage is sanidine + quartz + ferrohedenbergite + fayalite + aenigmatite + ferrorichterite + pyrrhotite ± apatite, although fayalite, ferrohedenbergite and ilmenite are absent from more evolved rocks (e.g. with SiO₂ > 71%). QUILF temperature calculations for the trachytes range from 709 to 793 °C and for the pantellerites 668–708 °C, the latter temperatures being among the lowest recorded for peralkaline silicic magmas. The QUILF thermobarometer demonstrates that the Eburru magmas crystallized at relatively low oxidation states (ΔFMQ + 0.5 to − 1.6) for both trachytes and pantellerites. The trachytes and pantellerites evolved along separate liquid lines of descent, the trachytes possibly deriving from a more mafic parent by fractional crystallization and the pantellerites from extreme fractionation of comenditic magmas.     

Selenium and mercury concentrations in harbor seals (Phoca vitulina) from central California: Health implications in an urbanized estuary

We measured total selenium and total mercury concentrations ([TSe] and [THg]) in hair (n = 138) and blood (n = 73) of harbor seals (Phoca vitulina) from California to assess variation by geography and sex, and inferred feeding relationships based on carbon, nitrogen, and sulfur stable isotopes. Harbor seals from Hg-contaminated sites had significantly greater [THg], and lesser [TSe] and TSe:THg molar ratios than seals from a relatively uncontaminated site. Males had significantly greater [THg] than females at all locations. Sulfur stable isotope values explained approximately 25% of the variability in [THg], indicating increased Hg exposure for seals with a greater use of estuarine prey species. Decreased [TSe] in harbor seals from Hg-contaminated regions may indicate a relative Se deficiency to mitigate the toxic effects of Hg. Further investigation into the Se status and the potential negative impact of Hg on harbor seals from Hg-contaminated sites is warranted.     

Bulk organic δ13C and C/N ratios as palaeosalinity indicators within a Scottish isolation basin

Microfossils in isolation basin sediments are frequently used to reconstruct sea‐level change, but preservation problems and non‐analogue situations can limit their usefulness. Here we investigate the potential of stable carbon isotopes (δ¹³C) and C/N ratios from bulk organic matter, as an alternative proxy of salinity within isolation basin sediments from a basin in northwest Scotland. Within the Holocene sediment δ¹³C and C/N are determined largely by the mean weighted values of the predominant source of the organic material. Analysis of modern materials and comparison with the diatom record shows that the marine parts of the sequence are dominated by high δ¹³C and variable C/N. In the fresh water sequences the organic material is a mixture of both freshwater aquatic and terrestrial plant input that have relatively low δ¹³C and high C/N. The application of δ¹³C and C/N ratios in the studied basin in general follow the environmental change recorded by the diatoms and shows the potential of bulk organic matter in the investigation of salinity change in isolation basins. Copyright © 2005 John Wiley & Sons, Ltd.     

Phytoplankton-zooplankton coupling in the outer continental shelf and slope waters of the Mid-Atlantic Bight,June 1979

Measurements of phytoplankton distribution and production, and zooplankton abundance and biomass were made during the summer of 1979 along several shelf-slope transects in the Mid-Atlantic Bight. At the shelf-break, macrozooplankton (>200 μm) grazing was estimated to be sufficient to remove a substantial proportion of daily phytoplankton production. In contrast, on the shelf and in slope waters, where ciliates were abundant, estimates of macrozooplankton grazing indicated a consumption rate less than 15% of the daily primary production. Ciliate grazing, even at non-maximum rates, potentially could have consumed the entire daily primary production in all areas sampled. The findings indicate that the nature of the heterotrophic community is spatially variable in offshore waters even during summer conditions and could influence not only trophodynamic pathways but perhaps nutrient regeneration and recycling. This would be an important consideration in evaluating the fate of particle-bound chemcial species in the water column since fecal pellet producing zooplankton would affect rates of removal and sedimentation in a different manner than ciliates which produce non-compacted digestive debris.     

Validating a rapid-update satellite precipitation analysis across telescoping space and time scales

In order to properly utilize remotely sensed precipitation estimates in hydrometeorological applications, knowledge of the accuracy of the estimates are needed. However, relatively few ground validation networks operate with the necessary spatial density and time-resolution required for validation of high-resolution precipitation products (HRPP) generated at fine space and time scales (e.g., hourly accumulations produced on a 0.25° spatial scale). In this article, we examine over-land validation statistics for an operationally designed, meteorological satellite-based global rainfall analysis that blends intermittent passive microwave-derived rainfall estimates aboard a variety of low Earth-orbiting satellite platforms with sub-hourly time sampling capabilities of visible and infrared imagers aboard operational geostationary platforms. The validation dataset is comprised of raingauge data collected from the dense, nearly homogeneous, 1-min reporting Automated Weather Station (network of the Korean Meteorological Administration during the June to August 2000 summer monsoon season. The space-time RMS error, mean bias, and correlation matrices were computed using various time windows for the gauge averaging, centered about the satellite observation time. For ±10 min time window, a correlation of 0.6 was achieved at 0.1° spatial scale by averaging more than 3 days; coarsening the spatial scale to 1.8° produced the same correlation by averaging over 1 h. Finer than approximately 24-h and 1° time and space scales, respectively, a rapid decay of the error statistics was obtained by trading-off either spatial or time resolution. Beyond a daily time scale, the blended estimates were nearly unbiased and with an RMS error of no worse than 1 mm day^?1.