Middle to Late Pleistocene palaeoenvironmental evolution of the southeastern Alpine Valeriano Creek succession (northeastern Italy)

The Middle–Late Pleistocene alluvial and lacustrine succession of Valeriano Creek (southeastern Alpine foothills, 190 m a.s.l.) documents the environmental evolution of the piedmont plain before the onset of the Last Glacial Maximum (LGM). The sedimentary record was investigated by multidisciplinary stratigraphical and sedimentological studies coupled with petrographic and palaeobotanical analysis. A chronology has been provided by luminescence, radiocarbon dating and pollen biochronology. The succession developed at the valley mouth of a small catchment and is confined in the piedmont plain by the alluvial fans of major rivers. The oldest deposits were formed during a cold phase during the late Middle Pleistocene. This part of the piedmont plain was generally stable until Termination II, when it was trenched more than 15 m deep by watercourses. The infilling succession of the trench, mostly by low‐energy alluvial sediments interbedded with mire and peat deposits, documents, for the first time on the southern side of the Alps, the relationships between fluvial activity, vegetation and climate change at the foothills piedmont plain during late Marine Isotope Stage (MIS) 5. The stadial–interstadial climate forcing implies a local reorganisation of fluvial dynamics and of forest composition, although substantial plant cover persisted even during cooler stadials. In accordance with coeval alluvial and speleothem records from the northern side of the Alps, this environmental evolution supports a very restricted Alpine glaciation of the main fluvial catchments of the southeastern Alps during MIS 5a–d. Copyright © 2009 John Wiley & Sons, Ltd.     

In situ survey of graphite in unequilibrated chondrites: Morphologies,C, N,O, and H isotopic ratios

Abstract— We performed in situ morphological and isotopic studies of graphite in the primitive chondrites Khohar (L3), Mezö‐Madaras (L3), Inman (L3), Grady (H3), Acfer 182 (CH3), Acfer 207 (CH3), Acfer 214 (CH3), and St. Marks (EH5). Various graphite morphologies were identified, including book, veins, fibrous, fine‐grained, spherulitic, and granular graphite, and cliftonite. SIMS measurements of H, C, N, and O isotopic compositions of the graphites revealed large variations in the isotopic ratios of these four elements. The δ¹⁵N and δ¹³C values show significant variations among the different graphite types without displaying any strict correlation between the isotopic composition and morphology. In the Khohar vein graphites, large ¹⁵N excesses are found, with δ¹⁵N_max ～+955‰, confirming previous results. Excesses in ¹⁵N are also detected in fine‐grained graphites in chondrites of the CH clan, Acfer 182, Acfer 207, and Acfer 214, with δ¹⁵N ranging up to +440‰. The ¹⁵N excesses are attributed to ion‐molecule reactions at low temperatures in the interstellar molecular cloud (IMC) from which the solar system formed, though the largest excesses seem to be incompatible with the results of some recent calculation. Significant variations in the carbon isotopic ratios are detected between graphite from different chondrite groups, with a tendency for a systematic increase in δ¹³C from ordinary to enstatite to carbonaceous chondrites. These variations are interpreted as being due to small‐ and large‐scale carbon isotopic variations in the solar nebula.     

江汉平原长湖近代沉积物磁性测量及其气候意义

根据１９９２年长湖所取代表性９２－５ 面沉积物磁性测量结果并结合化学分析和孢粉分析,研究长湖近代沉积物磁性参数变化与气候变化的关系,指出该地区最近４００ａ来气候变化总趋势是一个由冷变暖的过程。     

Natural geobatteries associated with sulphide ore deposits,I. Theoretical studies

Any conductive sulphide ore body can generate electrical ore potentials and this can be regarded as a geobattery, with an upper positive cathode and a lower negative anode. Two mechanisms which can occur simultaneously and which appear to explain these potentials are the oxygen concentration cell (OCC) and the sulphide galvanic cell (SGC). When there is a difference of O₂ concentration between the cathode and anode, the OCC operates by contributing oxygen to the anode, and ceases when the difference is diminished. However, gradients of pH, temperature or pressure can keep the cell operating. In the SGC the sulphides dissolve at the anode (producing metal ions, sulphur and electrons), while at the cathode, either sulphides dissolve producing metal and sulphur ions, or reaction is as in the OCC. The ore potential measured in the field is the sum of the oxygen concentration cell and at times locally dominant sulphide galvanic cells.     

GHOST – A Novel Airborne Gas Chromatograph for In Situ Measurements of Long-Lived Tracers in the Lower Stratosphere: Method and Applications

A novel fully-automated airborne gas chromatograph for in situmeasurements of long-lived stratospheric tracers hasbeen developed, combining the high selectivity of a megabore PLOTcapillary column with recently developed sampling and separationtechniques. The Gas cHromatograph for theObservation of Stratospheric Tracers (GHOST)has been successfully operated during three STREAM campaigns(Stratosphere TRoposphere Experiment byAirborne Measurement) onboard a Cessna Citation IIaircraft in two different modes: Either N₂O andCF₂Cl₂(CFC-12) or CFC-12 and CFCl₃ (CFC-11) have been measuredsimultaneously, with a time resolution of 2 min for both modes.Under flight conditions the instrument precision (1) forthese species is better than 0.9%, and the accuracy(1) is better than 2.0% of the tropospheric values ofall measured compounds. The detection limits (3) arebelow 28 ppb for N₂O, 14 ppt for CFC-12, and 8 ppt forCFC-11, respectively, i.e., well below 10 % of the troposphericvalues of all measured compounds. Post-mission optimization of thechromatographic separation showed a possible enhancement of thetime resolution by up to a factor of 2, associated with acomparable increase in precision and detection limit. As test ofactual performance of GHOST results from an in-flight N₂Ointercomparison with a tunable diode laser absorptionspectrometer (TDLAS) are presented. They yield an excellentagreement between both instruments. Furthermore, on the basis ofthe hitherto most extensive set of upper tropospheric and lowerstratospheric data, the relative stratospheric N₂2O lifetime isre-assessed. When referenced to the WMO reference CFC-11 lifetimeof 45 ± 7 years an N₂O lifetime of 91 ± 15 yearsis derived, a value substantially smaller than the WMO referencelifetime of 120 years. Moreover, this value implies astratospheric N₂O sink strength of 16.3 ± 2.7 Tg (N)yr^–1 which is 30% larger than previous estimates.     

Aqueous Phase Reaction of HNO4: The Impact on Tropospheric Chemistry

We use a global atmospheric chemistry transport model to study the possible influence of aqueous phase reactions of peroxynitric acid (HNO₄) on the concentrations and budgets of NO_x, SO_x, O₃ and H₂O₂. Laboratory studies have shown that the aqueous reaction of HNO_4aq withHSO^– _3aq, and the uni-molecular decomposition of the NO₄ ^– anion to form NO₂ ^– (nitrite) occur on a time scale of about a second. Despite a substantial contribution of the reaction of HSO^– _3aq with HNO_4aq to the overall in-cloud conversion of SO₂ to SO₄ ^2–, a simultaneous decrease of other oxidants (most notably H₂O₂) more than compensated the increase in SO₄ ^2– production. The strongest influence of heterogeneous HNO₄ chemistry was found in the boundary layer, where calculated monthly average ozone concentrations were reduced between 2% to 10% andchanges of H₂O₂ between –20% to +10%compared to a simulation which ignores this reaction. Furthermore, SO₂ was increased by 10% to 20% and SO₄ ^2–depleted by up to 10%. Since the resolution of our global model does not enable a detailed comparison with measurements in polluted regions, it is not possible to verify whether considering heterogeneous HNO₄ reactions results in a substantial improvement of atmospheric chemistry transport models. However, the conversion of HNO₄ in the aqueous phase seems to be efficient enough to warrant further laboratory investigations and more detailed model studies on this topic.     

Late Pleistocene palaeolake in the interior of Oman: a potential key area for the dispersal of anatomically modern humans out‐of‐Africa?

Relict fluvial and lacustrine deposits in the interior of Oman near Saiwan consist of waterlain breccias with pebble imbrications and current ripples, covered by algal laminites containing calcified reeds and charcoal pieces. Geomorphological evidence suggests that the palaeolake covered a maximum surface of 1400 km² and had a maximum depth of about 25 m. Optically stimulated luminescence (OSL) and thermally transferred OSL dating indicate that this palaeolake existed sometime between 132 and 104 ka. The rich archaeological evidence in the area suggests substantial human occupation, possibly at the time when Palaeolake Saiwan existed. Interestingly, the lithic traditions of the archaeological material show no clear relation to coeval findings from neighbouring areas, putting a question mark on the origin of the culture found at Saiwan. This finding raises questions concerning the origin of the population inhabiting Saiwan, as the site lies along one possible route for the dispersal of anatomically modern humans out‐of‐Africa. Copyright © 2011 John Wiley & Sons, Ltd.     

Qualitative spatial reasoning: cardinal directions as an example

ABSTRACT

Abstract. Geographers use spatial reasoning extensively in large-scale spaces, i.e., spaces that cannot be seen or understood from a single point of view. Spatial reasoning differentiates several spatial relations, e.g. topological or metric relations, and is typically formalized using a Cartesian coordinate system and vector algebra. This quantitative processing of information is clearly different from the ways human draw conclusions about spatial relations. Formalized qualitative reasoning processes are shown to be a necessary part of Spatial Expert Systems and Geographical Information Systems.

Addressing a subset of the total problem, namely reasoning with cardinal directions, a completely qualitative method, without recourse to analytical procedures, is introduced and a method for its formal comparison with quantitative formula is defined. The focus is on the analysis of cardinal directions and their properties. An algebraic method is used to formalize the meaning of directions. The standard directional symbols (N, W, etc.) are supplemented with a symbol corresponding to an undetermined direction between points too close to each other which greatly increases the power of the inference rules. Two specific systems to determine and reason with cardinal directions are discussed in some detail.

From this example and some other previous work, a comprehensive set of research steps is laid out, following a mathematically based taxonomy. It includes the extension of distance and direction reasoning to extended objects and the definitions of other metric relations that characterize situations when objects are not disjointed. The conclusions compare such an approach with other concepts.