Geology, Geochemistry and Tectonic Significance of Mafic-ultramafic Rocks of Mesoproterozoic Phulad Ophiolite Suite of South Delhi Fold Belt, NW Indian Shield

A thick sequence of mafic-ultramafic rocks, occurs along a major shear zone (Phulad lineament), running across the length of Aravalli Mountain Range for about 300 kms. It has been suggested, that this sequence may represent a fragment of ophiolite or a rift related metavolcanic suite made up of basalts and fractionated ultramafics. The geological and tectonic significance of the complex is assessed using field relationships, petrography and geochemistry. Structurally, the lowest part of the complex comprises a discontinuous band of plastically deformed harzburgite (mantle component) followed by layered cumulus gabbroic rocks (crustal component). A complex of non-cumulus rocks comprising hornblende schists, gabbros, sheeted dykes and pillowed basalts structurally overlies layered gabbros. Huge bodies of diorite intrude volcanics.

Geochemical classification suggests that all non-cumulus mafic rocks are sub-alkaline basalts except one variety of dykes which shows mildly alkaline character. The sub-alkaline rocks are tholeiite to calc-alkaline with boninite affinity. Tectono-magmatic variation diagrams and MORB normalised patterns suggest a fore arc tectonic regime for the eruption of these rocks.

The mafic rocks of Phulad Ophiolite Suite are zoned across the strike in terms of their distribution from west to east. The hornblende schists and basalts are exposed at the westernmost margin followed by gabbros and dykes. The alkaline dyke occurs at the easternmost part. The rocks of Phulad suite are juxtaposed with shallow water sediments in the east followed by platformal sediments and then continental slope sediments in the further east indicating gradual thickening of the crust from west to east and an eastward subduction. The geochemical interpretation presented in this study, together with discussion of lithological association is used to decipher the tectonic evolution of the Mesoproterozoics of NW Indian shield.     

Groundwater control of mangrove surface elevation: Shrink and swell varies with soil depth

We measured monthly soil surface elevation change and determined its relationship to groundwater changes at a mangrove forest site along Shark River, Everglades National Park, Florida. We combined the use of an original design, surface elevation table with new rod-surface elevation tables to separately track changes in the mid zone (0–4 m), the shallow root zone (0–0.35 m), and the full sediment profile (0–6 m) in response to site hydrology (daily river stage and daily groundwater piezometric pressure). We calculated expansion and contraction for each of the four constituent soil zones (surface [accretion and erosion; above 0 m], shallow zone [0–0.35 m], middle zone [0.35–4 m], and bottom zone [4–6]) that comprise the entire soil column. Changes in groundwater pressure correlated strongly, with changes in soil elevation for the entire profile (Adjusted R² = 0.90); this relationship was not proportional to the depth of the soil profile sampled. The change in thickness of the bottom soil zone accounted for the majority (R² = 0.63) of the entire soil profile expansion and contraction. The influence of hydrology on specific soil zones and absolute elevation change must be considered when evaluating the effect of disturbances, sea level rise, and water management decisions on coastal wetland systems.     

Late Holocene environmental conditions in Coronation Gulf,southwestern Canadian Arctic Archipelago: evidence from dinoflagellate cysts,other non‐pollen palynomorphs,and pollen

Boxcore 99LSSL‐001 (68.095° N, 114.186° W; 211 m water depth) from Coronation Gulf represents the first decadal‐scale marine palynology and late Holocene sediment record for the southwestern part of the Northwest Passage. The record was studied for organic‐walled microfossils (dinoflagellate cysts, non‐pollen palynomorphs), pollen, terrestrial spores, and sediment characteristics. ²¹⁰Pb, ¹³⁷Cs, and three accelerator mass spectrometry ¹⁴C dates constrain the chronology. Three prominent palaeoenvironmental zones were identified. During the interval AD 1470–1680 (Zone I), the climate was warmer and wetter than at present, and environmental conditions were more favourable to biological activity and northward boreal forest migration, with reduced sea‐ice and a longer open‐water (growing) season. The interval AD 1680–1940 (Zone II) records sea‐ice increase, and generally cool, polar conditions during the Little Ice Age. During AD 1940–2000 (Zone III), organic microfossils indicate an extended open‐water season and decreased sea‐ice, with suggested amelioration surpassing that of Zone I. Although more marine studies are needed to place this record into an appropriate context, the succession from ameliorated (Zone I) to cooler, sea‐ice influenced conditions (Zone II) and finally to 20th‐century warming (Zone III) corresponds well with several terrestrial climatic records from the neighbouring mainland and Victoria Island, and with lower‐resolution marine records to the west. Copyright © 2011 John Wiley & Sons, Ltd.     

Application of a confluence‐based sediment‐fingerprinting approach to a dynamic sedimentary catchment,New Zealand

Fine sediment is a dynamic component of the fluvial system, contributing to the physical form, chemistry and ecological health of a river. It is important to understand rates and patterns of sediment delivery, transport and deposition. Sediment fingerprinting is a means of directly determining sediment sources via their geochemical properties, but it faces challenges in discriminating sources within larger catchments. In this research, sediment fingerprinting was applied to major river confluences in the Manawatu catchment as a broad‐scale application to characterizing sub‐catchment sediment contributions for a sedimentary catchment dominated by agriculture. Stepwise discriminant function analysis and principal component analysis of bulk geochemical concentrations and geochemical indicators were used to investigate sub‐catchment geochemical signatures. Each confluence displayed a unique array of geochemical variables suited for discrimination. Geochemical variation in upstream sediment samples was likely a result of the varying geological source compositions. The Tiraumea sub‐catchment provided the dominant signature at the major confluence with the Upper Manawatu and Mangatainoka sub‐catchments. Subsequent downstream confluences are dominated by the upstream geochemical signatures from the main stem of Manawatu River. Variability in the downstream geochemical signature is likely due to incomplete mixing caused in part by channel configuration. Results from this exploratory investigation indicate that numerous geochemical elements have the ability to differentiate fine sediment sources using a broad‐scale confluence‐based approach and suggest there is enough geochemical variation throughout a large sedimentary catchment for a full sediment fingerprint model. Combining powerful statistical procedures with other geochemical analyses is critical to understanding the processes or spatial patterns responsible for sediment signature variation within this type of catchment. Copyright © 2015 John Wiley & Sons, Ltd.     

A new approach to estimate canopy evaporation and canopy interception capacity from evapotranspiration and sap flow measurements during and following wetting

Canopy interception and its evaporation into the atmosphere during irrigation or a rainfall event are important in irrigation scheduling, but are challenging to estimate using conventional methods. This study introduces a new approach to estimate the canopy interception from measurements of actual total evapotranspiration (ET) using eddy covariance and estimation of the transpiration from measurements of sap flow. The measurements were conducted over a small‐scale sprinkler‐irrigated cotton field before, during and after sprinkler irrigation. Evaporation and sap flow dynamics during irrigation show that the total ET during irrigation increased significantly because of the evaporation of free intercepted water while transpiration was suppressed almost completely. The difference between actual ET and transpiration (sap flow) during and immediately following irrigation (post irrigation) represents the total canopy evaporation while the canopy interception capacity was calculated as the difference between actual ET and transpiration (sap flow) during drying (post irrigation) following cessation of the irrigation. The canopy evaporation of cotton canopy was calculated as 0.8 mm, and the interception capacity was estimated to be 0.31 mm of water. The measurement uncertainty in both the non‐dimensional ET and non‐dimensional sap flow was shown to be very low. Copyright © 2015 John Wiley & Sons, Ltd.     

Oxygen‐18 dynamics in precipitation and streamflow in a semi‐arid agricultural watershed,Eastern Washington,USA

Understanding flow pathways and mechanisms that generate streamflow is important to understanding agrochemical contamination in surface waters in agricultural watersheds. Two environmental tracers, δ¹⁸O and electrical conductivity (EC), were monitored in tile drainage (draining 12 ha) and stream water (draining nested catchments of 6‐5700 ha) from 2000 to 2008 in the semi‐arid agricultural Missouri Flat Creek (MFC) watershed, near Pullman Washington, USA. Tile drainage and streamflow generated in the watershed were found to have baseline δ¹⁸O value of ?14·7‰ (VSMOW) year round. Winter precipitation accounted for 67% of total annual precipitation and was found to dominate streamflow, tile drainage, and groundwater recharge. ‘Old’ and ‘new’ water partitioning in streamflow were not identifiable using δ¹⁸O, but seasonal shifts of nitrate‐corrected EC suggest that deep soil pathways primarily generated summer streamflow (mean EC 250 µS/cm) while shallow soil pathways dominated streamflow generation during winter (EC declining as low as 100 µS/cm). Using summer isotopic and EC excursions from tile drainage in larger catchment (4700‐5700 ha) stream waters, summer in‐stream evaporation fractions were estimated to be from 20% to 40%, with the greatest evaporation occurring from August to October. Seasonal watershed and environmental tracer dynamics in the MFC watershed appeared to be similar to those at larger watershed scales in the Palouse River basin. A 0·9‰ enrichment, in shallow groundwater drained to streams (tile drainage and soil seepage), of δ¹⁸O values from 2000 to 2008 may be evidence of altered precipitation conditions due to the Pacific Decadal Oscillation (PDO) in the Inland Northwest. Copyright © 2009 John Wiley & Sons, Ltd.