Time-scale calibration by high-precision UPb zircon dating of interstratified volcanic ashes in the Ordovician and Lower Silurian stratotypes of Britain

High initial parent/daughter element ratios and a unique dual decay scheme make UPb zicron ages more precise and reliable than most isotopic ages, and thus inherently superior for time-scale calibration. Employing improved techniques to the conventional method of UPb dating, we have analyzed microgram-size (2–12 × 10⁻⁸ g) zircon fractions from biostratigraphically controlled volcanic ashes and dated key Paleozoic time-markers with a precision better than 1% (±2Ma). Four of the stratotype samples from Britain for which fission-track ages [1] were previously reported have yielded improved ages of:438.7 ± 2.0Ma for the lower Silurian zone of Coronograptus cyphus from Llandovery strata at Dob's Linn, southern Scotland;457.5 ± 2.2 Ma for a Middle Ordovician Caradoc (Longvillian) ash near Bala, North Wales, and;465.7 ± 2.1and464.6 ± 1.8 Ma for the Didymograptus artus Zone and the type Didymograptus Murchisoni Zone, respectively, of the Llanvirn Series at Arenig Fawr and Abereiddi Bay, Wales. Another sample from the zone of Dicellograptus anceps (P. pacificus Subzone) of the Ashgill Series at Dob's Linn has been dated at445.7 ± 2.4Ma, suggesting placement of the Ordovician-Silurian time boundary at approximately 441 Ma. A sixth bentonite from Caradocian age strata of North America (Spechts Ferry Shale, Decorah Formation, Missouri) is453.7 ± 1.8Ma old, indicating that the Rocklandian Stage of the Mohawkian Series is only slightly younger than the Longvillian Stage of the Caradoc Series in Britain.     

Petrology of Peter I Øy (Peter I Island), West Antarctica

Peter I Øy is located in the Bellinghausen Sea, 400 km NE of Thurston Island, West Antarctica. It is a Pleistocene volcanic island situated adjacent to a former tranform fault on the continental rise of the presently passive margin between the Pacific and Antarctica. New K-Ar age determinations ranging from 0.1 to 0.35 Ma show that the volcanism responsible for this island took place at the same time as post-subduction, rift-related volcanism occurred in the nearby Marie Byrd Land and the Antarctic Peninsula. The rocks of the island are alkalic basalt and hawaiite, benmoreite and trachyte. The basic tocks typically contain phenocrysts of olivine (Fo_61–84), diopsidic augite, and plagioclase (ca. An₆₀). Small xenoliths are present and consist of mantle-type spinel lherzolite, cumulate clinopyroxenite and gabbro and felsic inclusions that consist of medium-grained strained quartz, plagioclase, and abundant colorless glass. Chemically, the basic rocks are characterized by rather high MgO (7.8–10.2 wt.%) and TiO₂ (3.1–3.7 wt.%) and relatively low CaO (8.4–9.5 wt.%) contents. They have steep REE patterns, [(La/Yb)_N = 20] with HREE only 5 x chrondrite. Y and Sc are almost constant at relatively low levels. Compatible trace elements such as Ni and Cr show considerable variation (190–300 and 150–470 ppm, respectively.), whereas V shows only little variation. Sr and Nd isotope ratios vary slightly with ⁸⁷Sr/⁸⁶Sr averaging 0.70388 and ¹⁴³Nd/¹⁴⁴Nd 0.512782, both typical for ocean island volcanism. Lead isotope ratios are consistently high in basalts; ²⁰⁶Pb/²⁰⁴Pb = 19.194, ²⁰⁷Pb/²⁰⁴Pb = 15.728 and ²⁰⁸Pb/²⁰⁴Pb = 39.290, whereas benmoreïte is somewhat less radiogenic. Oxygen isotope analyses average δ¹⁸O = +6.0‰. Incompatible trace elements vary by a factor of 1.5–2.0 within the range of the basic rocks. It is proposed that the incompatible trace-element variations represent different degrees (<10%) of partial melting, and that these melts were later modified by minor (<15‰) olivine and spinel fractionation. The very small variation in Y (and Sc) and the very fractionated REE pattern indicate that the source had an Y- and HREE-rich residual phase, most probably garnet. Furthermore, it is suggested that the source was slightly hydrous and that melting took place at 18–20 kbar. Trachyte was derived by multiphase fractionation of ne-normative basalts, and benmoreite from hy-normative parental liquids. The rocks of Peter I Øy are generally of the same type and age as those outcropping in extensional regimes on the nearby continent, and therefore, these occurrences may be related to each other in some way. However, the Peter I Øy rocks are considerably more radiogenic in strontium and less radiogenic in neodymium than the rocks of the Antarctic Peninsula and Marie Byrd Land. Possible explanations are that Peter I Øy represent asthenospheric hot spot activity, or transtensional rifting as subduction ceased.     

An examination of the use of the logratio transformation for the testing of endmember hypotheses

Given a compositional dataset in the absence of any prior information on any mixing process which may have formed it, a complete analysis of mixtures determines three distinct types of estimates in order. These are: (i) the estimate of the number of endmembers or fixed source compositions, of which all the sample compositions of the dataset must be approximate mixtures; (ii) the estimated compositions for each of these chosen number of endmembers; and (iii) the estimated contributions of each of these endmember estimates to each sample. Traditionally, the estimate for the number of endmembers has been assessed either by mapping or by inspection of the coefficients of determination between the observed and estimated variables. Mapping entails the plotting on a map of the region from which the samples were taken, either the contours of the contributions of each endmember to each sample, or some other portrayal of the distribution of endmember abundances. Because it requires the complete analysis, assessment by this method is too elaborate except for final confirmation and display. Alternatively, choosing a number of endmembers, which result in suitability high coefficients of determination for all or most variables, may account for elements which are not part of the conjectured mixing process or, worse, may result in the identification of endmembers which may never in fact have existed. Such an error is similar to overspecifying a multiple regression model. So, the obvious starting point from which to assess the validity, or otherwise choice of endmember numbers, is to examine the matrix of residuals. The differences between the logratio-transformed observed and estimated data form an array of residual logratios. A linear combination of these may be formed for each sample, which, under a random perturbation assumption, should follow a univariate normal distribution. Whether or not this scalar is normal can be readily tested. It can also be examined graphically for such desirable qualities as symmetry when the test for normality may be too severe. This procedure is employed to assess the decompositions of the U.S.G.S. Mid-Pacific data and the Nazca Plate Surface sediments.This paper was presented at the 18th Geochautauqua, Newark, Delaware, 13–14 October 1989.     

Temperature dependence of the cation distribution in nickel aluminate (NiAl2O4) spinel: a powder XRD study

NiAl₂O₄ is a largely inverse spinel, which in detail shows increasing randomisation with temperature of Ni and Al between the octahedral and tetrahedral cation sites of the spinel structure. We have used powder XRD to determine this cation distribution in various samples of NiAl₂O₄ quenched after annealing between 700 and 1400° C. The inversion parameter (x) can be measured with a precision of ± 0.004 (one standard deviation), and a comparison of different methods of synthesis, X-ray diffraction and refinement techniques, suggests a probable accuracy of better than 0.01. The results are supported by some preliminary single crystal refinements on flux-grown samples.Below 800° C the rate of cation ordering becomes very slow, and, despite reaching an apparently steady state, it is doubtful if our samples attained complete internal equilibrium. Above 1250° C the cation redistribution becomes so fast that the quenching method becomes unreliable. Between 800 and 1250° C inclusive, the degree of inversion changes smoothly from 0.87 at 800° C to 0.79 at 1250° C, and is accompanied by linear changes in u, the oxygen parameter, from 0.2555 to 0.2563 (±0.0002), and a₀, the lattice parameter, from 8.0462 to 8.0522 Å (±0.0002 Å).     

Atrazine Used as a Tracer of Induced Recharge

The city of Lincoln draws water from a well field along the banks of the Platte River in east-central Nebraska. We have been able to follow the infusion of atrazine into this well field under induced recharge. Samples of water from the river, several monitoring wells and a production well were analyzed by GC/MS and solid phase extraction and found to change in concentration over the range 0.1 and 5.0 ppb of atrazine through the spring, summer, and fall 1989. Increases in the concentration of atrazine relating to precipitation events in the Platte River Basin were observable in the well water samples and ultimately in Lincoln municipal tap water. Atrazine from the river was seen to move via induced recharge and into well field ground water and away from the river at an observable rate. The concentration of atrazine in the river is dependent upon time of year and precipitation in the river basin.     

Sediment budgeting: A case study in the Katiorin drainage basin,Kenya

The primary objective of this study was to compute a detailed budget for a small semiarid tropical drainage basin in Kenya. Results indicated that transfer of sediments (‘inputs’) from primary source areas was minor in comparison to changes in storage. The major sediment source area within the Katiorin drainage basin was the colluvial hillslope zone. The net change in storage within this zone was approximately 2100 Mg yr^?1. Surface wash and rilling were the dominant transport processes responsible for the remobilization of colluvial sediments. Sediment storage within the in-channel reservoir increased by 60 Mg yr^?1, which was minor when compared to the total store of sediment in this reservoir. During 1986, the channel network stored only a small fraction ( < 3 per cent) of the sediment delivered from the hillslope subsystem. Therefore, the in-channel reservoir had limited influence on sediment conveyance to the basin outlet. These data indicate that a static equilibrium condition cannot be assumed within the Katiorin drainage basin. Such an assumption would result in erosion estimates of approximately 5.5 mm yr^?1 for the entire basin (based on a sediment output of 7430 Mg km^?2 yr^?1 and a measured bulk density of 1.35 Mg m^?3). However, this masked the actual rates of 1.2 to 7.1 mm yr^?1 in subbasin primary source areas, and rates of 0.6 to 17 mm yr^?1 for colluvial material in the various subbasins. The extreme accelerated erosion rates resulted from minimal ground vegetation, steep slopes, soil crust formation, an erodible substrate, and a well-integrated drainage network for rapid conveyance of sediments from the hillslope subsystem to the basin outlet.     

Geometry of a convergent zone, Central British Columbia, Canada

The Canadian Cordillera is separable into two major northerly trending tectonic units—the Pacific Orogen and the Columbian Orogen, with the latter further separated into the Omineca Crystalline Belt and the easterly Rocky Mountain Fold and Thrust Belt. Synkinematic metamorphism of Jurassic age within the Omineca Belt is thought to be associated with accretion of westerly terranes of the Pacific Orogen—more specifically the Quesnellia terrane—that was thrust easterly over the Omineca Belt towards the craton. Mylonitic rocks mark the margin between these two belts and this margin is well-exposed near Crooked Lake, central British Columbia.Structural analysis across the zone of convergence between these two terranes indicates that the cratonic basement and the accreted cover sequences have several phases of deformation and metamorphism in common. The initial common phase of deformation, wherein convergence is accomplished, is characterized by easterly verging folds that are superposed by a second common phase having westerly verging folds that deform the zone of convergence and control the present regional map pattern. A final common phase of deformation produced easterly verging folds.Change in vergence direction is interpreted as resulting from change in direction of transport related to subduction process: first obduction of Quesnellia onto the Omineca craton, followed later by easterly subduction of an oceanic Quesnellia below the craton.All evidence of transport direction(s) points to convergence occurring at very high angles to the zone of convergence. There appears to be no evidence of transport parallel with the strike of the zone. If transport has taken place parallel to the strike of the zone, then this transport occurred before convergence or evidence of this motion has been destroyed during the convergence.     

Al,Si ordering in cordierite using “magic angle spinning” NMR

A method of determining the number of Al-O-Al bonds per unit cell from ²⁹Si nuclear magnetic resonance (NMR) data of synthetic cordierites with increasing Si, Al order is described. The number of Al-O-Al bonds is found to vary linearly with the logarithm of the annealing time. This may be correlated with previously published heat of solution data on similar samples (Carpenter et al. 1983) to determine the enthalpy change Δh, associated with a single Al?Si interchange in cordierite. Δh is found to be 8.1 kcal/mole. The NMR data show that the short range Al, Si order cannot be described in terms of twin domains of ordered orthorhombic cordierite. An ordering model derived from group theoretical constraints on possible Al, Si distributions within the hexagonal symmetry of the cordierite is found to provide a better fit to the NMR data.     

The quaternary stratigraphy of mount Etna,sicily: the effects of differing palaeoenvironments on styles of volcanism

Using recently published radiometric dates of important horizons within the Etna succession, correlations are proposed with the Late Quaternary biostratigraphies of the Italian mainland and the Mediterranean sea floor. This enables palaeoclimatic, palaeohydrological and palaeogeographical conditions on Etna to be established at stages in the volcano's evolution. It is argued that several major volcaniclastic suites were formed through the operation of processes that were under complex environmental, rather than simple volcanological control alone. In particular it is suggested that certain episodes of phreatomagmatic and laharic activity cannot be related to episodes of more evolved magma production, but rather to times during which the environment, height and configuration of Etna favoured the eruption and emplacement of these deposits. The authors reiterate their explanation of the formation of the Valle del Bove through processes of massive slope failure and indicate that conditions favouring this occurred at an appropriate stage in the history of the volcano. It is concluded that on active basaltic volcanoes, especially those like Etna which are also high mountains, the explanation of more violent phases requires the consideration of both internal volcanological and external environmental and morphological variables and that this is particularly important when its development has been set within the context of Late Quaternary environmental change. Finally the implications of these findings for the assessment of hazard are considered.

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Resumé Utilisant récemment des publications sur les datations radiométriques de couches importantes à l'intérieur de la succession de l'Etna, nous proposons d'établir des corrélations entre les biostratigraphies du Quaternaire Récent de la Péninsule Italienne et due fond marin Méditerranéen. Par ce procédé, nous pouvons établir les conditions paléoclimatiques, paléohydrologiques et paléogéographiques par stades selon l'évolution du volcan, capendant il faut tenir compte du fait que plusieurs suites volcaniclastiques majeures se sont formées à partir d'opérations de processus qui etaient eux-mêmes sous une complexe influence écologique plutôt que volcanologique seulement. Il est suggéré, en particulier, que certains épisodes d'activités phreatomagmatiquer et laharique ne puissent être reliés à des épisodes de production de magma plus elaborée, mais plutôt à des périodes pendant lesquelles le milieu, la hauteur et la configuration de l'Etna ont favorisé l'éruption et la localisation de ces dépôts. Les auteurs réitèrant leur explication sur la formation de la Vallée del Bove selon un processus de rupture radicale de pente et indiquent que les conditions favorables à ce dernier sont survenues à un stade opportun dans l'histoire du volcan. Ceci amènè à conclure que, sur des volcans basaltiques actifs comme l'Etna en particulier qui sont egalement des montagnes élevées, l'explication de phases plus violentes demande la consideration de facteurs volcanologiques internes d'une part, et morphologiques et écologiques externes d'autre part et que ceci est essential lorsque son développement a été fixé dans le contexte du changement de milieu au Quaternaire Recent. Enfin, il faut tenir compte de l'implication de ces résultats face aux incidences de risques.