Tetrad effects in REE abundance patterns of chondrules from CM meteorites: Implications for aqueous alteration on the CM parent asteroid

Lanthanide tetrad effect in bulk chondrules from two moderately altered CM chondrites, Murchison and Yamato-793321 (Y-793321), are reported for the first time. Twenty-three chondrules were petrographically characterized and analyzed for 10 rare earth elements (REE) and other trace and major elements (Ba, Sr, Rb, K, Ca, Mg and Fe) using the precise isotope dilution technique. The results indicate systematic depletion (several times) of alkali and alkaline earths compared to CV and CO chondrules. Most of the porphyritic olivine (8 PO) and olivine-pyroxene (4 POP), porphyritic and radial pyroxene (2 PP, 1 RP), and granular olivine (1 GO) chondrules show a light-REE (L-REE) depleted, heavy-REE (H-REE) smoothly fractionated pattern composed of four (upward convex) segments possessing a relatively large negative Eu anomaly (CI-normalized La/Sm, Lu/Er and Eu/Eu* ratios = 0.3-1: Eu*, normal value). On the other hand, all barred-olivine (5 BO) chondrules, a few PO and POP indicate almost a flat L-REE pattern. In addition, regardless of their textural types, nearly half of the chondrules have a variable degree of Ce and Yb anomalies, and/or L/H-REE discontinuity, which is similar to CV and CO chondrules. The observed L- and H-convex REE patterns accompanied with the negative Eu anomaly is the first known case for chondrules as well as meteoritic materials, but have been previously reported for geological samples such as sedimentary rocks, late stage igneous and metamorphic rocks, and are explained as the lanthanide tetrad effect, which plausibly results from fluid-rock interaction. We suggest that the marked REE fractionations occurred by the selective incorporation of L-, H-REEs and Eu into alteration products in the matrix during alteration processes on the CM parent body, but that the gas/solid REE fractionation characteristics established in the nebula have basically remained unchanged. We suggest that the tetrad effects observed here represent a new index of physico-chemical conditions of fluid-rock interactions prevalent on the CM parent body.     

Assessing the role of forests in mitigating eutrophication downstream of pasture during spring snowmelt

Little research has examined whether forests reduce stream water eutrophication in agricultural areas during spring snowmelt periods. This study evaluated the role of forests in ameliorating deteriorated stream water quality in agricultural areas, including pasture, during snowmelt periods. Temporal variation in stream water quality at a mixed land‐use basin (565 ha: pasture 13%, forestry 87%), northern Japan, was monitored for 7 years. Synoptic stream water sampling was also conducted at 16 sites across a wide range of forest and agricultural areas in a basin (18.3 km²) in spring, summer and fall. Atmospheric nitrogen (N) and phosphorus (P) deposition were measured for 4 years. The results showed that concentration pulses of nitrate, organic N and total P in stream water were observed when discharge increased during spring snowmelt. Their concentrations were high when silicate concentrations were low, suggesting surface water exported from pasture largely contributed to stream water pollution during snowmelt. Atmospheric N and P deposition (4.1 kg N ha^?1 y^?1; 0.09 kg P ha^?1 y^?1, respectively) was too low to affect the background concentrations of N and P in streams from forested areas. Reduction of eutrophication caused by nutrients from pasture was mainly due to dilution by water containing low concentrations of N and P exported from forested areas, whereas in‐stream reduction was not a dominant process. Results indicate that forests have a limited capacity to reduce the concentration pulses of N and P in stream water during snowmelt in this study basin. Copyright © 2014 John Wiley & Sons, Ltd.     

Real-time hybrid experimental system with actuator delay compensation and its application to a piping system with energy absorber

A real-time hybrid experimental method, in which output from an actuator-excited vibration experiment and response calculation are combined on-line and conducted simultaneously in real time, is being developed as a new seismic experimental method for structural systems. In real-time hybrid experiments, however, there is an inevitable actuator-response delay, which has an effect equivalent to negative damping. To solve this problem, a real-time hybrid experimental system (including an actuator-delay compensation method) was developed. And seismic experiments were conducted in order to demonstrate the advantages of this system. Experimental results obtained using the developed hybrid experimental system were compared with exact results obtained using shaking-table experiments, and it was found that the two experimental methods gave almost identical results. It can therefore be concluded that the structural response can be obtained precisely by using the developed hybrid experimental system. Comparison of these experiments showed the advantages of the hybrid experiments; that is, they are simple and economical. This is because the hybrid experiment requires only a small structure as the excitation model, while a shaking-table experiment must consider the whole structural system. Copyright © 1999 John Wiley & Sons, Ltd.     

Three-dimensional antidunes coexisting with alternate bars

Antidunes are fluvial bedforms that form in rivers with supercritical flows. The water surface over antidunes is strongly in phase with the bed surface, and the water surface is amplified to produce large surface waves. Many experimental studies have addressed antidunes; however, the shapes of three-dimensional antidunes in a wide channel with alternate bars have not yet been appropriately understood. In this study, we experimentally investigated the streamwise and transverse length scales of antidunes under conditions with a large width–depth ratio. Our experimental results provide evidence for the coevolution of antidunes and free alternate bars, and show for the first time that the development of free bars greatly alters the three-dimensional shape of water surface waves over antidunes. In the absence of free bars in a wide channel, multiple longitudinal wave trains form, and the number of wave trains counted in the transverse direction increases with increases in the width–depth ratio. However, the presence of free bars affects the local flow characteristics, resulting in a decrease of the number of wave trains in the transverse direction. Therefore, we propose a simple model for predicting the reduction in the number of wave trains by combining two previous theories for antidunes and free bars. Results obtained by the model were found to largely agree with experimental observations. © 2020 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd     

VSOP Space VLBI observations of Pearson-Readhead survey sources

The VSOP Space VLBI mission uses the HALCA spacecraft, launched from Japan in February 1997, in conjunction with ground radio observatories around the world to create a high resolution radio-wavelength imaging facility. We are using this unique facility to observe a sub-sample of Pearson-Readhead Survey sources at 4.8 GHz to determine core brightness temperatures and pc-scale jet properties. We will highlight one of the sources that has been observed using a combination of the HALCA spacecraft and the EVN, 1642+690, and describe the preliminary brightness temperature distribution for the sub-sample, based on all data analyzed to date.     

Age of the Solomon Sea Basin from magnetic lineations

Magnetic anomalies measured in the central to western half of the Solomon Sea, when considered with other magnetic data, reveal the existence of linear patterns. Magnetic lineation anomaly models of the Cenozoic, 65 to 0 Ma, suggest that an age between 34 and 28 Ma and a half-rate spreading speed of 5.8 cm/yr for the northern flank of a former spreading center best fits our present magnetic data in the Solomon Sea Basin. Heat flow and bathymetry data support this preferred model.     

A new high-stress undrained ring-shear apparatus and its application to the 1792 Unzen–Mayuyama megaslide in Japan

Sassa and others in the Disaster Prevention Research Institute (DPRI), Kyoto University, developed a series of undrained ring-shear apparatus to physically simulate landslide initiation and motion, from DPRI-3 (Sassa 1992) to DPRI-7 (Sassa et al., Landslides 1(1):7–19, 2004). The maximum undrained capacities in the DPRI series ranged from 300 to 650 kPa. Sassa and others in the International Consortium on Landslides (ICL) have developed a new series of undrained ring-shear apparatus (ICL-1and ICL-2) for two projects of the International Programme on Landslides (IPL-161 and IPL-175). Both projects are supported by the Science and Technology Research Partnership for Sustainable Development Program (SATREPS) of Japan. ICL-1 was developed to create a compact and transportable apparatus for practical use in Croatia; one set was donated to Croatia in 2012. ICL-2 was developed in 2012–2013 to simulate the initiation and motion of megaslides of more than 100 m in thickness. The successful undrained capacity of ICL-2 is 3 MPa. This apparatus was applied to simulate possible conditions for the initiation and motion of the 1792 Unzen–Mayuyama megaslide (volume, 3.4?×?10⁸ m³; maximum depth, 400 m) triggered by an earthquake. The megaslide and resulting tsunami killed about 15,000 people. The Unzen Restoration Office of the Ministry of Land, Infrastructure and Transport (MLIT) of Japan systematically collected various papers and reports and published two summary leaflets: one in English in 2002 and an extended version in Japanese in 2003. Samples were taken from the source area (for initiation) and the moving area (for motion). The hazard area was estimated by the integrated landslide simulation model LS-RAPID, using parameters obtained with the ICL-2 undrained ring-shear apparatus. The estimated hazard area agrees reasonably with the landslide moving area reported in the Ministry leaflets.     

Relationship between surface morphology and chemical composition of spheroidal carbonaceous particles within sediment core samples recovered from Osaka Bay,Japan

Spheroidal carbonaceous particles (SCPs) are produced by the high-temperature combustion of fossil fuels and are emitted to the atmosphere. Previous studies are divided regarding whether SCPs derived from the combustion of various fossil fuels can be identified based on their surface morphologies and chemical compositions. In this study, we examined the surface morphology and chemical composition of SCPs in sediment core samples collected from Osaka Bay, Japan, with the aim of evaluating the usefulness of SCPs morphology in identifying their origin. Scanning electron microscope (SEM) observations reveal three distinct surface morphologies: (1) smooth, (2) rough and irregular, and (3) convoluted and layered. According to a morphological classification scheme proposed previously, the former two morphologies correspond to coal-derived carbon particles, whereas the latter corresponds to oil-derived carbon particles. In terms of the chemical compositions of the particles with different morphologies, as analyzed by energy-dispersive spectroscopy, linear discriminant analysis reveals that the two fuel types can be distinguished. An overall success rate of >90% of reference of morphologically classified material correctly assigned to two groups that are chemically different each other, indicating a relationship between surface morphology and chemical composition. This result suggests that morphological characterization based on conventional SEM observations is useful in identifying the source fuel of SCPs.     

The spatial and temporal distributions of spheroidal carbonaceous particles from sediment core samples from industrial cities in Japan and China

Spheroidal carbonaceous particles (SCPs) are produced by the high-temperature combustion of fossil fuels and emitted in to the atmosphere. The distribution and concentration of SCPs in sediments have been used as a proxy for the distribution of pollutants emitted to the atmosphere. However, the effect on the distribution of SCPs due to industrial activity at nearby industrial cities is yet to be quantified. To clarify the origin of SCPs of ~20 μm in size that are preserved in sediments, we evaluated the abundance, surface morphology, and chemical composition of SCPs in sediment core samples recovered from industrial cities in Japan (Tokyo, Osaka, and Nagasaki) and China (Beijing), with the cities being located at least ~500 km away from each other. Vertical profiles of SCP concentration in sediment cores from the Japanese cities and Beijing are different, reflecting the contrasting industrial histories of the two countries. The SCPs from different cities show contrasting morphological and chemical characteristics, suggesting that ~20 μm SCPs in sediments from the industrial cities could represent the local combustion history in detail, as the influx of local SCPs is dominant at such sites.