The finite volume method for Richards equation

In this paper we prove the convergence of a finite volume scheme for the discretization of an elliptic–parabolic problem, namely Richards equation β(P)_t?div(K(β(P))× ?(P+z))=0, together with Dirichlet boundary conditions and an initial condition. This is done by means of a priori estimates in L² and the use of Kolmogorov's theorem on relative compactness of subsets of L².     

The ideology behind the technology - Chilean microentrepreneurs and public ICT policies

Digital divides are differences in access to information and communication technologies (ICTs) which tend to reflect the social and regional inequalities between and within countries. This paper presents a case study from Chile, which is among the leaders in Latin America both in levels of e-readiness and in social and regional inequality. The Chilean state’s ICT policies are situated within the “Third Way” approach of the centre-left government, reflecting the tensions between a pro-active and positive view of neoliberal globalisation, and state social programmes to support poorer sectors of society.The paper presents a multi-level analysis of two elements of Chilean ICT policy: Chilecompra, an online public e-procurement system aimed at creating transparent and competitive transactions in line with neoliberal economic theory, and Red Comunitaria, a network of Community Information Centres which offer free internet access and training to individuals, including microentrepreneurs. Interviews were conducted at the national, regional and local level. Findings were that the Community Information Centres (telecentros) had indeed furthered digital inclusion while in the meantime the shift to e-procurement had excluded many microentrepreneurs who had not registered with the system of Chilecompra. The larger of the local enterprises had registered but were having difficulties competing online with bigger companies located in the regional and national capitals.The paper argues that while both state policies see themselves as successes, the political objectives underlying the technology mirror the Chilean government’s struggle to simultaneously embrace neoliberal globalisation while working towards greater social and regional cohesion. At the local level there is evidence of the failure to reconcile the two approaches which may be indicative of a more general tension between these goals.     

Geological characteristics and spatial distribution of paleo-inlet channels beneath the outer banks barrier islands,North Carolina,USA

Nearly 200 km of high-resolution ground penetrating radar (GPR) data were acquired along the Outer Banks barrier island system of North Carolina, USA. GPR data combined with lithofacies and biofacies data reveal multiple depositional facies including inlet channel, flood-tide delta, overwash, peat and inner shelf. Previously undocumented paleo-inlet channels constitute a significant portion of the shallow geologic framework between Oregon Inlet and Cape Hatteras. GPR data reveal the complex stratigraphy associated with multiple sequences of cut-and-fill within inlet channels. Two types of paleochannels (non-migrating and migrating) were classified based on geometry and fill-patterns. Sediments and foraminifera collected from vibracores were correlated to GPR data to define the regional shallow stratigraphic framework. Channel-fill facies are characterized by clinoform packages, sometimes bounded by erosional surfaces, indicating variable sediment transport directions from the ocean and sound sides. Channels are incised into older flood-tide delta deposits corresponding to older inlet activity when barriers existed further seaward. Flood-tide delta deposits are capped with marsh peat and overwash units. Migrating inlet facies occur under the widest portions of the island, whereas narrow portions of the island are underlain by the non-migrating inlet facies or flood-tide delta/overwash facies. This geologic/geomorphic relationship is attributed to the successional stage of island evolution during transgression, and sediment transport processes associated with the different inlet types. The radar facies, lithofacies, and biofacies provide a comprehensive dataset that will permit more precise identification of barrier island facies in the geologic record.     

53Mn and 60Fe in iron meteorites—New data,model calculations

We measured specific activities of the long‐lived cosmogenic radionuclides ⁶⁰Fe in 28 iron meteorites and ⁵³Mn in 41 iron meteorites. Accelerator mass spectrometry was applied at the 14 MV Heavy Ion Accelerator Facility at ANU Canberra for all samples except for two which were measured at the Maier‐Leibnitz Laboratory, Munich. For the large iron meteorite Twannberg (IIG), we measured six samples for ⁵³Mn. This work doubles the number of existing individual ⁶⁰Fe data and quadruples the number of iron meteorites studied for ⁶⁰Fe. We also significantly extended the entire ⁵³Mn database for iron meteorites. The ⁵³Mn data for the iron meteorite Twannberg vary by more than a factor of 30, indicating a significant shielding dependency. In addition, we performed new model calculations for the production of ⁶⁰Fe and ⁵³Mn in iron meteorites. While the new model is based on the same particle spectra as the earlier model, we no longer use experimental cross sections but instead use cross sections that were calculated using the latest version of the nuclear model code INCL. The new model predictions differ substantially from results obtained with the previous model. Predictions for the ⁶⁰Fe activity concentrations are about a factor of 2 higher, for ⁵³Mn, they are ~30% lower, compared to the earlier model, which gives now a better agreement with the experimental data.     

Suitability of Mn‐ and Fe‐Rich Reference Materials for Microanalytical Research

Manganese‐ and iron‐rich materials are of major geoscientific and economic interest, many of which contain microscopic features that provide valuable information. To obtain accurate results, a homogeneous microanalytical reference material for calibration is needed. Several researchers have used the Mn‐ and Fe‐rich RMs, JMn‐1, NOD‐A‐1, NOD‐P‐1 and FeMn‐1, for this purpose; therefore, they were tested in this study to determine their suitability for microanalysis. Their homogeneity was investigated by laser ablation‐inductively coupled plasma‐mass spectrometry (LA‐ICP‐MS) with two different types of lasers (nano‐ and femtosecond), with spot and line scan analyses and with different operating parameters, such as spot size, pulse repetition rate and fluence. As the established manganese nodule RMs revealed inhomogeneities for picogram to microgram test portions, we also investigated the new synthetic Fe‐ and Mn‐rich RM, FeMnOx‐1. FeMnOx‐1 was found to be homogeneous for large (ø 40 μm: 2% RSD repeatability) and small (ø 8–10 μm: 10% RSD repeatability) spot sizes. This homogeneity is in the range of the homogeneous NIST SRM 610 and GSE‐1G reference glasses. Furthermore, FeMnOx‐1 revealed a large‐scale homogeneity within uncertainties of a few per cent, using test portions in the ng range, when measuring four individual mounts of this material.     

Cryptogam covers on sepulchral monuments and re-colonization of a marble surface after cleaning

Re-colonization of freshly cleaned surfaces by aeroterrestrial microbial communities is up to now poorly understood. Here, we present a comparative study addressing the composition of algal and fungal communities on a marble sculpture, based upon the analysis of 18S rRNA gene clone libraries from environmental samples. The samples were taken from a blackish and greenish biofilm cover before surface cleaning and 1 year after cleaning treatment, when traces of re-colonization became visible to the naked eye. The composition of the fungal community indicated clear differences between the old grown biofilm and the treated surface. While the former was dominated by the ascomycetes Rhinocladiella, Glyphium and Capnodiales, the black yeast Sarcinomyces was clearly dominant 1 year after cleaning, but could not be retrieved from the old grown black biofilm. The green algal community was dominated by different phylotypes of the lichen algae Trebouxia, as well as the cosmopolitan green algae Apatococcus and Stichococcus. No essential differences in the green algal community before and after cleaning could be observed.