Prognosis of pool phase state and hydrocarbon fluid composition for the Pre-Caspian OGP

The results of detailed studies and interpretations are presented for composition variations, structural properties and the phase state of hydrocarbon fluids from subsalt pools of the Pre-Caspian depression. These data serve as a basis for substantiating the existence of several types of condensate, and identifying the locations of the main centres of fluid generation. The basic geological-geochemical conditions controlling the composition of condensate and free gases have been determined as well as their present phase state. A set of basic criteria is proposed as well as prognostic maps for the condensate and free gas composition, and the pool phase states.     

Late Quaternary vegetation changes around Lake Rutundu,Mount Kenya,East Africa: evidence from grass cuticles,pollen and stable carbon isotopes

Woody, subalpine shrubs and grasses currently surround Lake Rutundu, Mount Kenya. Multiple proxies, including carbon isotopes, pollen and grass cuticles, from a 755‐cm‐long core were used to reconstruct the vegetation over the past 38 300 calendar years. Stable carbon‐isotope ratios of total organic carbon and terrestrial biomarkers from the lake sediments imply that the proportion of terrestrial plants using the C₄ photosynthetic pathway was greater during the Late Pleistocene than in the Holocene. Pollen data show that grasses were a major constituent of the vegetation throughout the Late Pleistocene and Holocene. The proportion of grass pollen relative to the pollen from other plants was greatest at the last glacial maximum (LGM). Grass cuticles confirm evidence that C₄ grass taxa were present at the LGM and that the majority followed the cold‐tolerant NADP‐MEC₄ subpathway. Copyright © 2003 John Wiley & Sons, Ltd.     

Estimation of snow water equivalent using microwave radiometry over Arctic first‐year sea ice

The magnitude and spatial distribution of snow on sea ice are both integral components of the ocean–sea‐ice–atmosphere system. Although there exists a number of algorithms to estimate the snow water equivalent (SWE) on terrestrial surfaces, to date there is no precise method to estimate SWE on sea ice. Physical snow properties and in situ microwave radiometry at 19, 37 and 85 GHz, V and H polarization were collected for a 10‐day period over 20 first‐year sea ice sites. We present and compare the in situ physical, electrical and microwave emission properties of snow over smooth Arctic first‐year sea ice for 19 of the 20 sites sampled. Physical processes creating the observed vertical patterns in the physical and electrical properties are discussed. An algorithm is then developed from the relationship between the SWE and the brightness temperature measured at 37 GHz (55°) H polarization and the air temperature. The multiple regression between these variables is able to account for over 90% of the variability in the measured SWE. This algorithm is validated with a small in situ data set collected during the 1999 field experiment. We then compare our data against the NASA snow thickness algorithm, designed as part of the NASA Earth Enterprise Program. The results indicated a lack of agreement between the NASA algorithm and the algorithm developed here. This lack of agreement is attributed to differences in scale between the Special Sensor Microwave/Imager and surface radiometers and to differences in the Antarctic versus Arctic snow physical and electrical properties. Copyright © 2003 John Wiley & Sons, Ltd.     

Timing and tectonic setting of Grenvillian metamorphism—constraints from a transect along Georgian Bay,Ontario*

Systematic mapping of a transect along the well-exposed shores of Georgian Bay, Ontario, combined with the preliminary results of structural analysis, geochronology and metamorphic petrology, places some constraints on the geological setting of high-grade metamorphism in this part of the Central Gneiss Belt. Correlations within and between map units (gneiss associations) have allowed us to recognize five tectonic units that differ in various aspects of their lithology, metamorphic and plutonic history, and structural style. The lowest unit, which forms the footwall to a regional decollement, locally preserves relic pre-Grenvillian granulite facies assemblages reworked under amphibolite facies conditions during the Grenvillian orogeny. Tectonic units above the decollement apparently lack the early granulite facies metamorphism; out-of-sequence thrusting in the south produced a duplex-like structure. Two distinct stages of Grenvillian metamorphism are apparent. The earlier stage (c. 1160–1120 Ma) produced granulite facies assemblages in the Parry Sound domain and upper amphibolite facies assemblages in the Parry Island thrust sheet. The later stage (c. 1040–1020 Ma) involved widespread, dominantly upper amphibolite facies metamorphism within and beneath the duplex. Deformation and metamorphism recently reported from south and east of the Parry Sound domain at c. 1100–1040 Ma have not yet been documented along the Georgian Bay transect. The data suggest that early convergence was followed by a period of crustal thickening in the orogenic core south-east of the transect area, with further advance to the north-west during and after the waning stages of this deformation.     

The significance of Messinian occurrences of Globorotalia margaritae and Globorotalia puncticulata in Sicily

Globorotalia puncticulata and Globorotalia margaritae are critical species that define internationally recognized planktonic foraminiferal biozones in the Pliocene. These biozones are defined from stratotype sections on Sicily and their fauna are commonly considered to have been introduced to the Mediterranean after an influx of Atlantic water that terminated the late Miocene desiccation of the basin. Herein new discoveries of these species in rocks that predate the late Miocene desiccation are described. These data are supported by magneto- and lithostratigraphy that have been integrated at a single continuous section. Not only do these discoveries question the existing foraminiferal biozone stratigraphy, they also suggest new models for the dispersal of planktonic species. It is proposed that Globorotalia puncticulata and perhaps even Globorotalia margaritae evolved in the Mediterranean during earliest Messinian times (during or before chron C3Bn1n) and dispersed into the Atlantic. This suggests that a marine connection remained between the two sea areas until at least chron C3An.1n. Using the existing geomagnetic polarity time scale, these occurrences are some 2 Myr earlier than previously recorded in the Mediterranean. The distribution of G. margaritae and G. puncticulata in Mediterranean sections is likely to reflect palaeoenvironment or the preservation of deposits rather than the absolute age of the sediments.