Chemical contamination of a coral reef by the grounding of a cruise ship in Bermuda

Bulk metal analyses of surficial sediments collected around the Norwegian Crown cruise ship grounding site in Bermuda indicated significant but localized contamination of reef sediments by copper and zinc, caused by the stripping of the tri-butyltin (TBT)-free antifouling (AF) paint (Intersmooth 460) from the underside of the hull. Highest copper and zinc values were found in heavily compacted and red-pigmented sediments inside the impact scar and were comparable to levels found close to slip ways of local boat yards where AF paints from hull stripping and cleaning processes are washed into the sea. The re-distribution of AF contaminated sediments by storms and deposition on nearby reefs constitutes a significant ecological risk that could delay recovery processes and reduce the effectiveness of remediation efforts. Whilst the ecotoxicological effects of AF paint particles interspersed with sediment is unknown, and in need of further study, it is argued that the significance of AF paint contamination of grounding sites has been overlooked.     

Fast approximate EM induction modeling of metallic and UXO targets using a permeable prism

The time-domain EM induction response of non-magnetic and magnetic targets can be approximated using a conductive permeable prism composed of six faces of conductive plates, each face being composed of a set of conductive ribbons. The effect of magnetic permeability is included by the use of two “apparent flux gathering” coefficients, and two “effective magnetic permeability” coefficients, in the axial and transverse directions. These four magnetic property coefficients are a function of physical properties and geometry of the target, but are independent of prism orientation relative to a transmitter. The approximation algorithm is computationally fast, allowing inversions for target parameters to be achieved in seconds. The model is tested on profiles acquired with a Geonics EM63 time-domain EM metal detector over a non-magnetic copper pipe target, and a steel artillery shell in horizontal and vertical orientations. Results show that this approximation to a permeable prism has a capability of fitting geometric, conductivity and magnetic parameters at both early and late sample times. The magnetic parameters show strong change from early to late times on the EMI decay curve, indicating that the magnetic properties of the target have non-linear characteristics. It is proposed that these magnetic parameters and the nature of their non-linearity may carry additional discrimination information for distinguishing between intact munitions and scrap in UXO studies.     

Persistent organic pollutants and stable isotopes in biopsy samples (2004/2006) from Southern Resident killer whales

“Southern Resident” killer whales include three “pods” (J, K and L) that reside primarily in Puget Sound/Georgia Basin during the spring, summer and fall. This population was listed as “endangered” in the US and Canada following a 20% decline between 1996 and 2001. The current study, using blubber/epidermis biopsy samples, contributes contemporary information about potential factors (i.e., levels of pollutants or changes in diet) that could adversely affect Southern Residents. Carbon and nitrogen stable isotopes indicated J- and L-pod consumed prey from similar trophic levels in 2004/2006 and also showed no evidence for a large shift in the trophic level of prey consumed by L-pod between 1996 and 2004/2006. ∑PCBs decreased for Southern Residents biopsied in 2004/2006 compared to 1993–1995. Surprisingly, however, a three-year-old male whale (J39) had the highest concentrations of ∑PBDEs, ∑HCHs and HCB. POP ratio differences between J- and L-pod suggested that they occupy different ranges in winter.     

Reunion hotspot activitity through tertiary time: Initial results from the ocean drilling program, leg 115

Leg 115 of the Ocean Drilling Program recovered basaltic rocks from four sites along the ancient trail of the Réunion hotspot. The age of volcanism, determined from biostratigraphic data at the four sites, increases to the north and records the motion of India away from the Réunion hotspot through Tertiary time. Hotspot activity began with the eruption of the Deccan flood basalt flows at the time of the Cretaceous/Tertiary boundary. The Réunion hotspot has been stationary with respect to other hotspots in the Atlantic and Indian Ocean basins through Tertiary time. The geochemical compositions of the drilled basalts differ according to the relative contributions of magmas from hotspot and MORB mantle sources.     

Explosion seismic reflections from the Earth’s core

Recent seismological studies have presented evidence for the existence of a layer with ultra-low seismic velocities at the core-mantle boundary at ca. 2900 km depth. We report high-amplitude, high-frequency, and laterally coherent seismic arrivals from three nuclear explosions in Siberia. With recording station intervals of 15 km, the seismic phases are readily correlated and show the presence of a thin, ultra-low velocity zone in a region where it was not previously reported. The duration and complexity of the arrivals are inconsistent with a simple core-mantle boundary and require a hitherto unidentified, kilometre-scale, fine structure in the ultra-low velocity zone. The observations may be explained by a ca. 7 km thick, two-layer, ultra-low velocity zone with exceptional low velocities, which indicate the presence of high percentages of melt (>15%), in particular in the lower part of the zone. Waveform variation implies lateral change in the thickness and physical properties of the ultra-low velocity zone with a wavelength of less than 100 km.     

Time-scale calibration by high-precision UPb zircon dating of interstratified volcanic ashes in the Ordovician and Lower Silurian stratotypes of Britain

High initial parent/daughter element ratios and a unique dual decay scheme make UPb zicron ages more precise and reliable than most isotopic ages, and thus inherently superior for time-scale calibration. Employing improved techniques to the conventional method of UPb dating, we have analyzed microgram-size (2–12 × 10⁻⁸ g) zircon fractions from biostratigraphically controlled volcanic ashes and dated key Paleozoic time-markers with a precision better than 1% (±2Ma). Four of the stratotype samples from Britain for which fission-track ages [1] were previously reported have yielded improved ages of:438.7 ± 2.0Ma for the lower Silurian zone of Coronograptus cyphus from Llandovery strata at Dob's Linn, southern Scotland;457.5 ± 2.2 Ma for a Middle Ordovician Caradoc (Longvillian) ash near Bala, North Wales, and;465.7 ± 2.1and464.6 ± 1.8 Ma for the Didymograptus artus Zone and the type Didymograptus Murchisoni Zone, respectively, of the Llanvirn Series at Arenig Fawr and Abereiddi Bay, Wales. Another sample from the zone of Dicellograptus anceps (P. pacificus Subzone) of the Ashgill Series at Dob's Linn has been dated at445.7 ± 2.4Ma, suggesting placement of the Ordovician-Silurian time boundary at approximately 441 Ma. A sixth bentonite from Caradocian age strata of North America (Spechts Ferry Shale, Decorah Formation, Missouri) is453.7 ± 1.8Ma old, indicating that the Rocklandian Stage of the Mohawkian Series is only slightly younger than the Longvillian Stage of the Caradoc Series in Britain.     

Petrology of Peter I Øy (Peter I Island), West Antarctica

Peter I Øy is located in the Bellinghausen Sea, 400 km NE of Thurston Island, West Antarctica. It is a Pleistocene volcanic island situated adjacent to a former tranform fault on the continental rise of the presently passive margin between the Pacific and Antarctica. New K-Ar age determinations ranging from 0.1 to 0.35 Ma show that the volcanism responsible for this island took place at the same time as post-subduction, rift-related volcanism occurred in the nearby Marie Byrd Land and the Antarctic Peninsula. The rocks of the island are alkalic basalt and hawaiite, benmoreite and trachyte. The basic tocks typically contain phenocrysts of olivine (Fo_61–84), diopsidic augite, and plagioclase (ca. An₆₀). Small xenoliths are present and consist of mantle-type spinel lherzolite, cumulate clinopyroxenite and gabbro and felsic inclusions that consist of medium-grained strained quartz, plagioclase, and abundant colorless glass. Chemically, the basic rocks are characterized by rather high MgO (7.8–10.2 wt.%) and TiO₂ (3.1–3.7 wt.%) and relatively low CaO (8.4–9.5 wt.%) contents. They have steep REE patterns, [(La/Yb)_N = 20] with HREE only 5 x chrondrite. Y and Sc are almost constant at relatively low levels. Compatible trace elements such as Ni and Cr show considerable variation (190–300 and 150–470 ppm, respectively.), whereas V shows only little variation. Sr and Nd isotope ratios vary slightly with ⁸⁷Sr/⁸⁶Sr averaging 0.70388 and ¹⁴³Nd/¹⁴⁴Nd 0.512782, both typical for ocean island volcanism. Lead isotope ratios are consistently high in basalts; ²⁰⁶Pb/²⁰⁴Pb = 19.194, ²⁰⁷Pb/²⁰⁴Pb = 15.728 and ²⁰⁸Pb/²⁰⁴Pb = 39.290, whereas benmoreïte is somewhat less radiogenic. Oxygen isotope analyses average δ¹⁸O = +6.0‰. Incompatible trace elements vary by a factor of 1.5–2.0 within the range of the basic rocks. It is proposed that the incompatible trace-element variations represent different degrees (<10%) of partial melting, and that these melts were later modified by minor (<15‰) olivine and spinel fractionation. The very small variation in Y (and Sc) and the very fractionated REE pattern indicate that the source had an Y- and HREE-rich residual phase, most probably garnet. Furthermore, it is suggested that the source was slightly hydrous and that melting took place at 18–20 kbar. Trachyte was derived by multiphase fractionation of ne-normative basalts, and benmoreite from hy-normative parental liquids. The rocks of Peter I Øy are generally of the same type and age as those outcropping in extensional regimes on the nearby continent, and therefore, these occurrences may be related to each other in some way. However, the Peter I Øy rocks are considerably more radiogenic in strontium and less radiogenic in neodymium than the rocks of the Antarctic Peninsula and Marie Byrd Land. Possible explanations are that Peter I Øy represent asthenospheric hot spot activity, or transtensional rifting as subduction ceased.