GGR Biennial Critical Review: Analytical Developments Since 2014

This GGR biennial critical review covers developments and innovations in key analytical methods published since January 2014, relevant to the chemical, isotopic and crystallographic characterisation of geological and environmental materials. In nine selected analytical fields, publications considered to be of wide significance are summarised, background information is provided and their importance evaluated. In addition to instrumental technologies, this review also presents a summary of new developments in the preparation and characterisation of rock, microanalytical and isotopic reference materials, including a précis of recent changes and revisions to ISO guidelines for reference material characterisation and reporting. Selected reports are provided of isotope ratio determinations by both solution nebulisation MC‐ICP‐MS and laser ablation‐ICP‐MS, as well as of radioactive isotope geochronology by LA‐ICP‐MS. Most of the analytical techniques elaborated continue to provide new applications for geochemical analysis; however, it is noted that instrumental neutron activation analysis has become less popular in recent years, mostly due to the reduced availability of nuclear reactors to act as a neutron source. Many of the newer applications reported here provide analysis at increasingly finer resolution. Examples include atom probe tomography, a very sensitive method providing atomic scale information, nanoscale SIMS, for isotopic imaging of geological and biological samples, and micro‐XRF, which has a spatial resolution many orders of magnitude smaller than conventional XRF.     

COSMO-CLM2: a new version of the COSMO-CLM model coupled to the Community Land Model

This study presents an evaluation of a new biosphere-atmosphere Regional Climate Model. COSMO-CLM² results from the coupling between the non-hydrostatic atmospheric model COSMO-CLM version 4.0 and the Community Land Model version 3.5 (CLM3.5). In this coupling, CLM3.5 replaces a simpler land surface parameterization (TERRA_ML) used in the standard COSMO-CLM. Compared to TERRA_ML, CLM3.5 comprises a more complete representation of land surface processes including hydrology, biogeophysics, biogeochemistry and vegetation dynamics. Historical climate simulations over Europe with COSMO-CLM and with the new COSMO-CLM² are evaluated against various data products. The simulated climate is found to be substantially affected by the coupling with CLM3.5, particularly in summer. Radiation fluxes as well as turbulent fluxes at the surface are found to be more realistically represented in COSMO-CLM². This subsequently leads to improvements of several aspects of the simulated climate (cloud cover, surface temperature and precipitation). We show that a better partitioning of turbulent fluxes is the central factor allowing for the better performances of COSMO-CLM² over COSMO-CLM. Despite these improvements, some model deficiencies still remain, most notably a substantial underestimation of surface net shortwave radiation. Overall, these results highlight the importance of land surface processes in shaping the European climate and the benefit of using an advanced land surface model for regional climate simulations.     

Sedimentary record of redox-sensitive elements (U, Mn, Mo) in a transitory anoxic basin (the Thau lagoon, France)

In order to further document the relation between redox conditions and the sedimentary record of Mn, U and Mo in a transitory anoxic water basin, their distribution has been studied along two profiles in the Thau lagoon (France). Sediments and pore-water have been sampled at two contrasting sites located, respectively, in the shellfish-farming area and in the centre of the lagoon. In the shellfish-farming area, the particulate organic carbon (POC) data indicate a more rapid organic matter mineralisation compared to the centre of the lagoon. This results in a sharper redox gradient characterized by the appearance of H₂S in pore-water a few millimetres below the sediment–water interface. In the centre of the lagoon, H₂S appears at a depth of 35 cm.In both cores, sedimentary Mn is relatively depleted through out the whole sedimentary column and varies with the proportion of clay minerals. After an initial release into solution at the sediment–water interface in relation to Mn-oxide reductive dissolution, authigenic U is immobilized when sulphides appear. Despite the occurrence of anoxic conditions at the sediment–water interface at the site influenced by shellfish farming, the burial of U is reduced by bioturbation, which raises reducing sediments to the surface. In the centre of the lagoon, Mo profiles reflect continuous diffusion into pore water and immobilization at 15 cm probably in anoxic microenvironments. At shellfish farms, dissolved Mo undergoes removal with sulphides but contrary to U, sedimentary Mo does not appear to be strongly affected by bioturbation. The profile indicates an increase in the frequency of anoxia crises during the second half of the 20th century.     

Glacial/interglacial sea surface temperature changes in the Southwest Pacific ocean over the past 360 ka

The phase relationship between climate parameters during terminations gives insight into deglaciation mechanisms. By combining foraminiferal Mg/Ca and alkenone thermometers with planktonic and benthic foraminiferal δ¹⁸O, we determined the phase relationship between local sea surface temperature (SST) and global seawater δ¹⁸O changes in the Coral Sea in the Southwestern Pacific over the last 360 ka. The onset of the SST warming preceded the seawater δ¹⁸O change by several ka for Termination I, II and III. During Termination I, the SST warming started at 20 ka BP, earlier than atmospheric CO₂ rise suggesting that the greenhouse effect was not the main trigger of this early warming. Compilation of ¹⁴C-dated SST records from the whole Pacific during Termination I reveals that the onset of the warming is generally earlier in the Southern and the tropical Pacific than in the North Pacific. This spatio-temporal warming pattern suggests linkage between the southern ocean and tropical Pacific. The early tropical warming could provide heat and moisture to the northern high latitudes, modifying radiative balance and precipitation over ice sheets at the onset of deglaciation.     

Site Effect Study in Urban Area: Experimental Results in Grenoble (France)

—?Three methods are used to determine the site effect in the town of Grenoble, located in the Western Alps. First we use the classical spectral ratio method in 14 sites to calculate the transfer function of the basin. We find an amplification of 10 in the frequency range of 0.25 to 10?Hz. Second, we compare these results with the H over V spectral ratio method, and propose a map of resonance frequency of the basin. We find a lower resonance frequency in the center of the basin than on the edge, that is consistent with the structure deduced from a gravity Bouguer anomaly map. Finally we use the empirical Green's function method to simulate a M _w 5.5 earthquake at a distance of 20?km from the town. The simulated acceleration reaches the level of 2?m/s² in the center of the basin compared to 0.2?m/s² on the edges. The simulated ground motion we compute is smaller than the French seismic codes on the edge of the valley but significantly larger in the center.     

Site effects in Mexico City eight years after the September 1985 Michoacan earthquakes

The purpose of this paper is to take a comprehensive look at site effects in Mexico City for the 1985 Michoacan earthquake. We examine, successively, 1D and 2D models. For the latter, we consider in detail both large scale and small scale heterogeneities, using extensively the Aki-Larner wave propagation method, in the version given by Bard and Gariel. In particular, we make a critical review of the different explanations proposed for the large duration of strong ground motion in the lake zone. Our purpose is two-sided. We first outline the difference between what is well established and what remains still unexplained regarding the seismic response of Mexico City basin. On the other hand, we wish to make explicit the conditions that the proposed models require to explain strong motion duration. Our results allow us to qualify the models proposed to date and to point out what could be the experiments and the new data required to find a truly satisfactory explanation of strong ground motion at Mexico City.     

Acebuches amphibolites in the Aracena hercynian metamorphic belt (southwest Spain): Geochemical variations and basaltic affinities

A 1500–2000 m sequence of amphibolites exhibits progressively increasing metamorphic grade from greenschist to the amphibolite/granulite facies transition. The chemical variations are considered to be principally inherited from the basaltic parent. The appearance of clinopyroxene is related to P,T and to bulk-rock composition during metamorphism. Excluding some basal rocks in the orthopyroxene zone, chemical variations related to metamorphism are minor. The small decrease in the K₂O content from 0.3% to 0.1% with increasing grade suggests that the low K content was a characteristic of the basaltic precursor. These amphibolites have affinities with abyssal tholeiites.     

Combining Ring Width, Density and Stable Carbon Isotope Proxies to Enhance the Climate Signal in Tree-Rings: An Example from the Southern French Alps

At present the most powerful tree-ring based climate reconstructions use high numbers of growth proxy series (ring width and density) to produce spatially smoothed estimates, such as average Northern Hemisphere summer temperatures. These single parameter reconstructions might be supplemented with regional climate reconstructions capable of capturing variability in more than one climate variable without lower replication compromising statistical quality, if multiple tree ring proxies were used. Pinus sylvestris and Pinus uncinata latewood density, width and δ¹³C series are presented from two sites in the French subalpine zone, east of Briançon. Where two proxies have the same dominant climate control their combination enhances that signal. Where proxies differ in dominant controlling climate variable, combining series allows access to bi-variable calibrations. Using this approach, multi-proxy reconstructions of both temperature and precipitation would better reflect complex synoptic variability in climate on spatially useful scales.