Coexisting serpentine and quartz from carbonate-bearing serpentinized peridotite in the Samail Ophiolite, Oman

Tectonically exposed mantle peridotite in the Oman Ophiolite is variably serpentinized and carbonated. Networks of young carbonate veins are prevalent in highly serpentinized peridotite, particularly near low-temperature alkaline springs emanating from the peridotite. An unusual feature in some samples is the coexistence of serpentine and quartz, which is not commonly observed in serpentinites. This assemblage is unstable with respect to serpentine?+?talc or talc?+?quartz under most conditions. Serpentine in the carbonated serpentinites in this study is more iron rich than in most serpentinites reported in previous studies, and samples with co-existing quartz contain the most iron-rich serpentines. Calculations of thermodynamic equilibria in the MgO–SiO₂–H₂O–CO₂ system suggest that serpentine?+?quartz may be a stable assemblage at low temperatures (e.g., <~15–50?°C) and is stabilized to higher temperatures by preferential cation substitutions in serpentine over talc. Based on these calculations, serpentine?+?quartz assemblages could result from serpentinization at near-surface temperatures. Clumped isotope thermometry of carbonate veins yields temperatures within error of the observed temperatures in Oman groundwater for all samples analyzed, while the δ¹⁸O of water calculated to be in equilibrium with carbonate precipitated at those temperatures is within error of the observed isotopic composition of Oman groundwater for the majority of samples analyzed. As groundwater geochemistry suggests that carbonate precipitation and serpentinization occur concomitantly, this indicates that both hydration and carbonation of peridotite are able to produce extensive alteration at the relatively low temperatures of the near-surface weathering environment.     

Length of phytoplankton species patches on the Southern California Shelf

Study of a longshore transect off Southern California suggests that the length scales (22 to 27 km) of phytoplankton species patches may be related to those of low-frequency currents. The patch boundaries were independent of shelf width but they were probably not independent of changes in chlorophyll fluorescence, temperature, and bottom topography.     

The phthalate diesters DEHP and DBP do not induce lauric acid hydroxylase activity in rainbow trout

Aquatic organisms are extensively exposed to phthalate esters. We have investigated in trout the effects of diethylhexylphthalate (DEHP) and dibutylphthalate (DBP) on xenobiotic metabolizing enzymes which have been suggested as possible environmental biomarkers. Rainbow trout (Oncorhynchus mykiss) were waterborne exposed to DEHP (1 mg/l) or DBP (0.1 or 1 mg/l) for 72 h. Another group of rainbow trout received daily for 3 days an intraperitoneal injection of 50 mg/kg of DEHP or DBP. Laurate hydroxylation, ethoxyresorufin-o-deethylation, UDP-glucuronyltransferase activity and glutathione-S-transferase activity were measured in liver and extrahepatic tissues. The phthalate esters have been found not to induce these enzymes; in particular, the results do not support the previously described induction of lauric acid hydroxylase in sea bass treated with DEHP [Comp. Biochem. Physiol. B122 (1999) 253.].     

Palaeosecular variation in Central Mexico over the last 30 000 years: the record from lavas

13 lava flows of known age (ages from ¹⁴C dating), which have been erupted in the last 30 000 years, have been studied to determine the palaeosecular variation of the geomagnetic field in Central Mexico. Samples were taken from two different monogenetic volcanic fields: the Michoacan-Guanajuato volcanic field (six sites) and the Chichinautzin Formation (seven sites), both part of the Transmexican Volcanic Belt. The lavas were studied in detail using rock magnetic methods (magnetic susceptibility at room temperature, low-temperature susceptibility behaviour, hysteresis loops, Curie temperatures), combined with reflected light microscopy, in order to deduce their magnetic mineralogy and the domain states of the magnetic minerals. The magnetic carriers are titanomagnetites, which show differing degrees of high-temperature deuteric oxidation, and seem to be predominantly pseudo-single domain (PSD), though in many cases are probably a mixture of domain states. Mean palaeomagnetic directions and palaeointensity values using Shaw and Thellier techniques were obtained using several specimens from each flow. Our data seem to indicate a sharp easterly swing in declination about 5000 years ago, which is also observed in lake sediments from Central Mexico. The calculated values of the virtual dipole moment (VDM) range from 3.1 to 14.9 × 10²² A m². Our data indicate that the virtual dipole moment seems to have increased gradually in magnitude over the last 30 kyr, with a peak at about 9000 years BP. These are features that have been observed in other parts of the globe and are probably caused by variations in the dipole part of the geomagnetic field.     

Interpretation of Na–Cl–Br Systematics in Sedimentary Basin Brines: Comparison of Concentration, Element Ratio, and Isometric Log-ratio Approaches

Mathematicians and geochemists have long realized that compositional data intrinsically exhibit a structure prone to spurious and induced correlations. This paper demonstrates, using the Na–Cl–Br system, that these mathematical problems are exacerbated in the study of sedimentary basin brines by such processes as the evaporation or dissolution of salts owing to their high salinities. Using two published datasets of Na–Cl–Br data for fluids from the Appalachian Basin, it is shown that log concentration and Na/Br versus Cl/Br methods for displaying solute chemistry may lead to misinterpretation of mixing trends between meteoric waters (for example shallow drinking water aquifers) and basinal brines, partially due to spurious mathematical relationships. An alternative approach, based on the isometric log-ratio transformation of molar concentration data, is developed and presented as an alternative method, free from potential numerical problems of the traditional methods. The utility, intuitiveness, and potential for mathematical problems of the three methods are compared and contrasted. Because the Na–Cl–Br system is a useful tool for sourcing solutes and investigating the evolution of basinal brines, results from this research may impact such critical topics as evaluating sources of brine contamination in the environment (possibly related to oil and gas production), evaluating the behavior of fluids in the reservoir during hydraulic fracturing, and tracking movement of fluids as a result of geologic CO₂ sequestration.     

Fate of pioneering vegetation patches in a dynamic meandering river

Fluvial biomorphodynamics in actively meandering rivers entail interactions between hydromorphodynamics and pioneering tree species that have eco-engineering effects. Here we study spatiotemporal patterns of vegetation patches smaller than 150 m² in a 4 km reach of the river Allier in France in order to unravel causes for tree persistence and mortality and identify spatial trends across the river valley. To this end we analysed aerial photographs by object-based image analysis over a period of 56 years and tracked individual patches through time. Furthermore the cover and surface age of the study reach were classified. The large-scale shifts of channels, bars and vegetation are consistent with the meandering process and chute cutoffs. However, the spatiotemporal patterns of the vegetation patches are surprising in that they are ubiquitous and have ages up to decades on the highly dynamic meander belt, but hardly expand into larger vegetation patches. Patches disappear exponentially as a function of their age, and faster so in the last decades. Causes are amalgamation into the riparian forest flanking the meander belt and mortality likely due to desiccation or erosion. Patches have a higher probability of survival when further away from the active channel and closer to high vegetation patches and valley boundary. The window of opportunity of vegetation settlement widens towards the valley boundaries and in floodplain lows of former channels and chutes. These results imply a gradual cross-valley gradient of riparian vegetation settling, survival and succession. © 2019 The Authors. Earth Surface Processes and Landforms Published by John Wiley & Sons Ltd.     

Reducing climate risk for micro-insurance providers in Africa: A case study of Ethiopia

Recurrent climate hazards challenge subsistence farmers in developing countries. Reliance on various diversification strategies and traditional risk sharing among kin and families has serious limitations, such as the problem of covariate risk within such networks. Index-based crop insurance could help to reduce people's climate-related risk, but raising the necessary capital to make insurance schemes financially secure is difficult for micro-insurance providers. We examine the extent to which spatial pooling of micro-insurance schemes could reduce these capital requirements. We simulate a hypothetical insurance market operating in Ethiopia, using rainfall data and yield estimates for 15 stations. By performing a Monte Carlo analysis, risk capital required to keep the probability of financial ruin below a threshold value is identified. We investigate the marginal benefits of pooling increasing numbers of sites, as well as the relationship between the benefits of pooling and the spatial covariance of rainfall. We find spatial diversification to offer considerable savings in required capitalization with as few as three sites pooled, as well as a weak but significant relationship between rainfall covariance and those benefits. The results suggest that spatial pooling may be an attractive option for micro-insurers, worthy of a detailed case-by-case analysis when designing index-insurance schemes.     

Production, preservation and prediction of source-rock facies in deltaic settings

This article hypothesizes that production and preservation of source-rock type facies in deltaic systems, both landward and seaward of a coastline, is mutually exclusive, time-successive and related to the dynamics of relative sea level. Sedimentologic research in the Holocene Mississippi and Rhône delta complexes suggests that rheotrophic peats and associated organic-rich beds preferably accumulate in the accommodation space created behind landward stepping shorelines in a transgressive systems tract (TST). Such a setting also allows for a sufficient supply of recharging fresh nutrient-rich groundwater into the peat forming mires [Kosters, E.C., Suter, J.R., 1993. Facies relationships and systems tracts in the late Holocene Mississippi Delta Plain. Journal of Sedimentary Petrology 63 (4) 727–733.]. Independently carried-out quantitative paleoecological studies in the same delta systems (and in addition in the Orinoco and Po deltas) suggest that in a progradational setting (highstand systems tract/HST), seasonally discharged nutrient- and sediment-laden river waters on the shelf may give rise to anoxia or dysoxia. Subsequent overfertilization of the shelf leads to accumulation of organic-rich mud belts on the shelf [VanderZwaan, G.J., Jorissen, F.J., 1991. Biofacial patterns in river-induced anoxia. In: Tyson, R.V., Pearson, T.H. (Eds.), Modern and Ancient Continental Shelf Anoxia. Geological Society of London, Special Publication no. 58, pp. 65–82.]. Thus, production and preservation of source-rock type facies landward of a shoreline (as peats and related sediments) is preferred in a TST, when accommodation space and nutrient supply are landward of the shoreline. Vice versa, production and preservation of such facies seaward of a shoreline (as organic-rich shelf muds) occurs preferentially in a highstand systems tract. In that situation, accommodation space is on the shelf, where river-fed nutrients are supplied as well. This hypothesis suggests further potential for application of sequence stratigraphic concepts for improved understanding of the occurrence of source-rock type facies.