Yaxcopoil-1 and the Chicxulub impact

CSDP core Yaxcopoil-1 was drilled to a depth of 1,511 m within the Chicxulub crater. An organic-rich marly limestone near the base of the hole (1,495 to 1,452 m) was deposited in an open marine shelf environment during the latest Cenomanian (uppermost Rotalipora cushmani zone). The overlying sequence of limestones, dolomites and anhydrites (1,495 to 894 m) indicates deposition in various carbonate platform environments (e.g., sabkhas, lagoons). A 100-m-thick suevite breccia (894–794 m) identifies the Chicxulub impact event. Above the suevite breccia is a dolomitic limestone with planktic foraminiferal assemblages indicative of Plummerita hantkeninoides zone CF1, which spans the last 300 ky of the Maastrichtian. An erosional surface 50 cm above the breccia/dolomite contact marks the K/T boundary and a hiatus. Limestones above this contact contain the first Tertiary planktic foraminifera indicative of an upper P. eugubina zone P1a(2) age. Another hiatus 7 cm upsection separates zone P1a(2) and hemipelagic limestones of planktic foraminiferal Zone P1c. Planktic foraminiferal assemblages of Zone Plc to P3b age are present from a depth of 794.04 up to 775 m. The Cretaceous carbonate sequence appears to be autochthonous, with a stratigraphic sequence comparable to late Cretaceous sediments known from outside the Chicxulub crater in northern and southern Yucatan, including the late Cenomanian organic-rich marly limestone. There is no evidence that these sediments represent crater infill due to megablocks sliding into the crater, such as major disruption of sediments, chaotic changes in lithology, overturned or deep dipping megablocks, major mechanical fragmentation, shock or thermal alteration, or ductile deformation. Breccia units that are intercalated in the carbonate platform sequence are intraformational in origin (e.g., dissolution of evaporites) and dykes are rare. Major disturbances of strata by the impact therefore appear to have been confined to within less than 60 km from the proposed impact center. Yaxcopoil-1 may be located outside the collapsed transient crater cavity, either on the upper end of an elevated and tilted horst of the terrace zone, or even outside the annular crater cavity. The Chicxulub site thus records a large impact that predates the K/T boundary impact and mass extinction.     

Ein metamorphes Erzgefüge

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Sex-specific biochemical and histological differences in gonads of sea urchins (Psammechinus miliaris) and their response to phenanthrene exposure

Female and male individuals of the same species often differ with respect to their susceptibility to toxicant stress. In the present study, sea urchins (Psammechinus miliaris) of both sexes were exposed to high (150 μg L?1) and environmentally relevant (5 μg L?1) concentrations of phenanthrene over 10 days. While food intake was significantly decreased following exposure to 150 μg L?1 phenanthrene, histological indices (lipofuscin accumulation, fibrosis, oocyte atresia), energetic status (energy charge, sum adenylates, AMP/ATP ratio) as well as ascorbate levels in the gonads showed either little or no effect upon phenanthrene exposure. However, most parameters (vitamin C, energy charge, sum adenylates, AMP/ATP ratio, ATP and ADP concentrations, lipofuscin content, fibrosis) significantly differed between male and female animals. This study illustrates the difficulties to identify toxic injury in reproductive tissue as it may be superimposed by gametogenesis and spawning of gametes.     

Geochemistry and tectonic setting of early Pan-African metamorphosed volcano–sedimentary sequence in southern Solaf zone, SW Sinai, Egypt

The south Solaf zone in SW Sinai comprises a metasedimentary sequence of metagraywackes intercalated with minor metavolcanic sheets, metasiltstones, meta-arenites, and calc–silicates. The metavolcanics (basalt–andesite) show high- to medium-K calc–alkaline nature. They exhibit distinctive Nb-Ta negative anomalies relative to enriched LILE, being highly similar to active continental margin lavas, but they also have the characteristics of rift-related magmatism. Magmas of similar composition are interpreted to be formed in an extensional environment and their source regions are zones of enriched subcontinental lithosphere. The metasediments are poor to moderate sorting, intercalated to the north with minor impure calcareous layers. Geochemical investigation shows that they are immature to semi-mature sediments derived from a source of mafic to felsic composition. These metasediments are chemically similar to the active continental margins and are comparable to the Feiran gneisses and metagraywackes that were deposited before 800 Ma in an extensional environment. The investigated rocks suffered LP-HT amphibolite facies metamorphism. The P-T estimates using various thermobarometric calibrations gave temperatures of 554–610 °C and pressures of 2.2–4.0 kbar.     

On the Stability of Colliding Flows: Radiative Shocks, ThinShells, and Supersonic Turbulence

High-resolution numerical simulations reveal the turbulent character of the interaction zone of colliding, radiative, hypersonic flows. As the shocked gas cools radiatively, the cooled matter is squeezed into thin, high density shells. The remaining kinetic energy causes supersonic turbulence within these shells, before it is finally dissipated by internal shocks and vortex cascades. The density is far from homogeneous. High density filaments and large voids coexist. Its mean value is significantly below the stationary value. Similarly, areas with supersonic velocities are found next to subsonic regions. The mean velocity is slightly below or above the sound speed. While quasi uniform flow motions are observed on smaller scales the large scale velocity distribution is isotropic. Part of the turbulent shell is occupied by relatively uniform flow-patches, resembling coherent structures. Astronomical implications of the turbulent interaction zone are multifarious. It probably drives the X-ray variability in colliding wind binaries as well as the surprising dust formation on orbital scales in some WR-binaries. It lets us understand the knotty appearance of wind-driven structures as planetary and WR-ring nebulae, symbiotics, supernova remnants, galactic supperbubbles. Also, WR and other radiatively driven, clumpy winds, advection dominated accretion, cooling flows and molecular cloud dynamics in star-forming regions may carry its stamp This revised version was published online in July 2006 with corrections to the Cover Date.     

Phytoliths infer locally dense and heterogeneous paleovegetation at FLK North and surrounding localities during upper Bed I time, Olduvai Gorge, Tanzania

The phytolith content of 10 samples collected immediately under Tuff IF (~ 1.785 Ma) at FLK N and other surrounding localities (~ 2 km²) provides a direct botanical evidence for woody vegetation in the eastern margin of Olduvai Gorge during uppermost Bed I time. Observation and counting of 143 phytolith types (5 to >150 μ) reveal dense but heterogeneous woody cover (~ 40–90%) of unidentified trees and/or shrubs and palms associated to the freshwater springs surrounding FLK N, and more open formation (presumably ~ 25–70% woody cover) in the southeast at localities VEK, HWK W and HWK E. The paleovegetation is best described as groundwater palm forest/woodland or bushland, which current analogue may be found near Lake Manyara in similar hydrogeological context (freshwater springs near saline/alkaline lake). Re-evaluating the published pollen data based on this analogy shows that 70% of the pollen signal at FLK N may be attributed to thicket-woodland, Acacia groundwater woodland, gallery and groundwater forests; while < 30% is attributed to swamp herbage and grasslands. Micro-botanical, isotopic, and taphonomical studies of faunal remains converge on the same conclusion that the area surrounding FLK N, which attracted both carnivores and hominins in the early Pleistocene, was densely wooded during uppermost Bed I time.     

Use of biliary PAH metabolites as a biomarker of pollution in fish from the Baltic Sea

During field campaigns of the BEEP project (Biological Effects of Environmental Pollution in Marine Coastal Ecosystems) in 2001-2002, metabolites of polycyclic aromatic hydrocarbons (PAHs) were determined in bile samples from three fish species, flounder (Platichthys flesus), perch (Perca fluviatilis) and eelpout (Zoarces viviparus), from four separate areas in the Baltic Sea. Two determination methods were applied: fixed wavelength fluorescence (FF) for pyrene-type metabolites and high-performance liquid chromatography with fluorescence detection (HPLC). There was a good correlation between the FF method and 1-OH pyrene determined by HPLC. Normalisation of the FF data for absorbance at 380 nm or bile protein concentrations greatly increased variance in one third and decreased it in two thirds of the cases and resulted in a loss of significant differences (protein normalisation) between the sampling stations, but normalisation of the HPLC data had little effect on the results. The biliary PAH metabolite content was usually higher in males than in females. In perch and eelpout the biliary PAH contents were at similar levels, whereas in flounder the levels were lower. The sampling areas arranged in decreasing order of biliary PAH contents were: Wismar Bay > Gulf of Gdansk > Lithuanian coast > Kvadofj?rden (reference area). It is concluded that FF with un-normalised data is a reliable and simple method for monitoring purposes and only one sex of a selected species should be used.     

A statistical procedure for the analysis of seismotectonically induced hydrochemical signals: A case study from the Eastern Carpathians, Romania

Changes in the stress field of an aquifer system induced by seismotectonic activity may change the mixing ratio of groundwaters with different compositions in a well, leading to hydrochemical signals which in principle could be related to discrete earthquake events. Due to the complexity of the interactions and the multitude of involved factors the identification of such relationships is a difficult task. In this study we present an empiric statistical approach suitable to analyse if there is an interdependency between changes in the chemical composition of monitoring wells and the regional seismotectonic activity of a considered area. To allow a rigorous comparison with hydrochemistry the regional earthquake time series was aggregated into an univariate time series. This was realized by expressing each earthquake in form of a parameter “e”, taking into consideration both energetic (magnitude of a seismic event) and spatial parameters (position of epi/hypocentrum relative to the monitoring site). The earthquake and the hydrochemical time-series were synchronised aggregating the e-parameters into “earthquake activity” functions E, which takes into account the time of sampling relative to the earthquakes which occurred in the considered area. For the definition of the aggregation functions a variety of different “e” parameters were considered. The set of earthquake functions E was grouped by means of factor analysis to select a limited number of significant and representative earthquake functions E to be used further on in the relation analysis with the multivariate hydrochemical data set. From the hydrochemical data a restricted number of hydrochemical factors were extracted. Factor scores allow to represent and analyse the variation of the hydrochemical factors as a function of time. Finally, regression analysis was used to detect those hydrochemical factors which significantly correlate with the aggregated earthquake functions.This methodological approach was tested with a hydrochemical data set collected from a deep well monitored for two years in the seismically active Vrancea region, Romania. Three of the hydrochemical factors were found to correlate significantly with the considered earthquake activities. A screening with different time combinations revealed that correlations are strongest when the cumulative seismicity over several weeks was considered. The case study also showed that the character of the interdependency depends sometimes on the geometrical distribution of the earthquake foci. By using aggregated earthquake information it was possible to detect interrelationships which couldn't have been identified by analysing only relations between single geochemical signals and single earthquake events. Further on, the approach allows to determine the influence of different seismotectonic patterns on the hydrochemical composition of the sampled well. The method is suitable to be used as a decision instrument in assessing if a monitoring site is suitable or not to be included in a monitoring net within a complex earthquake prediction strategy.     

Interactions between climate change and contaminants

There is now general consensus that climate change is a global threat and a challenge for the 21st century. More and more information is available demonstrating how increased temperature may affect aquatic ecosystems and living resources or how increased water levels may impact coastal zones and their management. Many ecosystems are also affected by human releases of contaminants, for example from land based sources or the atmosphere, which also may cause severe effects. So far these two important stresses on ecosystems have mainly been discussed independently. The present paper is intended to increase awareness among scientists, coastal zone managers and decision makers that climate change will affect contaminant exposure and toxic effects and that both forms of stress will impact aquatic ecosystems and biota. Based on examples from different ecosystems, we discuss risks anticipated from contaminants in a rapidly changing environment and the research required to understand and predict how on-going and future climate change may alter risks from chemical pollution.