Chemical classification of iron meteorites—VIII. Groups IC. IIE,IIIF and 97 other irons

Concentrations of Ni, Ga, Ge and Ir in 106 iron meteorites are reported. Three new groups are defined: IC, IIE and IIIF containing 10, 12 and 5 members, respectively, raising the number of independent groups to 12. Group IC is a cohenite-rich group distantly related to IA. Group IIE consists of those irons previously designated Weekeroo Station type and five others having similar compositions though diverse structures. The IIE irons are compositionally similar to the mesosiderites and pallasites, and the three groups probably formed at similar heliocentric distances. The mixing of the globular IIE silicates with the metal probably occurred during shock events. Group IIIF is a well-defined group of low-Ni and low-Ge irons. The compositions of these groups are summarized as follows:

     

152.

Greatlakean Substage: A replacement for Valderan Substage in the Lake Michigan basin     

Edward B. Evenson  William R. Farrand  Donald F. Eschman  David M. Mickelson  Louis J. Maher 《Quaternary Research》1976,6(3):411-424

New evidence from recent field and seismic investigations in the Lake Michigan basin and in the type areas of the Valders, Two Creeks and Two Rivers deposits necessitates revision of late-glacial ice-front positions, rock- and time-stratigraphic nomenclature and climatic interpretations and deglaciation patterns for the period ca. 14,000–7,000 radiocarbon years B.P. The previously reported and long accepted pattern of deglaciation for the Lake Michigan basin started with a regular retreat from the Lake Border Morainic System, with a minor oscillation marked by the Port Huron moraine(s) and then an extensive Twocreekan deglaciation followed by a major (320 km) post-Twocreekan advance (Valders). However, we now record a major retreat between the times of the Lake Border and Port Huron moraines, followed by a gradual retreat from the Port Huron limit and interrupted by a minor standstill (deposition of Manitowoc Till), a retreat (Twocreekan) and a readvance (Two Rivers Till). No Woodfordian or younger readvance was as extensive as had been the preceding one. This sequence argues for a normal, climatically controlled, progressive deglaciation rather than one interrupted by a major post-Twocreekan (formerly Valderan) surge. This revision appears finally to harmonize the geologic evidence and the palynological record for the Great Lakes region. Our investigations show that Valders Till from which the Valderan Substage was named is late-Woodfordian in age. We propose the term “Greatlakean” as a replacement for the now misleading time-stratigraphic term “Valderan”. The type section and the definition of the upper and lower boundaries of the Greatlakean Substage remain the same as those originally proposed for the Valderan Substage but the name is changed.     

153.

Chronology of cenozoic igneous and tectonic events in the central Chilean Andes — latitudes 35° 30′ to 36°S     

Robert Edward Drake 《Journal of Volcanology and Geothermal Research》1976,1(3):265-284

Sixty-six K---Ar dates from igneous rocks in the central Chilean Andes between 33° and 38°S are reported in this study. From these results and observed field relations, major Cenozoic volcanic and intrusive rock units are divided into chronologic groups representing igneous events.Volcanic units of Oligocene (33.3–27.9 m.y.) and Early Miocene (20.2 m.y.) age have been dated west of the present range at 33°S but neither the magnitude nor extent of these volcanic events has yet been established. Extensive Middle to Late Miocene volcanism (15.3–6.4 m.y.) followed by regional folding is recognized in the map area between 35° 20′ and 36°S. Partly contemporaneous Middle Miocene volcanism (18.4–13.7 m.y.) also followed by regional folding is recorded in the Andes between 37° 30′ and 38°S. General volcanic quiescence from 6.4 to 2.5 m.y. is observed in the map area but whether this volcanic hiatus is of regional significance is not known.The majority of the K---Ar dates document a history of nearly continuous volcanism throughout the last 2.5 m.y. in the map area. The abundant and diverse sequences of volcanic strata formed during this time, have been divided into four successive age groups which as map units show the evolution and distribution of latest volcanic activity.Landforms preserved by this volcanic series show that topographic relief similar to the present has prevailed during this time. Deep incision of rivers into young volcanic terrain, estimated to be on the order of 1–2 m/1000 years, has produced a complex volcanic and morphologic record.Four plutons dated in this study give ages of 62.0, 41.3, 19.5, and 7.0 m.y. No spatial pattern of emplacement is observed in the map area where three of these plutons are represented.Similarities in structural style, orientation and degree of deformation of Miocene and Mesozoic strata suggest that Late Miocene regional folding may have accounted for a significant part of the observed deformation in older basement strata previously ascribed to earlier orogenies.A regional comparison of ages of recognized igneous and tectonic event at different latitudes in the central and southern Andes shows the gross chronology of Cenozoic events which can be correlated with sea-floor spreading and subduction events.     

154.

The training of marine pollution scientists     

Edward D Goldberg 《Marine pollution bulletin》1977,8(11):241

     

155.

Formation of olivine-metal textures in pallasite meteorites     

Edward R.D Scott 《Geochimica et cosmochimica acta》1977,41(6):693-710

The olivine-metal textures of pallasites help elucidate the formation of these meteorites. Large sections of pallasites with angular olivines commonly contain olivine masses 5–30 cm in size, which appear to have been disintegrating into smaller fragments, like those dispersed through the metal. It is suggested that these masses were parts of olivine layers, which were intruded by underlying molten metal. Gravitational separation of olivine and metal was probably prevented by incipient solidification of metal.Pallasites with rounded olivines probably had a fairly similar history, but with additional annealing after metal solidification had started. Grain boundary energy was reduced by decreasing the area of metal-olivine interface and increasing the contact between touching olivines. Because of the vastly different nature of metal and olivine, their mutual interfacial energy is high and the degree of anisotropy of this energy is low. The occurrence of profuse, small faces on rounded olivines is therefore consistent with the ‘metamorphic’ origin which is proposed for rounded olivines. In many pallasites with angularolivine macrostructures, magnifications of 5–50 × reveal similar rounding effects, including aggregates of rounded olivines, and individual crystals which may be faceted.The high metal-troilite ratio of Phillips County suggests that this pallasite formed by mixing of olivine with S-rich liquid metal around 1000°C, near the Fe-FeS eutectic temperature.     

156.

Episodic Cenozoic volcanism and tectonism in the Andes of Peru     

Donald C. Noble  Edwin H. McKee  Edward Farrar  Ulrich Petersen 《Earth and Planetary Science Letters》1974,21(2):213-220

Radiometric and geologic information indicate a complex history of Cenozoic volcanism and tectonism in the central Andes. K-Ar ages on silicic pyroclastic rocks demonstrate major volcanic activity in central and southern Peru, northern Chile, and adjacent areas during the Early and Middle Miocene, and provide additional evidence for volcanism during the Late Eocene. A provisional outline of tectonic and volcanic events in the Peruvian Andes during the Cenozoic includes: one or more pulses of igneous activity and intense deformation during the Paleocene and Eocene; a period of quiescence, lasting most of Oligocene time; reinception of tectonism and volcanism at the beginning of the Miocene; and a major pulse of deformation in the Middle Miocene accompanied and followed through the Pliocene by intense volcanism and plutonism. Reinception of igneous activity and tectonism at about the Oligocene-Miocene boundary, a feature recognized in other circum-Pacific regions, may reflect an increase in the rate of rotation of the Pacific plate relative to fixed or quasifixed mantle coordinates. Middle Miocene tectonism and latest Tertiary volcanism correlates with and probably is genetically related to the beginning of very rapid spreading at the East Pacific Rise.     

157.

Distribution of gold and rhenium between nickel-iron and silicate melts: implications for the abundance of siderophile elements on the Earth and Moon     

Kan Kimura  Roy S Lewis  Edward Anders 《Geochimica et cosmochimica acta》1974,38(5):683-701

The distribution equilibrium of Au and Re between nickel-iron and basaltic melts was studied at 1400–1600°C, using radioactive tracers. Metal/silicate distribution coefficients were 1–3 orders of magnitude higher than earlier estimates, as follows. Mauna Loa basalt—Fe₁₀Ni₉₀: D_Au = 3.3 × 10⁴, D_Re = (2.4?89) × 10⁴. Gorda Ridge basalt—Fe₁₀Ni₉₀: D_Au = (18?75) × 10⁴. Synthetic lunar basalt—Fe₇₀ Ni₃₀: D_Au≥ 2 × 10⁴, D_Re ≥ 2 × 10³. The experimental ΔG₁₈₀₀^° for the distribution of Au between nickel-iron and Mauna Loa basalt is ?40 kcal/mole, compared to a calculated value of about ?110 kcal/mole for a reaction involving simple Au³⁺ ions. Presumably the difference represents stabilization of Au(III) by complex formation with ligands such as Cl^?, H₂O, etc.Gold abundances in lunar basalts are roughly consistent with the measured D_Au, but those in terrestrial basalts are two orders of magnitude too high. This discrepancy may reflect complexing by volatiles in the Earth's upper lithosphere, as well as oxidative destruction of metal in the final stages of accretion. In the absence of a metal phase, siderophile trace elements would remain trapped in the upper mantle and crust.     

158.

Land cover change detection in West Jilin using ETM ＋ images     

EdwardM.Osei Jr. ZHOUYun-xuan 《东北亚地学研究》2004,7(1):74-84

In order to assess the information content and accuracy of Landsat ETM digital images in land cover change detection,change-detection techniques of image differencing, normalized difference vegetation index,principal components analysis and tasseled-cap transformation were applied to yield 13 images. These images were thresholded into change and no change areas. The thresholded images were then checked in terms of various accuracies. The experiment results show that kappa coefficients of the 13 images range from 48.05-78.09. Different images do detect different types of changes. Images associated with changes in the near-inflared-reflectance or greenness detects crop-type changes and changes between vegetative and non-vegetative features. A unique means of using only Landsat imagery without reference data for the assessment of change in arid land are presented. Images of 12t June, 2000 and 2‘d June, 2002 are used to validate the means. Analyses of standard accuracy and spatial agreement are performed to compare the new images (hereafter called “change images” ) representing the change between the two dates. Spatial agreement evaluates the conformity in the classified “change pixels” and “no-change pixels” at the same location on different change images and comprehensively examines the different techniques. This method would enable authorities to monitor land degradation efficiently and aeculately.     

159.

Hyperspectral mapping of alteration assemblages within a hydrothermal vug at the Haughton impact structure,Canada          下载免费PDF全文

Rebecca N. Greenberger  John F. Mustard  Gordon R. Osinski  Livio L. Tornabene  Alexandra J. Pontefract  Cassandra L. Marion  Roberta L. Flemming  Janette H. Wilson  Edward A. Cloutis 《Meteoritics & planetary science》2016,51(12):2274-2292

Meteorite impacts on Earth and Mars can generate hydrothermal systems that alter the primary mineralogies of rocks and provide suitable environments for microbial colonization. We investigate a calcite–marcasite‐bearing vug at the ~23 km diameter Haughton impact structure, Devon Island, Nunavut, Canada, using imaging spectroscopy of the outcrop in the field (0.65–1.1 μm) and samples in the laboratory (0.4–2.5 μm), point spectroscopy (0.35–2.5 μm), major element chemistry, and X‐ray diffraction analyses. The mineral assemblages mapped at the outcrop include marcasite; marcasite with minor gypsum and jarosite; fibroferrite and copiapite with minor gypsum and melanterite; gypsum, Fe³⁺ oxides, and jarosite; and calcite, gypsum, clay, microcline, and quartz. Hyperspectral mapping of alteration phases shows spatial patterns that illuminate changes in alteration conditions and formation of specific mineral phases. Marcasite formed from the postimpact hydrothermal system under reducing conditions, while subsequent weathering oxidized the marcasite at low temperatures and water/rock ratios. The acidic fluids resulting from the oxidation collected on flat‐lying portions of the outcrop, precipitating fibroferrite + copiapite. That assemblage then likely dissolved, and the changing chemistry and pH resulting from interaction with the calcite‐rich host rock formed gypsum‐bearing red coatings. These results have implications for understanding water–rock interactions and habitabilities at this site and on Mars.     

160.

How Bedrock‐Controlled Channel Migration Can Structure Selective Preservation of Archaeological Sites: Implications for Modeling Paleoindian Settlement     

Edward W. Herrmann 《Geoarchaeology》2016,31(1):58-74

Although Paleoindian sites in Indiana, USA, are commonly located on late Wisconsin (Last Glacial Maximum) outwash terraces, drainage basin development since deglaciation often obscures the visibility of such sites on flood plains by either burying them under alluvium or destroying them through erosion. Significant clusters of Paleoindian and Early Archaic sites, however, have been identified proximal to the modern White River channel in central Indiana on what is mapped as “floodplain.” These site cluster locations are patterned. They typically occur within bedrock‐controlled river reaches but are rare along unconfined meandering reaches. Subsurface reconnaissance and chronology indicate that despite the fact that they often flood, portions of the so‐called flood plains within bedrock‐confined reaches are actually terraces constructed of late Wisconsin outwash with minimal overbank sedimentation. Terrace preservation in these settings is a result of bedrock structure that protects older sediments from lateral erosion and differentially preserves archaeological sites near the modern channel in bedrock‐controlled reaches. Comparisons of archaeological sites within bedrock‐controlled segments of the White River to those in unconfined meandering segments suggests that significant numbers of Paleoindian and Early Archaic sites may be missing from river settings across the midcontinent. These findings demonstrate that bedrock channel controls are important to recognize when assessing prehistoric settlement distributions.     

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Group	Ni (%)	Ga (ppm)	Ge (ppm)	Ir (ppm)
IC	6.1–6.8	42–54	85–250	0.07–10
IIE	7.5–9.7	21–28	62–75	0.5–8
IIIF	6.8–7.8	6.3–7.2	0.7–1.1	1.3–7.9

Greatlakean Substage: A replacement for Valderan Substage in the Lake Michigan basin

New evidence from recent field and seismic investigations in the Lake Michigan basin and in the type areas of the Valders, Two Creeks and Two Rivers deposits necessitates revision of late-glacial ice-front positions, rock- and time-stratigraphic nomenclature and climatic interpretations and deglaciation patterns for the period ca. 14,000–7,000 radiocarbon years B.P. The previously reported and long accepted pattern of deglaciation for the Lake Michigan basin started with a regular retreat from the Lake Border Morainic System, with a minor oscillation marked by the Port Huron moraine(s) and then an extensive Twocreekan deglaciation followed by a major (320 km) post-Twocreekan advance (Valders). However, we now record a major retreat between the times of the Lake Border and Port Huron moraines, followed by a gradual retreat from the Port Huron limit and interrupted by a minor standstill (deposition of Manitowoc Till), a retreat (Twocreekan) and a readvance (Two Rivers Till). No Woodfordian or younger readvance was as extensive as had been the preceding one. This sequence argues for a normal, climatically controlled, progressive deglaciation rather than one interrupted by a major post-Twocreekan (formerly Valderan) surge. This revision appears finally to harmonize the geologic evidence and the palynological record for the Great Lakes region. Our investigations show that Valders Till from which the Valderan Substage was named is late-Woodfordian in age. We propose the term “Greatlakean” as a replacement for the now misleading time-stratigraphic term “Valderan”. The type section and the definition of the upper and lower boundaries of the Greatlakean Substage remain the same as those originally proposed for the Valderan Substage but the name is changed.     

Chronology of cenozoic igneous and tectonic events in the central Chilean Andes — latitudes 35° 30′ to 36°S

Sixty-six K---Ar dates from igneous rocks in the central Chilean Andes between 33° and 38°S are reported in this study. From these results and observed field relations, major Cenozoic volcanic and intrusive rock units are divided into chronologic groups representing igneous events.Volcanic units of Oligocene (33.3–27.9 m.y.) and Early Miocene (20.2 m.y.) age have been dated west of the present range at 33°S but neither the magnitude nor extent of these volcanic events has yet been established. Extensive Middle to Late Miocene volcanism (15.3–6.4 m.y.) followed by regional folding is recognized in the map area between 35° 20′ and 36°S. Partly contemporaneous Middle Miocene volcanism (18.4–13.7 m.y.) also followed by regional folding is recorded in the Andes between 37° 30′ and 38°S. General volcanic quiescence from 6.4 to 2.5 m.y. is observed in the map area but whether this volcanic hiatus is of regional significance is not known.The majority of the K---Ar dates document a history of nearly continuous volcanism throughout the last 2.5 m.y. in the map area. The abundant and diverse sequences of volcanic strata formed during this time, have been divided into four successive age groups which as map units show the evolution and distribution of latest volcanic activity.Landforms preserved by this volcanic series show that topographic relief similar to the present has prevailed during this time. Deep incision of rivers into young volcanic terrain, estimated to be on the order of 1–2 m/1000 years, has produced a complex volcanic and morphologic record.Four plutons dated in this study give ages of 62.0, 41.3, 19.5, and 7.0 m.y. No spatial pattern of emplacement is observed in the map area where three of these plutons are represented.Similarities in structural style, orientation and degree of deformation of Miocene and Mesozoic strata suggest that Late Miocene regional folding may have accounted for a significant part of the observed deformation in older basement strata previously ascribed to earlier orogenies.A regional comparison of ages of recognized igneous and tectonic event at different latitudes in the central and southern Andes shows the gross chronology of Cenozoic events which can be correlated with sea-floor spreading and subduction events.     

Formation of olivine-metal textures in pallasite meteorites

The olivine-metal textures of pallasites help elucidate the formation of these meteorites. Large sections of pallasites with angular olivines commonly contain olivine masses 5–30 cm in size, which appear to have been disintegrating into smaller fragments, like those dispersed through the metal. It is suggested that these masses were parts of olivine layers, which were intruded by underlying molten metal. Gravitational separation of olivine and metal was probably prevented by incipient solidification of metal.Pallasites with rounded olivines probably had a fairly similar history, but with additional annealing after metal solidification had started. Grain boundary energy was reduced by decreasing the area of metal-olivine interface and increasing the contact between touching olivines. Because of the vastly different nature of metal and olivine, their mutual interfacial energy is high and the degree of anisotropy of this energy is low. The occurrence of profuse, small faces on rounded olivines is therefore consistent with the ‘metamorphic’ origin which is proposed for rounded olivines. In many pallasites with angularolivine macrostructures, magnifications of 5–50 × reveal similar rounding effects, including aggregates of rounded olivines, and individual crystals which may be faceted.The high metal-troilite ratio of Phillips County suggests that this pallasite formed by mixing of olivine with S-rich liquid metal around 1000°C, near the Fe-FeS eutectic temperature.     

Episodic Cenozoic volcanism and tectonism in the Andes of Peru

Radiometric and geologic information indicate a complex history of Cenozoic volcanism and tectonism in the central Andes. K-Ar ages on silicic pyroclastic rocks demonstrate major volcanic activity in central and southern Peru, northern Chile, and adjacent areas during the Early and Middle Miocene, and provide additional evidence for volcanism during the Late Eocene. A provisional outline of tectonic and volcanic events in the Peruvian Andes during the Cenozoic includes: one or more pulses of igneous activity and intense deformation during the Paleocene and Eocene; a period of quiescence, lasting most of Oligocene time; reinception of tectonism and volcanism at the beginning of the Miocene; and a major pulse of deformation in the Middle Miocene accompanied and followed through the Pliocene by intense volcanism and plutonism. Reinception of igneous activity and tectonism at about the Oligocene-Miocene boundary, a feature recognized in other circum-Pacific regions, may reflect an increase in the rate of rotation of the Pacific plate relative to fixed or quasifixed mantle coordinates. Middle Miocene tectonism and latest Tertiary volcanism correlates with and probably is genetically related to the beginning of very rapid spreading at the East Pacific Rise.     

Distribution of gold and rhenium between nickel-iron and silicate melts: implications for the abundance of siderophile elements on the Earth and Moon

The distribution equilibrium of Au and Re between nickel-iron and basaltic melts was studied at 1400–1600°C, using radioactive tracers. Metal/silicate distribution coefficients were 1–3 orders of magnitude higher than earlier estimates, as follows. Mauna Loa basalt—Fe₁₀Ni₉₀: D_Au = 3.3 × 10⁴, D_Re = (2.4?89) × 10⁴. Gorda Ridge basalt—Fe₁₀Ni₉₀: D_Au = (18?75) × 10⁴. Synthetic lunar basalt—Fe₇₀ Ni₃₀: D_Au≥ 2 × 10⁴, D_Re ≥ 2 × 10³. The experimental ΔG₁₈₀₀^° for the distribution of Au between nickel-iron and Mauna Loa basalt is ?40 kcal/mole, compared to a calculated value of about ?110 kcal/mole for a reaction involving simple Au³⁺ ions. Presumably the difference represents stabilization of Au(III) by complex formation with ligands such as Cl^?, H₂O, etc.Gold abundances in lunar basalts are roughly consistent with the measured D_Au, but those in terrestrial basalts are two orders of magnitude too high. This discrepancy may reflect complexing by volatiles in the Earth's upper lithosphere, as well as oxidative destruction of metal in the final stages of accretion. In the absence of a metal phase, siderophile trace elements would remain trapped in the upper mantle and crust.     

Land cover change detection in West Jilin using ETM ＋ images

In order to assess the information content and accuracy of Landsat ETM digital images in land cover change detection,change-detection techniques of image differencing, normalized difference vegetation index,principal components analysis and tasseled-cap transformation were applied to yield 13 images. These images were thresholded into change and no change areas. The thresholded images were then checked in terms of various accuracies. The experiment results show that kappa coefficients of the 13 images range from 48.05-78.09. Different images do detect different types of changes. Images associated with changes in the near-inflared-reflectance or greenness detects crop-type changes and changes between vegetative and non-vegetative features. A unique means of using only Landsat imagery without reference data for the assessment of change in arid land are presented. Images of 12t June, 2000 and 2‘d June, 2002 are used to validate the means. Analyses of standard accuracy and spatial agreement are performed to compare the new images (hereafter called “change images” ) representing the change between the two dates. Spatial agreement evaluates the conformity in the classified “change pixels” and “no-change pixels” at the same location on different change images and comprehensively examines the different techniques. This method would enable authorities to monitor land degradation efficiently and aeculately.     

Hyperspectral mapping of alteration assemblages within a hydrothermal vug at the Haughton impact structure,Canada

Meteorite impacts on Earth and Mars can generate hydrothermal systems that alter the primary mineralogies of rocks and provide suitable environments for microbial colonization. We investigate a calcite–marcasite‐bearing vug at the ~23 km diameter Haughton impact structure, Devon Island, Nunavut, Canada, using imaging spectroscopy of the outcrop in the field (0.65–1.1 μm) and samples in the laboratory (0.4–2.5 μm), point spectroscopy (0.35–2.5 μm), major element chemistry, and X‐ray diffraction analyses. The mineral assemblages mapped at the outcrop include marcasite; marcasite with minor gypsum and jarosite; fibroferrite and copiapite with minor gypsum and melanterite; gypsum, Fe³⁺ oxides, and jarosite; and calcite, gypsum, clay, microcline, and quartz. Hyperspectral mapping of alteration phases shows spatial patterns that illuminate changes in alteration conditions and formation of specific mineral phases. Marcasite formed from the postimpact hydrothermal system under reducing conditions, while subsequent weathering oxidized the marcasite at low temperatures and water/rock ratios. The acidic fluids resulting from the oxidation collected on flat‐lying portions of the outcrop, precipitating fibroferrite + copiapite. That assemblage then likely dissolved, and the changing chemistry and pH resulting from interaction with the calcite‐rich host rock formed gypsum‐bearing red coatings. These results have implications for understanding water–rock interactions and habitabilities at this site and on Mars.     

How Bedrock‐Controlled Channel Migration Can Structure Selective Preservation of Archaeological Sites: Implications for Modeling Paleoindian Settlement

Although Paleoindian sites in Indiana, USA, are commonly located on late Wisconsin (Last Glacial Maximum) outwash terraces, drainage basin development since deglaciation often obscures the visibility of such sites on flood plains by either burying them under alluvium or destroying them through erosion. Significant clusters of Paleoindian and Early Archaic sites, however, have been identified proximal to the modern White River channel in central Indiana on what is mapped as “floodplain.” These site cluster locations are patterned. They typically occur within bedrock‐controlled river reaches but are rare along unconfined meandering reaches. Subsurface reconnaissance and chronology indicate that despite the fact that they often flood, portions of the so‐called flood plains within bedrock‐confined reaches are actually terraces constructed of late Wisconsin outwash with minimal overbank sedimentation. Terrace preservation in these settings is a result of bedrock structure that protects older sediments from lateral erosion and differentially preserves archaeological sites near the modern channel in bedrock‐controlled reaches. Comparisons of archaeological sites within bedrock‐controlled segments of the White River to those in unconfined meandering segments suggests that significant numbers of Paleoindian and Early Archaic sites may be missing from river settings across the midcontinent. These findings demonstrate that bedrock channel controls are important to recognize when assessing prehistoric settlement distributions.