Enzymatische Bestimmung von Glucose,Fructose und Saccharose in Gewässern

Zusammenfassung Die Anwendung der vonBergmeyer mitgeteilten enzymatischen Bestimmung von Glucose, Fructose und Saccharose in Gew?ssern erfordert bei Zuckerkonzentrationen unter 50 μMol/l eine spezielle Vorbereitung des Analysengutes, die anhand eines Beispiels beschrieben wird. Reproduzierbarkeit und analytische Ausbeute der Methode werden angegeben. Es wird auf die M?glichkeit hingewiesen, die Methodik auch bei der Untersuchung geologischer Proben einzusetzen.

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Summary Enzymatic analysis of glucose, fructose and sucrose by the method given byBergmeyer requires a special procedure when these sugars are determined in natural waters at concentrations below 50 μMol/l. The modified method, its reproducibility and analytical yield are described. The possibility of applying this method also to geological samples is considered.

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Résumé Le méthode du dosage enzymatique de la glucose, la fructose et la saccharose, indiquée parBergmeyer, est modifiée pour les cas où ces sucres doivent être déterminés dans des eaux naturelles à des concentrations inférieures à 50 μMol/l. On examine la variation statistique et l'exploitation analytique de la méthode modifiée. Celle-ci pourrait également être utilisée pour l'analyse d'échantillons géologiques.

     

The Formation of Knots and Filaments in Shocks

We present a survey of different kinds of instabilities in the context of radiative colliding flows which greatly contribute to structure formation. In particular, this includes analytical results for different kinds of thin shell instabilities (DI, NDI, NTSI). New numerical results for the non-linear evolution of such instabilities in two dimensions, and their coupling with the thermal cooling instability are presented. The astrophysical implications are briefly outlined, in particular the formation of knots and filaments. This revised version was published online in July 2006 with corrections to the Cover Date.     

Hydrothermal gases offshore Milos Island, Greece

Hydrothermal fluids emerge from the seafloor of Paleohori Bay on Milos. The gases in these fluids contain mostly CO₂ but CH₄ concentrations up to 2% are present. The stable carbon isotopic composition of the CO₂ (near 0%) indicates an inorganic carbon source (dissociation of underlying marine carbonates). The carbon and hydrogen isotopes of most CH₄ samples are enriched in the heavy species (δ¹³C = −9.4 to −17.8‰; δD = −102 to −189‰) which is believed to be characteristic for an abiogenic production of CH₄ by CO₂-reduction (Fischer-Tropsch reactions). Depletions in the deuterium content of three CH₄ samples (to −377%) are probably caused by unknown subsurface rock alteration processes. Secondary hydrogen isotope exchange processes between methane, hydrogen and water are most likely responsible for calculated unrealistic methane formation temperatures.

We show that excess helium, slightly enriched in ³He, is present in the hydrothermal fluids emerging the seafloor of Paleohori Bay. When the isotopic ratio of the excess component is calculated a ³He/⁴He_excess of 3.6 · 10⁻⁶ is obtained: This indicates that the excess component consists of about one third of mantle helium and two thirds of radiogenic helium. We infer that the mantle-derived component has been strongly diluted by radiogenic helium during the ascent of the fluids to the surface.     

Contamination of Farmstead Wells by Pesticides, Volatile Organics, and Inorganic Chemicals in Kansas

Concern about the public health consequences of possible contamination of farmstead wells led to a random statewide survey in Kansas. Results of the analyses showed that 8 percent of tested wells had detectable amounts of pesticides, 2 percent had detectable amounts of volatile organic chemicals, and 37 percent had some inorganic contaminant exceeding the maximum contaminant level (MCL). Nitrate was the most common source of inorganic contamination, exceeding the MCL in 28 percent of the wells. Selenium levels exceeded the MCL in 9 percent of the wells. A multiple regression model for nitrate-N was developed. The factors included the age of the well, land use around the well, and the distance to the closest possible source of organic contamination.     

Spatial structure of hydrography and flow in a Chilean fjord,Estuario Reloncaví

Underway current velocity profiles were combined with temperature and salinity profiles at fixed stations to describe tidal and subtidal flow patterns in the middle of the northernmost Chilean fjord, Estuario Reloncaví. This is the first study involving current velocity measurements in this fjord. Reloncaví fjord is 55 km long, 2 km wide, and on average is 170 m deep. Measurements concentrated around a marked bend of the coastline, where an 8-km along-fjord transect was sampled during a semidiurnal tidal cycle in March 2002 and a 2-km cross-fjord transect was occupied, also during a semidiurnal cycle, in May 2004. The fjord hydrography showed a relatively thin (<5 m deep), continuously stratified, buoyant layer with stratification values >4 kg m⁻³ per meter of depth. Below this thin layer, the water was relatively homogeneous. Semidiurnal tidal currents had low amplitudes (<10 cm s⁻¹) that allowed the persistence of a surface front throughout the tidal cycle. The front oscillated with a period of ca. 2.5 h and showed excursions of 2 km. The front oscillations could have been produced by a lateral seiche that corresponds to the natural period of oscillation across the fjord. This front could have also caused large (2 h) phase lags in the semidiurnal tidal currents, from one end of the transect to the other, within the buoyant layer. Tidal phases were relatively uniform underneath this buoyant layer. Subtidal flows showed a 3-layer pattern consisting of a surface layer (8 m thick, of 5 cm s⁻¹ surface outflow), an intermediate layer (70 m thick, of 3 cm s⁻¹ net inflow), and a bottom layer (below 80 m depth, of 3 cm s⁻¹ net outflow). The surface outflow and, to a certain extent, the inflow layer were related to the buoyant water interacting with the ambient oceanic water. The inflowing layer and the bottom outflow were attributed to nonlinear effects associated with a tidal wave that reflects at the fjord's head. The weak subtidal currents followed the morphology of the bend and caused downwelling on the inside and upwelling on the outside part of the bend.     

Numerical Modeling of Al-Induced Radioactive Melting of Asteroids Considering Accretion

We have developed a computer code that solves numerically the 1D heat transport equation for small planetary bodies consisting of silicate material and heated by ²⁶Al. At the same time the bodies' accretion (with a size from 1 km—or smaller—to several hundred kilometers) is taken into account as radial growth. We find that the consideration of accretion is inevitable as it affects the thermal evolution resulting from heating by radioisotopes. Significant changes in thermal behavior are shown to occur in comparison with calculations that assume instantaneous accretion.     

Recovery from demographic shock in the New Länder of Germany

After the fall of the Berlin Wall in November 1989, East Germany experienced a demographic shock as the ensuing insecurity and disorientation of the population was mirrored in their demographic behaviour. The situation is examined with respect to marriage, fertility and mortality. There are now signs of recovery but most people in the New Länder are still traumatised by events: nuptiality and fertility are still extremely low, while mortality is rapidly moving towards West German levels. Future demographic development will very much depend on socio-economic development and the provision of both hard and soft infrastructure conducive to stable partnerships and families since the current 'framework' has proved to be particularly unfriendly to women and children.     

Regime shifts in the marine environment: the scientific basis and political context

Regime shifts in the marine environment have recently received much attention. To date, however, few large-scale meta-analyses have been carried out due to insufficient data coverage and integration between sustained observational datasets because of diverse methodologies used in data collection, recording and archival. Here we review the available data on regime shifts globally, followed by a review of current and planned policies with relevance to regime shifts.We then focus on the North and Baltic Seas, providing examples of existing efforts for data integration in the MarBEF Network of Excellence. Existing gaps in data coverage are identified, and the added value from meta-analyses of multiple datasets demonstrated using examples from the MarBEF integrated data project LargeNet. We discuss whether these efforts are addressing current policy needs and close with recommendations for future integrated data networks to increase our ability to understand, identify and predict recent and future regime shifts.     

More evidence that the Chicxulub impact predates the K/T mass extinction

Abstract Yaxcopoil‐1 (Yax‐1), drilled within the Chicxulub crater, was expected to yield the final proof that this impact occurred precisely 65 Myr ago and caused the mass extinction at the Cretaceous‐Tertiary (K/T) boundary. Instead, contrary evidence was discovered based on five independent proxies (sedimentologic, biostratigraphic, magnetostratigraphic, stable isotopic, and iridium) that revealed that the Chicxulub impact predates the K/T boundary by about 300,000 years and could not have caused the mass extinction. This is demonstrated by the presence of five bioturbated glauconite layers and planktic foraminiferal assemblages of the latest Maastrichtian zone CF1 and is corroborated by magnetostratigraphic chron 29r and characteristic late Maastrichtian stable isotope signals. These results were first presented in Keller et al. (2004). In this study, we present more detailed evidence of the presence of late Maastrichtian planktic foraminifera, sedimentologic, and mineralogic analyses that demonstrate that the Chicxulub impact breccia predates the K/T boundary and that the sediments between the breccia and the K/T boundary were deposited in a normal marine environment during the last 300,000 years of the Cretaceous.