Some reflections on World Heritage

Summary This paper presents some initial reflections on the emergence of the World Heritage Convention in 1972, the significance of the appellation 'world' and the interpretation of 'heritage'. The dichotomous definition of heritage has found decreasing support in practice and occasioned changes in the original Operational Guidelines for implementing the Convention .     

Recovering magnetic susceptibility from electromagnetic data over a one-dimensional earth

While the inversion of electromagnetic data to recover electrical conductivity has received much attention, the inversion of those data to recover magnetic susceptibility has not been fully studied. In this paper we invert frequency-domain electromagnetic (EM) data from a horizontal coplanar system to recover a 1-D distribution of magnetic susceptibility under the assumption that the electrical conductivity is known. The inversion is carried out by dividing the earth into layers of constant susceptibility and minimizing an objective function of the susceptibility subject to fitting the data. An adjoint Green's function solution is used in the calculation of sensitivities, and it is apparent that the sensitivity problem is driven by three sources. One of the sources is the scaled electric field in the layer of interest, and the other two, related to effective magnetic charges, are located at the upper and lower boundaries of the layer. These charges give rise to a frequency-independent term in the sensitivities. Because different frequencies penetrate to different depths in the earth, the EM data contain inherent information about the depth distribution of susceptibility. This contrasts with static field measurements, which can be reproduced by a surface layer of magnetization. We illustrate the effectiveness of the inversion algorithm on synthetic and field data and show also the importance of knowing the background conductivity. In practical circumstances, where there is no a priori information about conductivity distribution, a simultaneous inversion of EM data to recover both electrical conductivity and susceptibility will be required.     

Leucoxene fish as a micro-kinematic indicator

Asymmetric aggregates of fine-grained leucoxene and quartz are reported from siliceous L-S tectonites deformed by progressive simple shear. The leucoxene fish, morphologically similar to mica fish, consistently yield shear senses in agreement with other kinematic criteria. We interpret the leucoxene as a pre- or early syntectonic alteration product of detrital heavy-minerals in a siliciclastic protolith. The leucoxene fish behave as passive markers, and they record kinematics by modification of pre-existing aggregates rather than syndeformational mineral growth. For siliceous metasedimentary rocks otherwise lacking in micro-kinematic indicators, leucoxene fish may provide an alternative to quartz c-axis analysis.     

Arrays of Unpumped Wells for Plume Migration Control by Semi-Passive In Situ Remediation

Arrays of unpumped wells can be used as discontinuous permeable walls in which each well serves both as a means to focus ground water flow into the well for treatment and as a container either for permeable reactive media which directly destroy dissolved ground water contaminants or for devices or materials which release amendments that support in situ degradation of contaminants within the aquifer downgradient of the wells. This paper addresses the use of wells for amendment delivery, recognizing the potential utility of amendments such as electron acceptors (e.g., oxygen nitrate), electron donors (primary substrates), and microbial nutrients for stimulating bioremediation, and the potential utility of oxidizers, reducers, etc., for controlled abiotic degradation. Depending on its rate and constraints, the remedial reaction may occur within the well and/or downgradient. For complete remediation of ground water passing through the well array, the total flux of amendment released must meet or exceed the total flux demand imposed by the plume. When there are constraints on the released concentration of amendment (relative to the demand), close spacing of the wells may be required. If the flux balance allows wider spacing, it is likely that limited downgradient spreading of the released amendment will then be the primary constraint on interwell spacing. Divergent flow from the wells, roughly two times the well diameter, provides the bulk of downgradient spreading and constrains maximum well spacing in the absence of significant lateral dispersion. Stronger lateral dispersion enhances the spreading of amendment, thereby increasing the lateral impact of each well, which allows for wider well spacing.     

Cold anticyclonic eddies formed from cold pool water in the southern Middle Atlantic Bight

AVHRR satellite imagery of the southern Mid-Atlantic Bight during May 1993 revealed a large area of cold water over the shelf break and slope that appeared to spin up into a series of southward propagating anticyclonic eddies. The eddies had diameters of 35–45 km at the surface and moved southward at about 20 cm/sec. A radial TOYO CTD (to 50m) and ADCP velocity (to 400m) transect was conducted across the southern-most of these eddies. The upper 50 meters had minimum temperatures of less than 7°C and salinities of about 33 pss, characteristics similar to cold pool waters usually found over the continental shelf. ADCP velocity data from one of the eddies revealed anticyclonic flow extending to a depth of about 250m. The transport of cold pool water by the eddies was estimated to be 0.1 to 0.2 Sv which is of the same order as the annual mean alongshore transport of shelf water in this region. The origin of the deeper water within the eddy is unlikely to be the continental shelf because the shelf break is less than 100 m. The depth and velocity profiles along the TOYO transect were consistent with the constant potential vorticity eddy model of Flierl (1979) although the source of the eddy kinetic energy is uncertain. The cause for the exodus of cold pool water from the shelf, which extended northward to at least 38°N, is unclear but must involve the establishment of an alongshore baroclinic pressure gradient against the usual southwestward shelf flow. It is possible that the intrusion of Gulf Stream waters onto the shelf near Cape Hatteras was a precursor of this off shelf transport. The southern-most eddy was marked by high biological productivity and very high oxygen supersaturation. The phytoplankton bloom detected within the exported cold pool water, located over the continental slope, suggests a mechanism whereby production fueled by nutrients derived from the shelf can be locally exported into deep water.     

The making of Stars 'R' Us!

The team behind a successful project to broaden the understanding of astrochemistry – Serena Viti, Wendy Brown, Martin McCoustra, Helen Fraser, Nigel Mason and Robert Massey – recount how they went about it and what benefits resulted.     

On the Incorporation of the Effect of Crustal Structure into Empirical Strong Ground Motion Estimation

This article has two purposes. Firstly, a validation exercise of the modal summation technique for the computation of synthetic strong-motion records is performed for two regions of Europe (Umbria-Marche and south Iceland), using a variety of region specific crustal structure models, by comparing the predicted ground motion amplitudes with observed motions. It is found that the rate of decay of ground motions is well predicted by the theoretical decay curves but that the absolute size of the ground motions is underpredicted by the synthetic time-histories. This is thought to be due to the presence of low-velocity surface layers that amplify the ground motions but are not included in the crustal structure models used to compute the synthetic time-histories. Secondly, a new distance metric based on the computed theoretical decay curves is introduced which should have the ability to model the complex decay of strong ground motions. The ability of this new distance metric to reduce the associated scatter in empirically derived equations for the estimation of strong ground motions is tested. It is found that it does not lead to a reduction in the scatter but this is thought to be due to the use of crustal structure models that are not accurate or detailed enough for the regions studied. This revised version was published online in July 2006 with corrections to the Cover Date.     

The geomorphic dynamics and environmental history of an upper deltaic floodplain tract in the Sacramento–San Joaquin Delta,California, USA

A multi‐proxy approach was used to examine the geomorphic dynamics and environmental history of an upper deltaic ?oodplain tract in the Sacramento–San Joaquin Delta, California. Three long cores were collected from the McCormack–Williamson Tract (MWT) and these cores were analyzed for bulk density, loss‐on‐ignition, ?ne (clay and silt) content, Al concentration, magnetic susceptibility, pollen, and charcoal. Radiocarbon dates obtained for the cores were converted into calendar years and an age–depth model was constructed. Long‐term vertical accretion and sedimentation rates were estimated from the age–depth model. Cross‐core relations show that coarse sediment generally accumulates more rapidly and has greater magnetic susceptibility compared to ?ne sediment. Percentage ?ne and LOI data show a strong linear relationship that indicates ?ooding is the primary mechanism for the deposition of particular organic matter on the ?oodplain and that landscape wash load has contributed a highly consistent fraction of persistent organic matter averaging 5·5 per cent to the site. Down‐core grain size pro?les show two hydrological domains in the cores, namely millennial ?ne–coarse ?uctuations superimposed on general up‐core ?ning. Coarse sediment is viewed as channel or near‐channel overbank deposits, whereas ?ne deposits are considered to be distal overbank ?ood deposits. The coarse–?ne ?uctuations are indicative of changing depositional settings as channels migrated laterally across MWT, whereas the upward ?ning trend re?ects a combination of self‐limiting overbank deposition as ?oodplain elevation increased and decreasing competence as sea‐level rise reduced ?ood‐pulse energy slopes. MWT has been cross‐cut and incised numerous times in the past, only to have the channels abandoned and subsequently ?lled by ?ne sediment. The channels around MWT attained their modern con?guration about 4000 years ago. MWT likely came under tidal in?uence at about 2500 cal BP. Wetlands have recently developed on MWT, but they are inorganic sediment dominated. Copyright © 2004 John Wiley & Sons, Ltd.     

Oxygen isotopic compositions of IVA iron meteorites: implications for the thermal evolution derived from in situ ultraviolet laser microprobe analyses

Oxygen isotopic compositions of silicate inclusions in IVA iron meteorites have been measured with an in situ UV laser microprobe technique. The homogeneity of oxygen isotopic compositions within and among individual mineral grains has also been examined. Oxygen isotope fractionations between coexisting mineral pairs were utilized in oxygen isotope thermometry. Our measured Δ¹⁷O values, ranging from 0.97 to 1.25‰, are characteristic of a single reservoir and fully confirm the oxygen isotopic similarity between IVA irons and L/LL chondrites. Steinbach and São João Nepomuceno, containing inclusions of two silicate minerals in mutual contact, exhibit a mass-dependent fractionation of ¹⁸O/¹⁶O between tridymite and bronzite with apparent oxygen isotopic heterogeneity. The SiO₂-bearing member, Gibeon, gives homogeneous oxygen isotopic compositions without detectable fractionation of ¹⁸O/¹⁶O between tridymite and quartz. Oxygen isotope equilibrium temperatures are estimated for coexisting tridymite and bronzite in the same sample slabs or clusters in Steinbach and São João Nepomuceno. The fractionations of ¹⁸O/¹⁶O between bronzite and tridymite range from 1.6 to 2.3‰ in different sample slabs or clusters. On the basis of the closure temperature concept, cooling rates are estimated at approximately 20 to 1000°C/Myr between 800 and 1000°C, a range of temperatures not accessible to other cooling rate methods. Using the Fast Grain Boundary diffusion model, we have demonstrated that significant oxygen heterogeneity both in tridymite and bronzite is probably due to isotope exchange during cooling between minerals with various grain sizes and mineral abundances in different regions of the samples. The new estimates of cooling rate by oxygen isotope thermometry refine previous cooling curves of IVA irons and support the breakup-reassembly model for the IVA parent body.