Investigating soil thermodynamic parameters of the active layer on the northern Qinghai-Tibetan Plateau

The soil thermodynamic parameters, including thermal conductivity, diffusivity and volumetric capacity within the active layer on the northern Tibetan Plateau, were calculated using the measured data of soil temperature gradient, heat flux, and moisture at four stations from October 2003 to September 2004. The results showed that the soil thermodynamic parameters exhibited clear seasonal fluctuation. The thermal conductivity and diffusivity in summer and autumn at Beiluhe, Kexinling, and Tongtianhe were larger than those in winter. The volumetric thermal capacity causes an opposite change; it was larger in autumn and winter than in summer. In spring, the soil thermal conductivity at the Kekexili station was larger than that in summer. Generally, fine-grained soils and lower saturation degrees in the topsoil might be a reason for the lower soil thermal conductivity in winter. For a given soil, soil moisture was the main factor influencing the thermodynamic parameters. The unfrozen water content that existed in frozen soils greatly affected the soil thermal conductivity, whose contribution rate was estimated to be 55 %. The thermodynamic parameters of frozen soils could be expressed as a function of soil temperature, volumetric ice content and soil salinity, while for the unfrozen ground the soil moisture content is the dominant factor for those thermal parameters. As for the soil thermal diffusivity, there exists a critical value of soil moisture content. When the soil moisture content becomes less than a critical value, the soil thermal diffusivity increases as the soil moisture content rises.     

Surface characterization of maize-straw-derived biochars and their sorption performance for MTBE and benzene

Biochars generated at various temperatures might show significant differences in sorption for organic contaminants. In this study, a series of biochars, generated from pyrolyzing maize straws at different temperatures, were systematically characterized. The characterization results showed that with increasing pyrolysis temperature, the surface areas, micropore areas and aromaticity of biochars were enhanced. Batch experiments were conducted to study methyl tert-butyl ether (MTBE) and benzene sorption to biochars. The results indicated that the sorption capacity of benzene to biochars was higher than that of MTBE. The higher pyrolyzed temperature of biochars resulted in a stronger sorption affinity for target compounds, and the dominant sorption mechanisms varied for biochars pyrolyzed at different temperatures. The sorption to biochars pyrolyzed at 700 and 800 °C performed a high adsorption capacity, which indicated that they might be a promising sorbent to remove MTBE and benzene from water. Biochar pyrolyzed at 400 °C showed transitional sorption mechanisms from partition to adsorption for MTBE and benzene. Pore-filling was a possible sorption mechanism to biochars pyrolyzed at high temperature.     

Regional frequency analysis of extreme precipitation and its spatio-temporal characteristics in the Huai River Basin, China

With the increasing exposure of populations and economy to natural hazards, the spatio-temporal characteristics of extreme rainfall remain a key subject of study. Based on annual maximum rainfall (AM) and peaks over threshold rainfall series at 30 meteorological stations during 1960–2011 in the Huai River Basin (HRB), spatio-temporal characteristics of extreme rainfall are analyzed through regional frequency analysis method using L-moments. The accuracy and uncertainty analysis of quantile estimations are also carried out, and the regional and at-site frequency analyses are compared. Results indicate the following: (1) During 1960–2011, AM precipitation at 20 stations in the HRB shows an increasing trend, while at the other 10 stations, it shows a decreasing trend. And both the increased and decreased trends are not significant. (2) The HRB can be categorized into three homogeneous regions via cluster analysis. For both at-site and regional frequency analyses, the root mean square error values increase with the increase in return periods. The estimations are reliable enough for the return periods of less than 100 years. The quantile estimates of large return period from regional frequency analysis are more accurate and have smaller uncertainty than those from at-site frequency analysis. (3) Extreme precipitation in the HRB concentrates in the upstream of the Huai River and YiShuSi water system in the east of the HRB. Generally, the area with extreme precipitation, especially the upper reaches of the Huai River and Yimeng Mountain areas, also has large standard variations of extreme precipitation, which will increase the risk of natural hazards.     

Hazardous geology zoning and influence factors in the near-shore shallow strata and seabed surface of the modern Yellow River Delta,China

In this study, on the basis of 3,200 km shallow stratigraphic section and side-scan sonar data of the coastal area of the Yellow River Delta, we delineated and interpreted a total of seven types of typical hazardous geologies, including the hazardous geology in the shallow strata (buried ancient channel and strata disturbance) and hazardous geology in the seabed surface strata (pit, erosive residual body, sand patch, sand wave and scour channel). We selected eight parameters representing the development scale of the hazardous geology as the zoning indexes, including the number of hazardous geology types, pit depth, height of erosive residual body, length of scour channel, area of sand patch, length of sand wave, width of the buried ancient channel and depth of strata disturbance, and implemented the grid processing of the research area to calculate the arithmetic sum of the zoning indexes of each unit grid one by one. We then adopted the clustering analysis method to divide the near-shore waters of the Yellow River Delta into five hazardous geology areas, namely the serious erosion disaster area controlled by Diaokou lobe waves, hazardous geology area of multi-disasters under the combined action of the Shenxiangou lobe river wave flow, accumulation type hazardous geology area controlled by the current estuary river, hazardous geology area of single disaster in the deep water area and potential hazardous geology area of the Chengdao Oilfield. All four of the main factors affecting the development of hazardous geology, namely the diffusion and movement of sediment flux of the Yellow River water entering the sea, seabed stability, bottom sediment type and distribution, as well as the marine hydrodynamic characteristics, show significant regional differentiation characteristics and laws. These characteristics and laws are consistent with the above-mentioned zoning results, in which the distribution, scale and genetic mechanism of hazardous geology are considered comprehensively. This indicates that the hazardous geology zoning based on the cluster analysis is a new attempt in research regarding the hazardous geology zoning of the near-shore waters of the modern Yellow River Delta and that this type of zoning has a high level of reasonability.     

黄河三角洲地下水动态变化及其与地面沉降的关系

为了分析黄河三角洲地下水动态及其与地面沉降的关系, 利用多年地下水和地面沉降监测数据, 发现黄河三角洲广饶县和东营区的地下水动态变化剧烈且地面沉降严重, 含水层多处于超采状态, 浅、深层地下水降落漏斗先后出现.深层地下水降落漏斗中心水位下降速度达2~3m/a.近年来, 东营和广饶地面沉降漏斗中心沉降量和速率分别为155.1mm、28.2mm/a和356.0mm、64.7mm/a.借助GIS技术及数理统计法, 发现深层地下水降落漏斗与沉降漏斗空间耦合良好, 深层地下水位与地面高程呈线性正相关, 相关系数为0.92, 深层地下水过度开采已成为影响沉降的最根本因素.井灌区第三粘性压缩层成为地面沉降主要贡献层, 且深层地下水降落漏斗中心的地下水位已低于第三承压含水层临界水位, 沉降趋于严重.      

基于Budyko假设和分形理论的水沙变化归因识别——以北洛河流域为例

全球气候变化及人类活动深刻影响了区域水文过程,进行水沙变化归因识别对流域生态保护和高质量发展尤为重要。基于Budyko假设和分形理论,采用弹性系数法,对北洛河流域上（丘陵沟壑区）、中（土石山林—高塬沟壑区）、下游（渭北旱塬农区）3种不同地貌和植被类型区1959—2019年的水、沙通量变化进行归因分析。结果表明,北洛河上、中、下游径流量均显著减少,由20世纪60年代的35 mm、32 mm、34 mm,减少到21世纪10年代的19 mm、24 mm、6 mm,60 a减少率分别为0.3 mm a^-1、0.2 mm a^-1、0.4 mm a^-1。上游输沙量极显著减少,中游降低趋势不显著,下游显著减少,由20世纪60年代的99×10⁶ t、8×10⁶ t、3×10⁶ t,减少到21世纪10年代的10×10⁶ t、3×10⁶ t、0.3×10⁶ t,60 a减少率分别为1.5×10⁶ t a^-1、0.04×10⁶ t a^-1、0.1×10⁶ t a^-1。20世纪70年代以来,上游径流变化逐渐受人类活动影响,且影响程度逐渐增强,21世纪10年代人类活动贡献率达66.3%;气候变化是中游径流变化的主控因子,21世纪10年代降雨和潜在蒸散发的贡献率分别为77.0%和20.2%;下游径流减少主要为人类活动影响,21世纪10年代其贡献率为64.3%。对比20世纪60年代流域输沙量变化始终受人类活动主导,21世纪10年代人类活动对上、中、下游输沙量减少的贡献率分别为80.7%、59.2%和92.7%。上游人类活动对输沙量减少的贡献中,退耕还林等沟坡措施和沟道工程措施分别为39.0%、42.7%,中、下游人类活动贡献的估算结果反映出高植被覆盖区和农区汲水灌溉对区域水、沙的影响特征。     

“软−硬”关系框架下城市型目的地出入境旅游响应路径——基于1997―2019年中国香港特区数据的组态分析

选取1997―2019年中国香港特区数据,使用定性比较分析（QCA）方法对出入境旅游流产生路径的前因条件以及结果条件进行分析,研究结果表明：① 在路径数量上,虽持续简化,但是仍然具有复杂性;② 在核心条件中,所有的单因素均不构成影响的核心条件,中国香港出入境旅游流路径受到多因素组合作用;③ 在前因条件中,“软?硬”关系影响存在差异,硬实力关系对高出入境旅游流起主导作用,软实力关系则对非高出入境旅游流作用较大;④ 在路径国家（地区）中,高和非高出入境旅游流存在显著地区差异;⑤ 在时间层面上,阶段1与阶段2、阶段3路径差异较大,表明时间节点的分割事件对中国香港出入境旅游的影响不同。     

基于GEE和遥感大数据的1986—2015年全球城镇用地扩张占用水体时空特征

以全球年度城市动态数据（GAUD）和全球地表水动态数据集（GSW）为基础数据,利用Google Earth Engine（GEE）解析了1986—2015年全球城镇用地扩张占用永久性和季节性水体的时空分布特征。研究发现：30 a间全球城镇用地扩张直接占用水体的面积为1 033.2 km²,其中包括季节性水体711.7 km²和永久性水体321.5 km²,呈现先增加后降低的变化趋势。亚洲是城镇用地扩张占用水体面积最多的大洲,其次是北美洲和欧洲,占用水体的面积分别为799.4 km²、122.5 km²和61.1 km²。欧洲是唯一以占用永久性水体为主的大洲。陆地面积排名前十的国家中,中国、美国和印度是城镇用地扩张占用水体面积最多的国家,占用水体的面积分别为573.1 km²、109.6 km²和24 km²。以占用永久性水体为主的国家是俄罗斯和阿尔及利亚。尽管世界各国在水资源保护方面做出了巨大努力,但实现联合国可持续发展目标背景下,需防控更多的水体因城镇用地扩张而消失。     

河西绿洲农田土壤呼吸特征及其对长期施肥的响应

以河西走廊典型的荒漠绿洲新垦农田为研究对象,设置9个施肥处理（高量有机肥,M3;高量氮磷肥,NP3;低量氮磷肥+高量有机肥,NP1M3;低量氮磷钾肥,NPK1;中量氮磷钾肥,NPK2;高量氮磷钾肥,NPK3;低量氮磷钾肥+高量有机肥,NPK1M3;中量氮磷钾肥+中量有机肥,NPK2M2;高量氮磷钾肥+低量有机肥,NPK3M1）,于2019—2020年7—8月采用LI-COR 8100对玉米农田土壤呼吸进行观测,分析土壤呼吸的变化、日动态及其主要影响因素。结果表明：（1）不同施肥处理,土壤呼吸速率M3>NP3>NPK1M3>NPK3M1>NPK2M2>NP1M3>NPK2>NPK3>NPK1,单施有机肥能显著提高土壤呼吸速率,较其他处理增长22.1%—41.4%。（2）不同施肥措施土壤呼吸日变化呈单峰曲线,峰值出现在13：00—16：00,土壤呼吸日变化主要受土壤温度变化的影响。（3）土壤温度和土壤湿度分别解释了土壤呼吸变化的24.2%—44.8%和7.7%—36.4%,土壤呼吸与土壤温度显著正相关,而与土壤湿度无显著相关性,不同施肥处理土壤呼吸温度敏感性系数Q₁₀值1.419—1.600。（4）土壤呼吸与有机质、总氮、总碳、碱解氮存在显著正相关关系,施用有机肥使土壤有机质、总氮、总碳、碱解氮分别提升188.9%、80.5%、79.3%、147.0%,进而促进土壤呼吸,土壤呼吸与玉米产量无显著关系。不同的施肥措施会对土壤质量和土壤呼吸产生不同影响,有机肥和氮磷钾化肥的平衡施用,能够在提升土壤质量的同时减少碳排放,可在生产实践中采用。     

鄱阳湖沙地沉积物粒度特征及其影响因素北大核心CSCD

鄱阳湖沙地是亚热带湿润区典型风沙化土地,土地沙化问题严峻。鄱阳湖沙地研究多在小范围开展,研究意义有限,应在多处进行沙地粒度比对研究。选取庐山市、都昌县、永修县和南昌市新建区等沙地样品57个,分析其粒度特征。结果表明:(1)鄱阳湖沙地主要由中沙、细沙和粗沙组成,三者总含量超90%;Mz均值为1.79Φ,分选较差,呈正偏和尖锐分布;(2)鄱阳湖沙地不同土地类型沉积物表层(0-5 cm)与20-40 cm深度粒度特征存在一定差异,固定沙丘、半固定沙丘、流动沙丘和河滩表层比20-40 cm深度粒径大,但流动沙丘和湿地草滩表层分选优于20-40 cm深度;湿地草滩和河滩优势粒级含量和粒度参数有别于沙丘;(3)鄱阳湖沙地固定沙丘、半固定沙丘和流动沙丘为风成沉积;河滩以河流作用为主,风蚀为辅;湿地草滩是在风力和水动力共同作用下形成的。鄱阳湖沙地沿盛行风向从南到北S、SK、K依次减小,风沙运动多以两跳一悬式为主,以就地起沙为主,河滩湖滩作为补充。