Occurrence of selected estrogens in mangrove sediments

This paper presents results related to the occurrence and distribution of estrogens along the Brazilian coast. Three mangrove areas were chosen to evaluate the presence of estrogens in surface sediments of mangrove forests. The presence of estrogens was observed in all studied sites. 17-α-Ethinylestradiol (EE2), a synthetic estrogen, was the most common and has been found in higher concentration (0.45-129.78 ng/g) compared to 17-β-estradiol (E1) and estrone (E2) (both being natural estrogens). The concentrations of E1 and E2 ranged from 0.02 to 49.27 ng/g and 0.03 to 39.77 ng/g, respectively. Theoretically, under anaerobic conditions EE2 can be reduced to E1 even in environments such as sediments of mangrove forests, which are essentially anaerobic. Even if the concentrations of estrogens seem to be insignificant in some samples, the effects remain uncertain.     

Responses of humpback whales to a changing climate in the Southern Hemisphere: Priorities for research efforts

Globally, baleen whales were severely depleted by historic whaling. Recovering populations have been observed to alter their behaviour. These changes have been attributed to climate change in some cases and raise concerns over the successful recovery of baleen whale populations. Current data-driven statistical habitat and behavioural models have proven useful for addressing questions of whale distribution changes within their limitations. Given observed changes in oceanic conditions, a new approach to managing baleen whale population recovery is necessary. Model predictions of future whale movements and distributions under climate change scenarios are vital to enable adequate conservation management. This paper presents a new perspective on understanding the impacts of climate change on humpback whales, arguing the need for a system-based multidisciplinary research approach. Our approach includes coupled, mechanistic models based upon robust ecological principles, and integrates key physical, biogeochemical, biological and ecological modules to address long-term changes associated with climate change. To illustrate the need for this system-based multidisciplinary approach, we focus on Southern Hemisphere humpback whales, the recovery of which may be impacted by rapid changes in habitat conditions brought about by anthropogenic climate change.     

Isotopic fingerprints of Milankovitch cycles in Pennsylvanian carbonate platform‐top deposits: the Valdorria record,Northern Spain

Sedimentary cyclic sequences deposited during the Late Palaeozoic Ice Age are widespread. Glacio‐eustatic control of the cyclic patterns is commonly accepted, and the durations of the cyclothems generally match the short‐ and long‐eccentricity Milankovitch orbital parameters. Nevertheless, geochemical fingerprints of orbital parameters are poorly documented in deep‐time sedimentary records. Here, we report on well‐exposed Bashkirian cyclothems of c. 123 ka and c. 400 ka durations from the Valdorria platform. The shorter‐term cyclothems can be grouped into longer‐term composite sequences that are consistent with generally accepted durations of c. 125 ka and c. 400 ka for Milankovitch eccentricity cycles. The stratigraphic pattern is mirrored by the isotope geochemical signals, which show distinct recurring trends. These trends are confirmed by statistical tests. Whereas intrinsic factors and/or subaerial exposure related to sea‐level lowstands might have truncated cycle patterns in tectonically stable basins, rapid subsidence of the Valdorria platform's foreland basin appears to have contributed to a faithful recording of cyclothems of different orders. The patterns and biostratigraphic constraint revealed in this study demonstrate the power of orbital forcing in imprinting sedimentary and geochemical signals in the rock record.     

Climate extremes in South Western Siberia: past and future

In this study, the temporal and spatial trends of ten climate extreme indices were computed based on observed daily precipitation and on daily maximum and minimum temperatures at 26 weather stations in South Western Siberia during the period 1969–2011 and, based on projected daily maximum and minimum temperatures, during 2021–2050. The Mann–Kendall test was employed to analyze the temporal trend and a combination of multiple linear regressions and semivariogram functions were used to evaluate the regional spatial trends and the local spatial variability of climate extremes, respectively. The results show that the temperature-based climate extremes increase at a 0.05 significance level while none of the precipitation-based climate extremes did. Spatially, dominant gradients are observed along latitude: The northern taiga vegetation zone experiences a colder and wetter climate while the southern forest steppe zone is drier and hotter. Over time, a tendency towards homogenization of the regional climate is observed through a decrease of the spatial variability for most climate extreme indices. In the future, the most intense changes are anticipated for the bio-climate indicators “growing season length” and “growing degree days” in the north, while the warming indicators, “warm day” and “warm night” are expected to be high to the south.     

Lateglacial and early Holocene summer temperatures in the southern Swiss Alps reconstructed using fossil chironomids

We present a Lateglacial and early Holocene chironomid‐based July air temperature reconstruction from Foppe (1470 m a.s.l.) in the Swiss Southern Alps. Our analysis suggests that chironomid assemblages have responded to major and minor climatic fluctuations during the past 17 000 years, such as the Oldest Dryas, the Younger Dryas and the Bølling/Allerød events in the Lateglacial and the Preboreal Oscillation at the beginning of the Holocene. Quantitative July air temperature estimates were produced by applying a combined Norwegian and Swiss temperature inference model consisting of 274 lakes to the fossil chironomid assemblages. The Foppe record infers average July air temperatures of ca. 9.9 °C during the Oldest Dryas, 12.2 °C during most of the Bølling/Allerød and 11.1 °C for the Younger Dryas. Mean July air temperatures during the Preboreal were 14 °C. Major temperature changes were observed at the Oldest Dryas/Bølling (+2.7 °C), the Allerød/Younger Dryas (?2 °C) and the Younger Dryas/Holocene transitions (+3.9 °C). The temperature reconstruction also shows centennial‐scale coolings of ca. 0.8–1.4 °C, which may be synchronous with the Aegelsee (Greenland Interstadial 1d) and the Preboreal Oscillations. A comparison of our results with other palaeoclimate records suggests noticeable temperature gradients across the Alps during the Lateglacial and early Holocene. Copyright © 2011 John Wiley & Sons, Ltd.     

Modelling background seismicity components identified by nearest neighbour and stochastic declustering approaches: the case of Northeastern Italy

Stochastic Environmental Research and Risk Assessment - An adequate characterization of the temporal features of background seismicity, namely after removal of temporally and spatially clustered...     

Structural and geochemical data on the Rio Magno Unit: evidence for a new 'Apenninic' ophiolitic unit in Alpine Corsica and its geodynamic implications

The Rio Magno Unit (RMU) tectonically overlies the Schistes Lustrés units in south-eastern Alpine Corsica. It is represented by an ophiolitic sequence, showing remarkable differences with respect to the commonly recognized Corsican ophiolites. This unit can be distinguished from the Schistes Lustrés by the lack of HP–LT metamorphism, reflecting its different geodynamic setting, although both were involved early in the same tectonic events. Similarly, the RMU can be distinguished from the Balagne Unit by the presence of normal-MORB basalts and the scarcity of continent-derived sedimentary input, testifying to a different oceanic palaeogeographical setting. Moreover, the petrochemical and stratigraphic features of the RMU ophiolitic sequence show close analogies with the Internal Ligurides of the Northern Apennines. The RMU represents the first record of a nonmetamorphic 'Apenninic'-type ophiolitic unit in Alpine Corsica, supporting the hypothesis that the Alpine Corsica – Northern Apennine system represents a double-vergent accretionary wedge.     

Stable (C,O) and radiogenic (Sr,Nd) isotopes of carbonates as indicators of magmatic and post-magmatic processes of phoscorite-series rocks and carbonatites from Catalão I,central Brazil

The Late-Cretaceous Catalão I contains stockworks of thin dykes of phoscorite-series rocks, which can be subdivided into P1 (olivine-bearing, phoscorites) and P2/P3 (olivine-lacking, nelsonites). Dolomite carbonatites (DC) are intimately associated with nelsonites, as pockets and dykes. The P2 apatite nelsonite, the P3 magnetite nelsonite, and, to a lesser extent DC, host the Catalão I niobium mineralization. C–O isotopes signatures in carbonates reveal several distinct magmatic and post-magmatic processes. Limpid carbonates with stable isotopic mantle-like composition show Rayleigh fractionation and are interpreted as primary, while those with brittle-turbid aspect, and higher oxygen isotope composition, probably underwent recrystallization by interaction with H₂O-rich fluids. A group of samples shows higher oxygen compositions and lower carbon values, which could be explained by degassing of carbonatite magma during cooling. A degassing pattern, parallel to magmatic degassing but at higher oxygen and lower carbon compositions, observed in carbonate veins, may indicate degassing of fracture filling fluids. Furthermore, C–O isotopes of carbonate from monazite-bearing carbonatite have a positive correlation, indicating a distinct, late-stage carbo-hydrothermal event. Though the Catalão I nelsonites and phoscorites are of igneous origin, they underwent several post-magmatic events, which sometimes overprinted partially or entirely the magmatic isotope signature.     

Stratospheric climate and variability from a general circulation model and observations

The climate and natural variability of the large-scale stratospheric circulation simulated by a newly developed general circulation model are evaluated against available global observations. The simulation consisted of a 30-year annual cycle integration performed with a comprehensive model of the troposphere and stratosphere. The observations consisted of a 15-year dataset from global operational analyses of the troposphere and stratosphere. The model evaluation concentrates on the simulation of the evolution of the extratropical stratospheric circulation in both hemispheres. The December–February climatology of the observed zonal mean winter circulation is found to be reasonably well captured by the model, although in the Northern Hemisphere upper stratosphere the simulated westerly winds are systematically stronger and a cold bias is apparent in the polar stratosphere. This Northern Hemisphere stratospheric cold bias virtually disappears during spring (March–May), consistent with a realistic simulation of the spring weakening of the mean westerly winds in the model. A considerable amount of monthly interannual variability is also found in the simulation in the Northern Hemisphere in late winter and early spring. The simulated interannual variability is predominantly caused by polar warmings of the stratosphere, in agreement with observations. The breakdown of the Northern Hemisphere stratospheric polar vortex appears therefore to occur in a realistic way in the model. However, in early winter the model severely underestimates the interannual variability, especially in the upper troposphere. The Southern Hemisphere winter (June–August) zonal mean temperature is systematically colder in the model, and the simulated winds are somewhat too strong in the upper stratosphere. Contrary to the results for the Northern Hemisphere spring, this model cold bias worsens during the Southern Hemisphere spring (September–November). Significant discrepancies between the model results and the observations are therefore found during the breakdown of the Southern Hemisphere polar vortex. For instance, the simulated Southern Hemisphere stratosphere westerly jet continuously decreases in intensity more or less in situ from June to November, while the observed stratospheric jet moves downward and poleward.This paper was presented at the Third International Conference on Modelling of Global Climate Change and Variability, held in Hamburg 4–8 Sept. 1995 under the auspice of the Max Planck Institute for Meteorology, Hamburg. Editor for these papers is L. Dümenil.