Vibrational and thermodynamic properties of Ni<Subscript>3</Subscript>S<Subscript>2</Subscript> polymorphs from first-principles calculations

We have calculated the compressional, vibrational, and thermodynamic properties of Ni₃S₂ heazlewoodite and the high-pressure orthorhombic phase (with Cmcm symmetry) using the generalized gradient approximation to the density functional theory in conjunction with the quasi-harmonic approximation. The predicted Raman frequencies of heazlewoodite are in good agreement with room-temperature measurements. The calculated thermodynamic properties of heazlewoodite at room conditions agree very well with experiments, but at high temperatures (especially above 500 K) the heat capacity data from experiments are significantly larger than the quasi-harmonic results, indicating that heazlewoodite is anharmonic. On the other hand, the obtained vibrational density of states of the orthorhombic phase at 20 GPa reveals a group of low-frequency vibrational modes which are absent in heazlewoodite. These low-frequency modes contribute substantially to thermal expansivity, heat capacity, entropy, and Grüneisen parameter of the orthorhombic phase. The calculated phase boundary between heazlewoodite and the orthorhombic phase is consistent with high-pressure experiments; the predicted transition pressure is 17.9 GPa at 300 K with a negative Clapeyron slope of −8.5 MPa/K.     

Spatial patterns of chemical contamination (metals, PAHs, PCBs, PCDDs/PCDFS) in sediments of a non-industrialized but densely populated coral atoll/small island state (Bermuda)

There is a recognized dearth of standard environmental quality data in the wider Caribbean area, especially on coral atolls/small island states. Extensive surveys of sediment contamination (n = 109 samples) in Bermuda revealed a wide spectrum of environmental quality. Zinc and especially copper levels were elevated at some locations, associated with boating (antifouling paints and boatyard discharges). Mercury contamination was surprisingly prevalent, with total levels as high as 12 mg kg⁻¹ DW, although methyl mercury levels were quite low. PAH, PCB and PCDD/PCDF contamination was detected a several hotspots associated with road run-off, a marine landfill, and a former US Naval annexe. NOAA sediment quality guidelines were exceeded at several locations, indicating biological effects are possible, or at some locations probable. Overall, and despite lack of industrialization, anthropogenic chemicals in sediments of the atoll presented a risk to benthic biodiversity at a number of hotspots suggesting a need for sediment management strategies.     

Evaluation of snow water equivalent datasets over the Saint‐Maurice river basin region of southern Québec

A 10‐km gridded snow water equivalent (SWE) dataset is developed over the Saint‐Maurice River basin region in southern Québec from kriging of observed snow survey data for evaluation of SWE products. The gridded SWE dataset covers 1980–2014 and is based on manual gravimetric snow surveys carried out on February 1, March 1, March 15, April 1, and April 15 of each snow season, which captures the annual maximum SWE (SWEM) with a mean interpolation error of ±19%. The dataset is used to evaluate SWEM from a range of sources including satellite retrievals, reanalyses, Canadian regional climate models, and the Canadian Meteorological Centre operational snow depth analysis. We also evaluate a number of solid precipitation datasets to determine their contribution to systematic errors in estimated SWEM. None of the evaluated datasets is able to provide estimates of SWEM that are within operational requirements of ±15% error, and insufficient solid precipitation is determined to be one of the main reasons. The Climate System Forecast Reanalysis is the only dataset where snowfall is sufficiently large to generate SWEM values comparable to observations. Inconsistencies in precipitation are also found to have a strong impact on year‐to‐year variability in SWEM dataset performance and spread. Version 3.6.1 of the Canadian Land Surface Scheme land surface scheme driven with ERA‐Interim output downscaled by Version 5.0.1 of the Canadian Regional Climate Model was the best physically based model at explaining the observed spatial and temporal variability in SWEM (root‐mean‐square error [RMSE] = 33%) and has potential for lower error with adjusted precipitation. Operational snow products relying on the real‐time snow depth observing network performed poorly due to a lack of real‐time data and the strong local scale variability of point snow depth observations. The results underscore the need for more effort to be invested in improving solid precipitation estimates for use in snow hydrology applications.     

Theoretical models of planetary nebulae

Theoretical models are attempted for eight moderate excitation planetary nebulae which have been intensively observed with the image-tube scanner at Lick and in other investigations. The models are uniform density structures, often truncated, with central star energy distributions and chemical compositions so adjusted as to give an optimum fit with the observations. Although a satisfactory representation can be obtained for most of the stronger, usually observed lines, those arising from the 3p ³ configuration, specifically the nebular transitions of [Sii], [Cliii], and [Ariv], often give difficulties. A comparison with results of model predictions with those from simple, traditional procedures generally shows a good agreement, except in those instances where different judgments are made in interpreting emissions of ions of 3p ⁿ configurations.     

Fast lagrangian particle tracking in unstructured ocean model grids

Ocean Dynamics - Lagrangian particle tracking, based on currents derived from hydrodynamic models, is an important tool in quantifying bio-physical transports in the ocean. Particle tracking in the...     

Weighting of Observed Heads for the Inverse Problem

In using least-squares parameter estimation techniques to solve for hydrogeologic parameters, one may use a weighting function to reflect differing reliabilities of head measurements. In studies published to date, the weighting function has been used in an ad boc manner or not at all. The inverse square of the observed hydraulic gradient, adjusted to reflect the modeler's perception of geologic heterogeneity and data reliability, is typically an appropriate weighting function.     

Neutral gas composition measurements between 80 and 120 km

Atmospheric composition in the turbopause regime was determined by four rocket-borne mass spectrometers, which employed shock-freezing cryo-ion sources. Number densities of N₂, O₂, O, Ar and CO₂ are presented for these experiments. The results are compared with those of other rocket experiments taken from the literature. Ar/N₂ ratios are analyzed with respect to atmospheric turbulence. Magnitude and variability of atomic oxygen layer maximum density and layer content are discussed. Variations of O densities and simultaneous Ar/N₂ ratio changes are compared. Six CO₂ measurements are discussed in terms of CO₂/N₂ ratios.     

Observations from space of the solar corona/inner zodical light

Observations, from the Apollo 16 Spacecraft, in lunar orbit, of the total radiance of the K + F corona, from 3 R to 55 R are presented and discussed.

The logarithmic slope of the K + F coronal radiance, in the region r > 20 R, is found to be n = 1.93, slightly less steep than previous determinations. The photometric axis of the radiance is found to be displaced 3 ± 1° north of the ecliptic, for the region r > 20 R, and this displacement is interpreted as an annual variation due to non-coincidence of the ecliptic and the symmetry axis of the zodiacal cloud.     

Unlocking the applications of automated mineral analysis

Identifying and quantifying the relative abundance of minerals is a fundamental part of many aspects of both pure and applied geology. Historically, quantitative mineralogy could be achieved using optical microscopy and point counting. This is a slow and operator dependent process, and practically impossible to achieve in, for example, very fine grained samples. Over the last decade a range of automated mineralogy technologies have arisen from the global mining industry and are being increasingly used in other branches of geology. These technologies, based on scanning electron microscopy with linked energy dispersive spectrometers, have the potential to revolutionise how we quantify mineralogy. In addition, during measurement, the sample textures are also captured, providing a wealth of valuable data for the geologist. In this article we review the current state of automated mineralogy and highlight the many areas of application for this technology.     

Sociospatial aspects of Australian aboriginal underdevelopment. Empirical evidence from the East kimberley

Prior to the penetration of the European capitalist economy into central and northern Australia, the Aboriginal mode of production was one of hunting and gathering. Spiritual, economic and social relationships betwen people and land produced a spatial distribution of small bands of people living on their traditional lands. To the incoming white settlers the low population density and type of land use appeared uneconomic. This observation was used as ideological justification for the expropriation and development of the land for commercial pastoralism. This paper discusses the articulation of the Aboriginal and European modes of production in the East Kimberley region of northwest Australia. It argues that the introduced capitalist economy virtually destroyed the Aboriginal means of subsistence, incorporating Aborigines into the new mode of production within various subordinate roles. The exploitation of Aborigines, formerly as labour and now predominantely as consumers, is fundamental to the maintenance of the capitalist mode of production in pastoral areas. The spatial effects of the dominant mode of production have been to centralise Aborigines in locations suited to the various phases of development of the European economy, undermining the traditional Aboriginal social-spatial structure. The centralisation of the Aboriginal population also enhances the opportunities for the further development of the mining industry, which is in direct competition with Aboriginal interests in land. Aboriginal resistance to these spatial tendencies is intense in many quarters, but efforts to return to living on traditional lands and to develop alternative ways of living are hampered by the dominant mode of production.