Input-output models

Summary Elementary mass balance and export models are explored in relation to eutrophication as caused by phosphorus and nitrogen. New criteria for phosphorus loading are given in relation to the ratio ‘mean depth-water fill-in-time’ . The results suggest that lakes having long water renewal times are much more sensitive to phosphorus loading than would appear from mean depth only. Further, from comparison of the relative residence time of nitrogen and phosphorus, it is deduced that—with increasing eutrophication—the nitrogen metabolism is speeded up beyond the point of simple proportionality which would explain the transition from phosphorus to nitrogen limitation in highly eutrophied lakes. It is further suggested that the principles derived from eutrophication in regard to the metabolism of phosphorus and nitrogen in lakes are applicable also to other environmental compartments and stress factors.

---

Zusammenfassung Elementare Massenbilanzen und Exportmodelle werden bezüglich ihrer Bedeutung für die Eutrophierung von Seen mit Phosphor und Stickstoff untersucht. Als neues Kriterium für die Phosphorbelastung wird das Verh?ltnis ?mittlere Wassertiefe-Zeit der Wassererneuerung? eingeführt. Die Beobachtungen lassen vermuten, dass Seen mit langen Wassererneuerungsperioden viel empfindlicher auf die Phosphorbelastung ansprechen, als aus ihrer mittleren Tiefe geschlossen werden k?nnte. Aus dem Vergleich der mittleren Aufenthaltszeiten von Stickstoff und Phosphor ergibt sich, dass mit zunehmender Eutrophie der Stickstoffumsatz weit st?rker beschleunigt wird, als der einfachen Proportionalit?t zu seiner Konzentrationszunahme entsprechen würde. Dies erkl?rt die Verschiebung von Phosphor zu Stickstoff als limitierendem Faktor in hocheutrophierten Seen. Es wird vermutet, dass die Prinzipien, welche bezüglich der Eutrophierung aus dem Umsatz von Phosphor und Stickstoff in Seen abgeleitet werden, auch für andere Lebensr?ume und andere Belastungsfaktoren angewendet werden k?nnen.

---

Résumé Un équilibre massive élémentaire et des modèles de sortie ont été explorés en relation avec l’eutrophisation provoquée par le phosphore et l’azote. De nouveaux critères ont été décrits en relation avec le taux ?profondeur moyenne?—durée de remplissage d’eau? . Les résultats suggèrent que les lacs dont la durée de renouvellement de l’eau est longue, sont beaucoup plus sensibles aux charges de phosphore, que ne laisserait appara?tre le critère seul de la profondeur moyenne. De plus, en comparant les durées relatives de séjour de l’azote et du phosphore, on déduit que—avec la progression de l’eutrophisation—le métabolisme de l’azote est accéléré au delà du point de simple proportionalité qui expliquerait la transition du phosphore à l’azote en tant que nutriment limitant dans des lacs fortement eutrophes. En outre, il est suggéré que les principes, dérivant de l’eutrophisation des lacs en relation avec le métabolisme du phosphore et de l’azote, sont également applicables à d’autres compartiments et facteurs de containte de l’environnement.

---

---

Paper given at the Conference on Chemical-Ecological Considerations for Defining the Goals of Water Pollution Control, Kastanienbaum, Switzerland, April 19–21, 1972.     

Ambient Changes in Tracer Concentrations from a Multilevel Monitoring System in Basalt

Starting in 2008, a 4‐year tracer study was conducted to evaluate ambient changes in groundwater concentrations of a 1,3,6‐naphthalene trisulfonate tracer that was added to drill water. Samples were collected under open borehole conditions and after installing a multilevel groundwater monitoring system completed with 11 discrete monitoring zones within dense and fractured basalt and sediment layers in the eastern Snake River aquifer. The study was done in cooperation with the U.S. Department of Energy to test whether ambient fracture flow conditions were sufficient to remove the effects of injected drill water prior to sample collection. Results from thief samples indicated that the tracer was present in minor concentrations 28 days after coring, but was not present 6 months after coring or 7 days after reaming the borehole. Results from sampling the multilevel monitoring system indicated that small concentrations of the tracer remained in 5 of 10 zones during some period after installation. All concentrations were several orders of magnitude lower than the initial concentrations in the drill water. The ports that had remnant concentrations of the tracer were either located near sediment layers or were located in dense basalt, which suggests limited groundwater flow near these ports. The ports completed in well‐fractured and vesicular basalt had no detectable concentrations.     

Look out, aurorae about!

Jim Wild recounts the rationale and success of AuroraWatch, a service that alerts you when you might be able to see aurorae.     

A mineral magnetic and scaled-chrysophyte paleolimnological study of two northeastern Pennsylvania lakes: records of fly ash deposition, land-use change, and paleorainfall variation

A combined mineral magnetic and scaled chrysophyte study of lake sediments from Lake Lacawac and Lake Giles in northeastern Pennsylvania was conducted to determine the effects of land-use and sediment source changes on the variation of pH, conductivity, and alkalinity inferred from biotic changes. Ten 30–40 cm long gravity cores were collected from Lake Lacawac and three from Lake Giles. Isothermal remanent magnetizations (IRMs) were given to the lake sediments in a 1.3 T magnetic field to measure magnetic mineral concentration variations. IRM acquisition experiments were conducted to identify magnetic mineralogy. The bedrock, soils and a peat bog on the shores of Lake Lacawac were also sampled for magnetic analysis to determine possible lake sediment sources. The top 10 cm of sediment collected from Lakes Lacawac and Giles was two to four times more magnetic than deeper sediment. ²¹⁰Pb dating suggests that this intensity increase commenced circa 1900. SEM images of magnetic extracts from the highly magnetic sediments indicates the presence of magnetic fly ash microspheres from fossil fuel burning electric power generation plants. The similarity in magnetic coercivity in the top 8 cm lake sediments and in the peat bog supports an atmospheric source for some of the magnetic minerals in the youngest lake sediments. The highly magnetic sediments also contain an antiferromagnetic mineral in two cores closest to Lake Lacawacs southeastern shore. This magnetic mineral is only present deep in the soil profile and would suggest erosion and significant land-use changes in the Lacawac watershed as another cause for the high magnetic intensities (concentrations) in the top 10 cm of the lake sediments. The most significant changes in the scaled chrysophyte flora occurred immediately above the 10 cm level and were used to infer a doubling of the specific conductivity between circa 1910 and 1929. These variations also support land-use changes in the Lacawac catchment at this time. A similar shift in the scaled chrysophte flora was not observed in the top of Lake Giles, however, distinct changes were found in the deeper sections of the core coupled with a smaller peak in magnetic concentration. Fourier analysis of the ²¹⁰Pb-dated lake sediment magnetics indicates the presence of a 50 year period, low amplitude variation in the Lake Lacawac, Lake Giles, and Lake Waynewood (Lott et al., 1994) magnetic concentration records. After removal of the land-use/fly ash magnetic concentration peak by Gaussian filtering, the 50 year variation correlates strongly from lake to lake even though the lakes are in different watersheds separated by up to 30 km. When this magnetic variation is compared with Gaussian-filtered rainfall variations observed in New York City and Philadelphia over the past 120–250 years there is a strong correlation suggesting that magnetic concentration variations can record regional rainfall variations with an approximately 50 year period. This result indicates that magnetics could be used to document regional variations in climatic change.