鲁西新泰孟家屯2.7Ga变质沉积岩与黑云斜长片麻岩锆石Hf同位素特征

对出露于山东新泰孟家屯2.7Ga的孟家屯岩组中石榴石石英岩(M08)、含十字石石榴石黑云母石英片岩(D242-Y2)和黑云斜长片麻岩(M03)(TTG质片麻岩)进行锆石Lu-Hf同位素分析。石榴石石英岩锆石核部176Lu/177Hf、176Hf/177Hf变化范围为0.001730～0.002546、0.281249～0.281360,锆石变质边部176Lu/177Hf、176Hf/177Hf变化范围为0.000123～0.002070、0.281241～0.281318;含十字石石榴石黑云母石英片岩锆石核部176Lu/177Hf、176Hf/177Hf变化范围为0.001334～0.002169、0.281226～0.281324,锆石变质边部176Lu/177Hf、176Hf/177Hf变化范围为0.000445～0.001375、0.281227～0.281309;黑云斜长片麻岩锆石176Lu/177Hf、176Hf/177Hf变化范围为0.000315～0.000847、0.281186～0.281265。孟家屯岩组石榴石英岩、含十字石石榴石黑去母石英片岩中碎屑(岩浆)锆石和黑云斜长片麻岩中岩浆锆石的εHf(t)分别为3.75～7.26、2.31～7.26和3.21～6.27,同时TDM1与其U-Pb年龄非常接近,表明它们起源于新生地壳的部分熔融。结合区域研究资料认为,2.7Ga是鲁西重要的一期构造岩浆热事件,也可能是华北克拉通重要的构造岩浆活动时期。变质沉积岩中许多变质增生锆石相对于核部岩浆锆石低176Lu/177Hf、高176Hf/177Hf,显示变质作用过程中石榴石的存在对锆石的Lu-Hf同位素体系有很大影响。     

Source apportionment and distribution of atmospheric mercury in urban Beijing,China

The concentration of gaseous elemental mercury (GEM) in the atmosphere of urban Beijing was measured from October 2003 to September 2004 to investigate the origins and spatial-temporal variations of atmospheric Hg. The mean value of Hg concentration is 17.1 ng·m-3 (n=653). The atmospheric Hg data showed spatial-temporal variations throughout the duration of our observation. The maximum GEM concentration (53.7 ng·m-3) was observed at Gucheng in the western area of urban Beijing. The GEM concentrations increased from the north to the south of the studied area, and were higher in winter than in summer. The highest and lowest monthly averages of GEM concentrations were measured to be 23.3 and 4.1 ng·m-3 in January and July, respectively. In addition, GEM concentrations are higher in the daytime than at night in Autumn and from 14 March to 15 April, but daily GEM variation showed an inverse pattern from 22 April to 22 May. In winter, two peak values of GEM concentrations occurred at 13:30 and 21:30. Daily variation of GEM concentrations in summer was the lowest in the four seasons. Mercury from coal combustion was estimated to be the main source of anthropogenic emissions in Beijing from October 2003 to September 2004. Additionally, Hg emission from natural gas burning was estimated to be another dominant source of atmospheric Hg in Beijing.     

晋豫间黄河峡谷黄土状沙丘的光释光年代学探讨

通过对风陵渡-三门峡晋豫间黄河峡谷的地貌考察和1:50000 地形图(1970年)的分析,初步查明了黄河南岸黄土状沙丘的分布特征.选取河南省灵宝市豫灵镇阌底约75m高的黄土状沙丘剖面进行了观测和取样.根据该剖面的粒度分布特点,选取中颗粒(40～90μm)石英进行了光释光(OSL)测年研究.采用简化SAR法测量样品的等效剂量(De),其中5个样品与SAR法测量的De值对比,结果在误差范围内一致.对阌底剖面自上而下19个样品运用简化SAR法做了OSL年龄测定,其中8个还进行了4～11μm细颗粒石英简易多测片再生法(SMAR)OSL测年,两个粒级石英的OSL年龄测定值在测量误差范围内一致.初步结果表明,晋豫间黄河峡谷阌底黄土状沙丘发育不晚于距今约5.5万年前,并延续到全新世初期,风沙堆积速率在3.2万年前后曾出现显著变化.     

陕北能源化工基地采煤对地下水资源的影响及对策

陕北能源化工基地侏罗纪煤田是中国煤炭工业战略西移的首选基地,采煤引起的地下水资源及生态环境响应的研究是一个不可逾越的课题。从分析水文地质工程地质条件入手,将煤田区划分为7个水文地质结构类型和5个含水系统,按照排泄基准面进一步将含水系统划分若干地下水流子系统。在经验公式和数值法预测结果的基础上,综合考虑研究区实际,提出了本区能够保障生态、水资源和采煤安全的冒裂带高度为240 m,"三带"安全高度为300 m,并据此将煤采区划分为非导水区、无水导水区、贫水导水区和富水导水区。从水资源的角度提出了"保水采煤"、"煤水共采"和"含水层再造"的煤炭资源开发近期和中远期对策。     

Re–Os age of non-mineralized black shale from the Kupferschiefer, Poland, and implications for metal enrichment

Six samples of non-mineralized black shale from a Kupferschiefer section in the northern part of the Polish Zechstein Basin (Zdrada IG-8 drill hole: 1026.16–1026.90 m) were studied for Re–Os isotopes and selected major and trace elements. These black shales, averaging 5.82 wt.% C_org and 1.69 wt.% S_tot, display very low base metal values (up to 106 ppb Cu, 792 ppb Pb, and 144 ppb Zn) and have abundances of 64–1376 ppb Re and 0.37–1.25 ppb Os, with a ¹⁸⁷Os/¹⁸⁸Os ratio of 6.95–22.5. The regression of all Re–Os data yields an age of 247 ± 20 Ma, which is within the range of uncertainties of previous Rb–Sr and K–Ar geochronological studies. The scatter in the Re–Os data can be explained in terms of fluctuations in sedimentary conditions, i.e., restricted basin with terrestrial influence.     

Re-Os geochronology of Cu and W-Mo deposits in the Balkhash metallogenic belt,Kazakhstan and its geological significance

<正>The Central Asian metallogenic domain(CAMD) is a multi-core metallogenic system controlled by boundary strike-slip fault systems.The Balkhash metallogenic belt in Kazakhstan,in which occur many large and super-large porphyritic Cu—Mo deposits and some quartz vein- and greisen-type W—Mo deposits,is a well-known porphyritic Cu—Mo metallogenic belt in the CAMD.In this paper 11 molybdenite samples from the western segment of the Balkhash metallogenic belt are selected for Re—Os compositional analyses and Re—Os isotopic dating.Molybdenites from the Borly porphyry Cu deposit and the three quartz vein-greisen W—Mo deposits—East Kounrad.Akshatau and Zhanet—all have relatively high Re contents(2712—2772μg/g for Borly and 2.267—31.50μg/g for the other three W—Mo deposits),and lower common Os contents(0.670—2.696 ng/g for Borly and 0.0051—0.056 ng/g for the other three).The molybdenites from the Borly porphyry Cu—Mo deposit and the East Kounrad,Zhanet,and Akshatau quartz vein- and greisen-type W—Mo deposits give average model Re—Os ages of 315.9 Ma,298.0 Ma,295.0 Ma,and 289.3 Ma respectively.Meanwhile,molybdenites from the East Kounrad,Zhanet,and Akshatau W—Mo deposits give a Re—Os isochron age of 297.9 Ma,with an MSWD value of 0.97.Re-Os dating of the molybdenites indicates that Cu—W—Mo metallogenesis in the western Balkhash metallogenic belt occurred during Late Carboniferous to Early Permian(315.9—289.3 Ma),while the porphyry Cu—Mo deposits formed at—316 Ma,and the quartz vein-greisen W—Mo deposits formed at ~298 Ma.The Re—Os model and isochron ages thus suggest that Late Carboniferous porphyry granitoid and pegmatite magmatism took place during the late Hercynian movement.Compared to the Junggar-East Tianshan porphyry Cu metallogenic belt in northwestern China,the formation of the Cu—Mo metallogenesis in the Balkhash metallogenic belt occurred between that of the Tuwu-Yandong in East Tianshan and the Baogutu porphyry Cu deposits in West Junggar. Collectively,the large-scale Late Carboniferous porphyry Cu—Mo metallogenesis in the Central Asian metallogenic domain is related to Hercynian tectono-magmatic activities.     

Biosorption of cadmium(II) from aqueous solution onto <Emphasis Type="Italic">Hydrilla verticillata</Emphasis>

Biosorption is an effective method to remove heavy metals from wastewater. In this work, the biosorption of Cd(II) onto Hydrilla verticillata was examined in aqueous solution with parameters of initial pH, adsorbent dosage, contact time, initial Cd(II) concentration, temperature, and co-existing ion. Linear Langmuir and Freundlich models were applied to describe the equilibrium isotherms, and both of the two models were fitted well. The monolayer adsorption capacity of Cd(II) was found to be 50 mg/g at pH 6 and 20°C. Dubinin–Radushkevich isotherm model was also applied to the equilibrium data. The mean free energy of adsorption (11.18 kJ/mol) indicated that the adsorption of Cd(II) onto H. verticillata might be carried out via chemical ion-exchange mechanism. Thermodynamic parameters, including free energy (∆G ⁰), enthalpy (∆H ⁰), and entropy (∆S ⁰) of adsorption, were also calculated. These results showed that the biosorption of Cd(II) onto H. verticillata was a feasible, spontaneous, and exothermic process in nature. Desorption experiments indicated that 0.01 mol/L EDTA and HNO₃ were efficient desorbents for the recovery of Cd(II) from biomass. IR spectrum analysis suggested that amido, hydroxyl, C=O and C–O could combine strongly with Cd(II). EDX spectrum analysis suggested that an ion exchange mechanism might be involved.     

Radium-traced nutrient outwelling from the Subei Shoal to the Yellow Sea: Fluxes and environmental implication

The Subei Shoal is the largest sandy ridge in the southern Yellow Sea and is important source for nutrient loading to the sea. Here, the nutrient fluxes in the Subei Shoal associated with eddy diffusion and submarine groundwater discharge（SGD） were assessed to understand their impacts on the nutrient budget in the Yellow Sea. Based on the analysis of 223 Ra and 224 Ra in the field observation, the offshore eddy diffusivity mixing coefficient and SGD were estimated to be 2.3×10⁸ cm     

半球形多向波聚合波道振荡水柱气室优化设计

为了解决振动水柱式波浪能转换装置收集多向波浪问题,本文设计了半球形多向聚合波道振荡水柱气室结构,以适合远海单点波浪能采集和发电。在规则波正向入射条件下,基于流体仿真分析软件(FLUENT)、流体动力学连续性假设和粘性不可压缩流体动量守恒的运动方程(Navier-Stokes方程)建立半球形振荡气室和三维数值波浪水槽模型。仿真结果表明:增设气室后壁,合理设计波道开口角度实现多向迎波捕获波浪能,优化前壁形状可降低波浪触底反射带来的能量耗散,同时提高了气室内空气压强和出气口速度,有效提升波浪能俘获效率,为后续发电的二次能量转换提供高效的空气动力。     

微塑料添加对小麦苗期生长及干物质分配的影响

土壤环境中微塑料污染已成为全球关注的环境问题。关于微塑料对于植物生长的直接影响和由于土壤理化性状改变的间接影响研究已逐步开展,但针对小麦的研究鲜见报道。试验选择两个旱地小麦品种(甘春27和禾尚头)作为研究对象,选取高密度聚乙烯作为微塑料添加,设置3种质量浓度(0、1、4 g·kg^-1)开展盆栽试验,对不同微塑料组合处理下小麦的出苗率、株高、全株生物量和地上/地下干物质分配进行了分析。结果表明：(1)微塑料添加对两个品种出苗率没有影响。(2)禾尚头在添加1 g·kg^-1微塑料时比添加0、4 g·kg^-1时全株生物量分别高46.7%、8.5%,甘春27在添加1 g·kg^-1微塑料时比添加0、4 g·kg^-1时全株生物量分别高28.7%、17.2%;甘春27整体比禾尚头在3种浓度处理下全株生物量分别高24.9%、9.6%、1.5%。(3)不同试验处理条件下,甘春27将更多的干物质分配在地上植株的构建,其在地下(根系)和地上(茎叶)部分的分配比例整体小于禾尚头。整体上,适度微塑料添加可...