Geologic and infrastructure factors for delineating areas for clean coal: examples in Texas, USA

Texas has a wide variety of areas that can be targeted for new clean-coal facilities. These areas are delineated by mapping spatial linkages between coal- and lignite-bearing formations, groundwater and surface-water resources, and CO₂ sinks in brine formations for long-term CO₂ storage or in mature oil fields with potential for enhanced oil recovery (EOR). However, a variety of infrastructure factors make it feasible to also target numerous areas outside coal and lignite basins in Texas. These infrastructure factors include pipelines for delivery of CO₂ to subsurface sinks and delivery of coal-produced hydrogen to refineries, ease of connection to existing transmission lines, distribution of nonattainment areas where new clean-coal facilities could be constructed and be compliant with strict air-quality standards, and railroads that can transport coal and other feedstock to new clean-coal facilities. Primary regions in Texas where favorably co-located CO₂ source-sink factors related to coal and lignite trends include the Gulf Coast, the Eastern Shelf of the Permian Basin, and the Fort Worth Basin. However, areas outside coal and lignite basins, particularly the Permian Basin where a new clean-coal facility is being planned, also have clean-coal potential because of existing CO₂ pipelines and proximity to EOR fields that can economically sustain new clean-coal facilities.     

Comparative study of digestion methods EPA 3050B (HNO₃--H₂O₂--HCl) and ISO 11466.3 (aqua regia) for Cu, Ni and Pb contamination assessment in marine sediments

Knowing the metal extraction capacity of a digestion method is crucial for a better environmental interpretation of metal concentrations determined in sediments. One of the main problems at the present is the lack of harmonization of information obtained by two of the most popular sediment partial digestion methods: ISO 11466.3 (aqua regia) and EPA 3050B (HNO?--H?O?--HCl). In the present work, the amount of Cu, Ni and Pb leached by using both methods was compared with the total content of those elements in marine sediments collected, as an example, from the Cienfuegos Bay, Cuba. Similar amounts of Cu were extracted by both methods; while leaching of Ni and Pb were different. Generally, the EPA method extracted more Ni than the ISO method. In contrast, Pb was extracted in a larger amount by the ISO method. Some explanations are given for the observed results. X-ray Diffraction, X-ray Fluorescence, Particle Induced X-ray Emission Spectrometry and Energy Dispersive X-ray coupled to Scanning Electron Microscopy were employed for this purpose. On the other hand, none of the methods studied extracted simultaneously the fraction of all the metals, probably provided by human activity (Theoretical Anthropogenic Fraction) in both sediments studied. The use of ISO 11466.3 or EPA 3050B is recommended since the analytical performance parameters of both, in combination with Flame Atomic Absorption Spectrometry, are adequate. For a better environmental interpretation of the analytical results, information on the extraction efficiency of the selected method for specific elements and sediments under study should also be provided, together with the determined concentrations.     

Pigments in sediments beneath recently collapsed ice shelves: The case of Larsen A and B shelves,Antarctic Peninsula

In March 2002, 3200 km² of the Larsen B ice shelf collapsed off the Eastern Antarctic Peninsula (EAP). In the austral summer of 2006, sea floor sediment was recovered beneath the extinct Larsen B ice shelf and in a region off the Northern Antarctic Peninsula (NAP), which has been free of ice shelves for more than 1000 yr. To assess changes in the chemical composition of the sediment after ice shelf collapses, chlorophylls and pheophytins were measured in sediment cores at six stations. This is the first time that chlorophyll pigments have been analysed in sediment samples from regions under recently collapsed ice shelves. Five years after the ice shelf collapse, Chla and Chlc concentrations were similar in the interfacial sediment (upper 1 cm) of NAP and EAP regions. However, in EAP Chla and Chlc concentrations decreased more rapidly with depth in the sediment column and were negligible below 2 cm depth. The high Chla to Pheoa ratios indicated that sedimentary pigments found in EAP had undergone limited degradation suggesting that they were locally produced rather than laterally advected. Complementary information from excess ²¹⁰Pb activity and diatom valve distributions provided further evidence that the pigment fluxes to the seabed in EAP took place only after the ice shelf collapse.     

Bloom of the Yessotoxin producing dinoflagellate Protoceratium reticulatum (Dinophyceae) in Northern Chile

Potential spawning habitat is defined as the area where environmental conditions are suitable for spawning to occur. Spawning adult data from the first quarter (January–March) of the International Bottom Trawl Survey have been used to study the inter-annual variability of the potential spawning habitat of North Sea plaice from 1980 to 2007. Generalised additive models (GAM) were used to create a model that related five environmental variables (depth, bottom temperature and salinity, seabed stress and sediment type) to presence–absence and abundance of spawning adults. Then, the habitat model was applied each year from 1970 to 2007 to predict inter-annual variability of the potential spawning habitat. Predicted responses obtained by GAM for each year were mapped using kriging. A hierarchical classification associated with a correspondence analysis was performed to cluster spawning suitable areas and to determine how they evolved across years. The potential spawning habitat was consistent with historical spawning ground locations described in the literature from eggs surveys. It was also found that the potential spawning habitat varied across years. Suitable areas were located in the southern part of the North Sea and along the eastern coast of England and Scotland in the eighties; they expanded further north from the nineties. Annual survey distributions did not show such northward expansion and remained located in the southern North Sea. This suggests that this species' actual spatial distribution remains stable against changing environmental conditions, and that the potential spawning habitat is not fully occupied. Changes in environmental conditions appear to remain within plaice environmental ranges, meaning that other factors may control the spatial distribution of plaice spawning habitat.     

Recent observations of the WR central star of the planetary nebula LMC-N66

The recent evolution of the central star of the planetary nebula LMC-N66 is presented. Before 1987, it showed a weak continuum with aT _eff120 000 K andL _bol25 000L and in a few years it developed strong WR features (P Cygni line profiles in N v at 124.0 nm and C IV at 155.0 nm, wide Heii emission, etc.) typical of a WN 4.5. Additionally the stellar continuum increased by a large factor and the absolute visual magnitude of the star changed from + 1.24 in 1987 to–2.57 in January, 1995. The WR features and enhanced continuum, evidencing a powerful mass-loss event remained with small variations for more than 5 years. Recent ultraviolet and optical data shows that the mass-loss seems to have diminished abruptly in the last three months.     

Anatexis of interlayered amphibolite and pelite at 10 kbar: effect of diffusion of major components on phase relations and melt fraction

 We have conducted H₂O-undersaturated melting experiments on charges consisting of a layer of a sillimanite-bearing metapelite and a layer of garnet-bearing amphibolite, with the goal of studying how layered metamorphic rocks interact during anatexis. Experiments with the layered charges were performed at 10 kbar (1 GPa) at 900 °C (334 h), 925 °C (341 h), and 950 °C (50, 161, 332 h). Dehydration-melting of the amphibolite alone and of the pelite alone were studied at the same P-T conditions. When run alone at 900 °C, the pelite and the amphibolite yielded ca. 40 vol.% and 15 vol.% melt, respectively. Corresponding melt fractions at 950 °C were ca. 50 vol.% and 30 vol.%. When run side by side, melt abundance in the pelite is fairly uniform and ca. 20 vol.% higher than in the solo runs at all temperatures studied. In contrast, complex zoning patterns parallel to the interface develop in the amphibolite layer. Far from the interface the melt fraction is 5–10 vol.% lower than in the amphibolite-solo runs. Closer to the interface the melt fraction in the amphibolite layers are comparable to, or somewhat higher than, in the amphibolite-solo runs, and both clinopyroxene and plagioclase react-out and are replaced by orthopyroxene and quartz. Melt fraction closest to the interface reaches 65–70 vol.%, and the only crystalline phase present is garnet with hollow cores. The increase in melt fraction in the pelite layers of the layered runs is caused by transfer of Na from the amphibolite to the pelite, which forces biotite to be eliminated at lower temperature along the biotite-garnet reaction boundary. K is transferred from the pelite to the amphibolite, and the lower melt fraction in the distal end of the amphibolite layers is caused by faster diffusion of Na compared to K, which results in a net depletion of alkalies. Ca is transferred from the amphibolite to the pelite, and the resulting changes in CaO concentrations affect the stabilities of plagioclase, pyroxenes, garnet and quartz and cause the observed zoning in the amphibolite layer. Ca entering the pelite layer induces crystallization of large plagioclase neoblasts radiating from the interface into the pelite layer. These results show that diffusion of components between contiguous lithologies undergoing anatexis can cause profound changes in phase relations, melt fractions and restite compositions. Received: 21 December 1994 / Accepted: 26 June 1995     

Variations in some physico-chemical parameters in a hypersaline coastal lagoon of Baja California,Mexico

San Jose lagoon is a hypersaline body of water located in Mexico in the Baja California Peninsula. The lagoon belongs to a system that lies between the fault ridge known as San Jose Creek. Because of its marine origin, it can be considered as thalassohaline, but its isolation from the ocean has brought about changes in its salt composition. It has an area of 13,500 m², a mean depth of 80 cm and a total volume of 10,000 m³. It does not desiccate and can be considered as a permanent lagoon. Seasonal variations are small. TheArtemia population in San Jose produces cysts all year. To determine the physico-chemical conditions inducing permanent production of cysts, temperature, salinity, dissolved oxygen, and pH of the lagoon were monitored, as well as relative humidity and wind conditions in the region in different seasons of the year. From spring to summer, differences of 1 mg L^–1 of O₂, 1°C in water temperature, and 8 g L^–1 in salinity were observed, and from summer to winter differences of 3.3 mg L^–1, 6.5°C, and 14 g L^–1, respectively. Despite small seasonal variations, the lagoon exhibits strong spatial and daily changes that are important for cyst production.     

Surface measurements of carbon dioxide and methane at Alert during an Arctic haze event in April, 1986

Carbon dioxide (CO₂) has been measured at Alert by grab flask sampling since 1975 as part of the World Meteorological Organization's Background Air Pollution Monitoring Program. Deviations of CO₂ concentration from the mean annual cycle have previously been attributed to air masses arriving at Alert from the source regions of the industrialized parts of Europe and the Soviet Union. In situ measurements of ambient CO₂ and methane (CH₄) were made at Alert using an automated gas chromatograph, as part of the Arctic Haze Study during April 1986. The temporal behaviour of CO₂ and CH₄ during this period was found to be highly correlated with measurements of particulate sulphate and other atmospheric trace species of anthropogenic origin. Examination of calculated air mass back-trajectories provided further evidence that the observed short-term increases in CO₂ and CH₄ mixing ratios were due to long-range transport from anthropogenic source regions.     

A digital surface roughness meter

Geomorphological studies often require precise devices to measure surface roughness or variations with high precision and good repeatability. A digital measurement device is described, which provides these features and can be linked to a small, light and portable recorder and processor. Such an arrangement allows rapid, accurate data recording by a single operator and can be used in the laboratory or field. With interchangeable measurement rods the vertical range of the instrument is 150 mm, with an actual measured range of 30 mm per rod. The potential accuracy is 0·001 mm with an operating temperature range of+5 to +40°C. Its light weight, relatively low cost and precision make it a useful measuring device which can be adapted for many tasks simply by modification of the stand.     

Basic statistical characteristics of hourly rainfall amounts in Barcelona (Spain)

Summary In order to derive some statistical rainfall characteristics applicable to hydrology, data of continuous rainfall rate recordings of a Jardí gauge installed in Barcelona (Spain) have been converted to an hourly precipitation series. From these data, four useful distributions have been obtained and further compared with some theoretical models. It has been found that the duration of events is distributed exponentially. The duration of rainless intervals follow a generalized Pareto distribution, and the cumulative rainfall in the cumulative rain duration is beta distributed. Concerning the distribution of rain amounts, two models can be accepted, depending on the duration of the events. Comparison with a similar study carried out in Farnborough (United Kingdom) indicates that the events are shorter and that the amounts of rain collected in short events are larger in Barcelona.This work was supported by the DGICYT (Project NAT91-0596) and the CCE (Project PL 910104 Environment).With 7 Figures