Schorlomite: a discussion of the crystal chemistry, formula, and inter-species boundaries

Examination of schorlomite from ijolite at Magnet Cove (USA) and silicocarbonatite at Afrikanda (Russia), using electron-microprobe and hydrogen analyses, X-ray diffraction and Mössbauer spectroscopy, shows the complexity of substitution mechanisms operating in Ti-rich garnets. These substitutions involve incorporation of Na in the eightfold-coordinated X site, Fe²⁺ and Mg in the octahedrally coordinated Y site, and Fe³⁺, Al and Fe²⁺ in the tetrahedrally coordinated Z site. Substitutions Ti⁴⁺Fe³⁺Fe³⁺_–1Si_–1 and Ti⁴⁺Al³⁺Fe³⁺_–1Si_–1 are of major significance to the crystal chemistry of schorlomite, whereas Fe²⁺ enters the Z site in relatively minor quantities (<3% Fe). There is no evidence (either structural or indirect, such as discrepancies between the measured and calculated Fe²⁺ contents) for the presence of ^[6]Ti³⁺ or ^[4]Ti⁴⁺ in schorlomite. The simplified general formula of schorlomite can be written as Ca₃Ti⁴⁺₂[Si_3-x(Fe³⁺,Al,Fe²⁺)_xO₁₂], keeping in mind that the notion of end-member composition is inapplicable to this mineral. In the published analyses of schorlomite with low to moderate Zr contents, x ranges from 0.6 to 1.0, i.e. Ti⁴⁺ in the Y site is <2 and accompanied by appreciable amounts of lower-charged cations (in particular, Fe³⁺, Fe²⁺ and Mg). For classification purposes, the mole percentage of schorlomite can be determined as the amount of ^[6]Ti⁴⁺, balanced by substitutions in the Z site, relative to the total occupancy in the Y site: (^[6]Ti⁴⁺–^[6]Fe²⁺–^[6]Mg²⁺– ^[8]Na⁺)/2. In addition to the predominant schorlomite component, the crystals examined in this work contain significant (>15 mol.%) proportions of andradite (Ca₃Fe³⁺₂Si₃O₁₂), morimotoite (Ca₃Fe²⁺TiSi₃O₁₂), and Ca₃MgTiSi₃O₁₂. The importance of accurate quantitative determination and assignment of Fe, Ti and other cations to the crystallographic sites for petrogenetic studies is discussed.

A STUDY OF THE SEISMIC SIGNATURES OF SEDIMENTATION MODELS USING SYNTHETIC SEISMOGRAMS*

In modern exploration for hydrocarbons there is a great emphasis on the location of stratigraphic traps and estimation of lithologic information like sand-shale ratios from seismic data. In order to investigate the possibilities of success in this endeavour we have studied the synthetic seismograms for wave form and spectral characteristic for four basic sedimentation models: (I) interbedded sand-shale model representing the sediments of generally fluviatile origin, (2) interbedded coal-shale model representing deltaic deposits, (3) sedimentary models representing transgression and regression of shore lines, and (4) a basal sand model. The results have shown that for the first two models a change in the sand-shale or coal-shale ratio results in a characteristically different seismogram. The nature of the seismogram, however, is also strongly dependent on how the sand-shale or coal shale layers are arranged to ultimately give the same number of total layers, thus implying the same coal-shale or sand-shale ratios. The transgression, regression, and basal sand models also produce characteristically different seismic signatures. The spectra of these seismograms show attendant characteristic changes. However, it seems that in the case of real data which are disturbed by noise and the effects of overlying layers these characteristic features may not always be distinguishable.     

Density Structure,Isostatic Balance and Tectonic Models of the Central Tien Shan

A new combined satellite-terrestrial model of the gravity field is used together with seismic data for construction of a density model of the lithosphere of the Central Tien Shan and for estimation of its isostatic balance. The Tien Shan is one of the most active intraplate orogens in the world, located about 1,500 km north of the convergence between Indian and Eurasian plate, and surrounded by stable Kazakh platform to the north and the Tarim block to the south. Although this area was extensively studied during recent decades, several principal problems, related to its structure and tectonics, remain unsolved up to now: (1) various geodynamic scenarios have been discussed so far to explain tectonic evolution, such as direct “crustal shortening,” intracontinental subduction and some others, but no definite evidence for any of them has been found. (2) Still, it is not clear why Tien Shan grows so far from the plate boundary at the Himalayan collision zone. Gravity modeling can provide valuable constraints to resolve these questions. The results of this study show that: (1) there exists a very strong deflection of the Tien Shan lithosphere from isostatic equilibrium. At the same time, the patterns of the isostatic anomalies are very different in the Western and Central Tien Shan. The latter one is characterized by much stronger variations. The best fit of the modeling results is found for the model according to which the Tarim plate partially underthrusts the Central Tien Shan; (2) negative density anomalies in the upper mantle under the central block possibly relate to magmatic underplating during the initial stage of the tectonic evolution. Therefore, the weak lithosphere could be the factor that initiates mountain building far away from the collision zone. Alternatively, this might be a gap after detachment of the eclogised lower crust and lithospheric lid, which is filled with the hot asthenospheric material.     

Free convection effects on the oscillatory flow in the Stokes's problem past an infinite porous vertical limiting surface with constant suction — I

An analysis of Rayleigh's problem (also Stokes's problem) for the flow of a viscous fluid (e.g. of a stellar atmosphere) past an impulsively started infinite, vertical porous limiting surface (e.g. of a star) with constant suction, when the free stream velocity oscillates in time about a constant mean, has been carried out. On solving the coupled non-linear equations in approximate way, expressions for the mean velocity, the mean temperature, the mean skin-friction and the mean rate of heat transfer, expressed in terms of Nusselt number, are obtained. The effects of Grashof numberG, Eckert numberE and Prandtl numberP, on these quantities, is discussed for the cases of an externally heating and cooling of the limiting surface, by the free convection currents, and the variations of them are shown graphically.     

Evaluation of Interactions Between Oilfield Chemicals and Reservoir Rocks

Natural Resources Research - Sand failure and production occurs when the formation stress exceeds the strength of the formation, which is derived majorly from the natural material that cements the...     

A STUDY ON A NEW MECHANICAL MODEL FOR FOUNDATIONS AND ITS ELASTIC SETTLEMENT RESPONSE

In the present paper, a new foundation model has been proposed by introducing a stretched rough elastic membrane in the Pasternak shear layer sandwiched between two spring layers which is an extension of Kerr model. Considering the equilibrium of different elements, the equations governing the elastic settlement response of the model are derived. Finite difference scheme has been employed to solve the governing equations. The parametric studies carried out show the effect of several parameters on the elastic settlement response of the model. The proposed model is well suited for idealizing the behavior of geosynthetic-reinforced granular fill—soft soil system besides other applications.     

Mantle(?) xenoliths in the carbonatites of northern Transbaikalia

The composition and nature of high-Cr minerals in lithic clasts from the carbonatites of the Veseloe occurrence, northern Transbaikalia, were considered. In order to determine their source, the Cr-bearing phases were compared with chromite, magnetite, and rutile from ultrabasic rocks, mantle xenoliths, and eclogites. It was suggested that the xenoclasts studied were formed at great depths, whereas the carbonatites were directly derived from the mantle rather than formed by the crustal differentiation of a silicate-carbonate melt.     

Power spectrum of brightness temperature fluctuations derived from solar eclipse observations at 2.8 GHz

In this paper we report on the MEM power spectrum analysis of brightness temperature fluctuations observed at 2.8 GHz during the total solar eclipse of 16 February 1980. The observed periodicities range from 3.5 min to 64 min. These periodicities may arise due to spatial and/or temporal variations in the solar radio emission. The observed periodicities imply presence of scale sizes ranging from 70,000 to 600,000 km assuming that the brightness fluctuations arise because of spatial variation only. On the other hand, if these fluctuations are due to temporal variation, the observed periodicities correspond well to predicted modes of solar global oscillations.     

First data on the noble metal geochemistry of the rocks from the gabbro-anorthosite massifs of the Kalar group

This paper addresses the geochemical features of the noble metal disseminated sulfide and Timagnetite mineralization in the rocks of the Kalar group of autonomous gabbro-anorthosite massifs. The investigations suggest that this mineralization was formed in two stages. The first stage is related to the gabbroanorthosites proper and may be promising for low-sulfide PGE mineralization as well as PGE-bearing Ti-magnetite mineralization, while the second stage is linked to the ultrabasic intrusions associated with copper-nickel or chromite mineralization accompanying by PGE. The horizons of low-sulfide mineralization in the gabbro-anorthosites and copper-nickel mineralization in the dunite-pyroxenites are characterized by the Pd predominance over Pt, while the Cr-bearing and Ti-magnetite ores show the Pt predominance over Pd.