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Transport of three herbicides in ground water at Twin Lake test site,Chalk River,Ontario, Canada 总被引:2,自引:0,他引:2
A field tracer test performed under natural flow conditions at the Twin Lake test site, Chalk River Laboratories of the Atomic Energy of Canada Ltd. in Chalk River, Ontario, Canada, using tritium and three herbicides (Chlortoluron, Terbuthylazine, and Pendimethalin) was interpreted using the dispersion equation with a combined reaction model. The reaction model couples an instantaneous equilibrium reaction governed by a linear adsorption isotherm with a reversible or irreversible kinetic reaction of the first order, and decay. An improved interpretation method consists of a simultaneous fitting of theoretical concentration and mass-recovery curves to the experimental data, which leads to a more reliable determining of reaction models and improves the accuracy of fitting. Tritium served as the reference tracer to determine the flow velocity, dispersivity, and the recovery of the herbicides. Chlortoluron was slightly delayed by equilibrium exchange with strongly reduced concentration due to an irreversible kinetic reaction and/or decay. Terbuthilazine was slightly delayed by equilibrium exchange, with strongly reduced concentration due to a reversible kinetic reaction with some influence of decay. A strong equilibrium reaction and a strong reversible kinetic reaction without degradation governed the transport of Pendimethalin, reducing considerably its concentration. The results obtained show that simulations based only on Kd and decay constant, especially if these parameters are found in the laboratory, may considerably differ from those performed with reaction parameters determined in properly performed field tests. The dominant reaction types, and the values of parameters found in the study, supply useful information on the transport of the investigated herbicides in sandy aquifers under natural flow conditions. 相似文献
156.
黑龙江嘉荫地区白垩纪-第三纪界线初步观察 总被引:12,自引:3,他引:9
孙革 孙春林 董枝明 孙跃武 吕建生 熊宪政 周忠立 余福林 邢玉玲 全成 M.A.Akhmetiev A.R.Ashraf E.Bugdaeva D.L.Dilcher L.Golovneva K.Johnson T.Kezina T.Kodrul H.Okada 《世界地质》2003,22(1):8-14
本文报道了黑龙江嘉荫白山头地区一条新的地层剖面及其K/T界线的初步研究。新命名的“白山头段”代表乌云组下部的早古新世地层,含以Tiliaephyllum tsagajanicum等为代表的达宁早期植物化石。在白山头剖面上,作者发现可能为白垩纪末期的凝灰岩。结合与俄罗斯布列亚盆地含K/T界线的查加扬群标准剖面的对比,推测嘉荫地区的K/T界线可能位于白山头段底部与上述凝灰岩之上的一层炭质泥岩之间。 相似文献
157.
This paper analyses the spatial and temporal effects of a freshwater discharge (Canal Andreoni) on the macroinfauna community and its habitat in a sandy beach of Uruguay. Bimonthly, we examined 17 environmental variables plus macroinfauna abundance, biomass, richness, evenness and diversity of three sites: Andreoni, at the canal mouth, Coronilla, at 1 km, and Barra, at 13 km from the mouth. Both univariate and multivariate techniques showed an increasing degree of perturbation towards the canal. This was reflected by abiotic and biotic differences between sites and by a consistent two-dimensional ordination of the samples. A clear seasonal pattern was found, specially accentuated at Coronilla, where the effects of the canal were stronger in winter and weaker in summer. Multivariate linking between macroinfauna and its habitat highlighted the role of salinity as explanatory variable of the observed trends. 相似文献
158.
Bioconcentration of heavy metals in aquatic environments: the importance of bioavailability 总被引:2,自引:0,他引:2
The importance of heavy metal bioavailability on the bioconcentration in aquatic biota is examined. To this purpose, mono- and multivariate statistical techniques are applied to develop correlations between heavy metal bioconcentration factor and sediment characteristics, that are expected to affect bioavailability, using a database of heavy metal concentrations in biota and sediment along with the available physicochemical characteristics. The statistical analysis shows that satisfactory correlations are obtained only when factors that affect bioavailability, such as metal oxides concentration and organic carbon content in the sediment, are taken into account. 相似文献
159.
Cearreta A Irabien MJ Leorri E Yusta I Quintanilla A Zabaleta A 《Marine pollution bulletin》2002,44(6):487-503
The distribution and abundance of benthic foraminifera and a range of elements have been analysed in six long cores (up to 10 m long) from the Bilbao estuary, N. Spain, to document environmental transformation of this estuarine ecosystem and to determine sediment contamination levels. Three different environmental zones could be distinguished in the recent sedimentary record based on its microfaunal and geochemical contents. Initially, a pre-industrial zone containing very abundant and diverse foraminiferal assemblages together with baseline metal levels. Secondly, an older industrial zone exhibiting co-existence of abundant and diverse foraminiferal assemblages with high concentrations of metals. Finally, a younger industrial zone with extreme concentrations of metals and barren of indigenous foraminifera. This environmental transformation has been caused by the discharge of untreated domestic and industrial effluents during the last 150 years. The occurrence of foraminifera in the two industrial zones and along the estuary is not related to defined levels of metals, and this seems to confirm oxygen limitation as the key factor to explain complete estuarine defaunation during deposition of the younger industrial zone (period 1950-2000). Effectiveness of current regeneration schemes could be assessed using microfaunal and geochemical proxies as environmental quality indicators. 相似文献
160.
Much of the authors' knowledge of kin interaction and exchange in Britain is partial, in that it is based on studies of co-resident groups and excludes consideration of kin "beyond the household". It is known that there have been large declines in intergenerational co-residence, raising fears that family bonds have weakened. It is also commonly assumed that family members are less likely to live in close proximity than in the past. In this paper the authors examine one important aspect of kin relationships--proximity of adult children to their parents--using nationally representative data from 1986, 1995, and 1999. The analyses presented focus on: differences between 1986, 1995, and 1999 in proximity of adults to their parents; sociodemographic characteristics associated with variations in proximity, and temporal differences in the pattern of these variations. The paper concludes with an assessment of some of the policy implications of the findings. 相似文献