基于探地雷达属性分析的典型岩溶不良地质识别方法

采用探地雷达进行岩溶隧道超前地质预报时,受现场探测环境、岩溶地质的复杂性以及解译技术制约,多解性问题一直未能得到很好解决。从依托工程中选取代表性的案例,分析总结隧道建设中常见的几种典型岩溶不良地质的属性特征,结果表明岩溶不良地质类型与探地雷达属性参数有很好相关性,其中:空腔型溶洞、干燥松散黏土夹碎石充填型溶洞和无水破碎带雷达反射波中心频率随时间衰减较慢,分布范围分别为90~105、85~100、70~110MHz;软塑状黏土充填型溶洞和富水破碎带雷达反射波中心频率随时间衰减较快,分布范围分别为60~80MHz和40~70MHz。研究属性特征定量表示方法,提出基于广义S变换及子波谱模拟的雷达波吸收衰减参数计算方法。实际数据分析结果表明:每种属性都能从某些角度反映岩溶不良地质体雷达反射波的特征,在综合多个特征参数后,可以较好地区分不同的岩溶不良地质类型,从而提高探地雷达目标识别精度。     

Photocatalytic Degradation of 17α‐Ethinylestradiol and Inactivation of Escherichia coli Using Ag‐Modified TiO2 Nanotube Arrays

Ag‐modified TiO₂ nanotube arrays (Ag/TiO₂ NAs) were prepared and employed as a photocatalyst for degradation of 17α‐ethinylestradiol (EE2) and inactivation of Escherichia coli. The as‐synthesized Ag/TiO₂ NAs were characterized by field‐emission scanning electron microscope (FESEM), X‐ray diffraction (XRD), and X‐ray photoelectron spectroscopy (XPS). It was found that metallic Ag nanoparticles were firmly deposited on the TiO₂ NAs with the pore diameter of 100 nm and the length of 550 nm. Photocatalytic degradation of EE2 and inactivation of E. coli were enhanced effectively in an analogical trend using Ag/TiO₂ NAs. In particular, Ag/TiO₂ NAs exhibited the antimicrobial activity even in the absence of light. The Ag acted as a disinfection agent as well as the dopant of the modified TiO₂ NAs photocatalysis by forming a Schottky barrier on the surface of TiO₂ NAs. Inorganic ions suppressed the rates of photocatalytic degradation of EE2, with HCO having a more pronounced effect than NO or SO. Humic acid (HA) was found to increase the rate of EE2 degradation.     

影响黄体酮促两种沼虾卵巢发育作用的一些因素

在11月给不切眼柄的日本沼虾注射黄体酮和滴加黄体酮，对其卵巢发育无明显的作用，切眼柄组比不切眼柄组有更多的虾达到较成熟的卵巢发育期，而切眼柄又注射或滴加黄体酮的组又比仅切眼柄的组有更多的虾达到较成熟的卵巢发育期，结果表明，眼柄内的激素可抑制黄体酮对卵巢发育的作用，10^-9M和10^-12M黄体酮可使体外培养的罗氏沼虾II和Ⅲ期卵巢的卵母细胞直径显著增大或非常显著地增大，而这2种浓度的黄体酮对I期和IV期的卵巢的卵母细胞的直径都无增大作用，10^-9M和10^-2M的黄体酮可使体外培养的罗氏沼虾Ⅱ期和Ⅲ期卵巢的总蛋白合成较对照组非常显著或显著地增加，而这2种浓度的黄体酮对I期和IV期的卵巢的总蛋白合成都无增加作用，结果表明黄体酮对卵母细胞的作用是有发育期的选择性的。     

Hydrogeochemistry of Water in Coal Measures during Grouting Treatment of Taoyuan Mine,China

Permian coal measure sandstone fissure water (referred to as “coal measure water,” that is, water in coal measures) is one of the important water sources for industrial and agricultural activities in mining areas. However, the regional high-pressure grouting, one of the most widely used floor control methods, may affect the coal measure water which is connected with limestone aquifer. This study used Taoyuan mine, a typical coal mine in Huaibei coalfield, as the research area to study the influencing mechanism of a grouting treatment on the hydrogeochemical evolution of coal measure water. The hydrogeochemical characteristics and water-rock interaction mechanism of the coal measure water before and during the treatment were evaluated using a Piper trigram, ion combination ratio, and hydrogen-oxygen stable isotope. The anions and cations in the coal measure water before and during the treatment had the same trends at SO₄²⁻ > HCO₃⁻ > Cl⁻ and Na⁺ > Ca²⁺ > Mg²⁺, respectively. Hydrochemical types of coal measure water before treatment were mainly SO₄·Cl-Ca·Mg, SO₄·Cl-Na, and HCO₃-Na, and during treatment they were mainly SO₄·Cl-Na and HCO₃-Na. The formation of chemical components of coal measure water before treatment was mainly caused by carbonate dissolution, sulfate dissolution, and pyrite oxidation. During the treatment, sulfate dissolution and pyrite oxidation were the main geochemical processes, and ion exchange was enhanced. Atmospheric precipitation was the source of all water samples, and all showed an obvious ¹⁸O drift.     

北部湾现代沉积速率

运用210Pb法测定了北部湾16根柱样的现代沉积速率,结果显示北部湾柱样210Pb剖面分布呈现三段式正常型、二段式正常型和倒置型3种类型,主要受沉积物组成、沉积物供应和水动力条件控制。北部湾东侧现代沉积速率相对较高的区域分布在钦州湾附近20 m水深以浅的地区和涠洲岛至海南岛西岸一线外水深20~50 m的内陆架。而在海南岛西岸水下岸坡带、琼州海峡西口附近和北部湾顶东北角这3处强潮区,现代沉积强度可能较弱或无现代细粒沉积。在北部湾中部50 m水深以深,由于物质供应匮乏,现代沉积速率也极低。北部湾东侧存在由环流驱动的沉积物"传送带",自南向北运动,其西边界在琼州海峡一线以南是在50 m等深线附近,以北是在109°E附近,冬季可能略向西拓展。     

The improvement of the one-dimensional Mellor-Yamada and K-profile parameterization turbulence schemes with the non-breaking surface wave-induced verticalmixing

Both the level 2.5 Mellor-Yamada turbulence closure scheme(MY) and K-profile parameterization(KPP) are popularly used by the ocean modeling community.The MY and the KPP are improved through including the non-breaking surface wave-induced vertical mixing(Bv),and the improved schemes were tested by using continuous data at the Papa ocean weather station(OWS) during 1961–1965.The numerical results showed that the Bv can make the temperature simulations fit much better with the continuous data from Papa Station.The two improved schemes overcame the shortcomings of predicting too shallow upper mixed layer depth and consequently overheated sea surface temperature during summertime,which are in fact common problems for all turbulence closure models.Statistical analysis showed that the Bv effectively reduced the mean absolute error and root mean square error of the upper layer temperature and increased the correlation coefficient between simulation and the observation.Furthermore,the performance of vertical mixing induced by shear instability and the Bv is also compared.Both the temperature structure and its seasonal cycle significantly improved by including the Bv,regardless of whether shear instability was included or not,especially for the KPP mixing scheme,which suggested that Bv played a dominant role in the upper ocean where the mean current was relatively weak,such as at Papa Station.These results may provide a clue to improve ocean circulation models.     

Latest Devonian to earliest Carboniferous conodont and carbon isotope stratigraphy of a shallow‐water sequence in South China

To improve regional and intercontinental correlation of the uppermost Devonian–lowermost Carboniferous, we examined the conodont faunas and carbon isotopic records of the Tangbagou Formation in the Qilinzhai section, southern Guizhou, South China. The Tangbagou Formation is a succession of mixed carbonate–siliciclastic rocks that accumulated on a shallow‐water platform under normal marine conditions. Seven conodont zones for shallow‐water biofacies in South China, the Cl. gilwernensis–Cl. unicornis Zone, the Po. spicatus Zone, the Si. homosimplex Zone, the Si. sinensis Zone, the Si. eurylobata Zone, the Ps. multistriatus Zone and the Po. co. porcatus Zone in ascending order, are recognized in the Tangbagou Formation. Although apparently limited in its value for global correlation, this conodont zonation is more applicable to shallow‐water biofacies in South China. Carbonate samples have yielded carbon isotopic signatures consistent with those recorded in Euroamerica sections, in particular showing four distinct characteristics: (1) the peak values of Hangenberg Carbon Isotope Excursion (HICE) during the latest Devonian, (2) a minor positive shift (P1) in the Si. homosimplex Zone during the early Tournaisian, (3) a second minor positive shift (P2) in the Si. sinensis Zone and (4) the middle Tournaisian Carbon Isotope Excursion (TICE) in the middle part of the Tangbagou Formation. The similarity in peak values (~5.5‰) and magnitude of TICE for the Qilinzhai and Belgian sections indicates that the Euro‐asia δ¹³C_carb trends may reflect the changes in global mean ocean δ¹³C_DIC, rather than having been overprinted by local carbon cycling. Integration of conodont biostratigraphy and δ¹³C stratigraphy provides a powerful tool for stratigraphic correlation. Copyright © 2015 John Wiley & Sons, Ltd.     

东爪哇盆地抱球虫灰岩遗迹化石及其沉积环境分析

抱球虫灰岩是印尼东爪哇盆地已发现油气藏的主要储层岩性之一,是该盆地重要的勘探目的层.该套发育于上新世的抱球虫灰岩,其储层性质优,为高孔中高渗型性储层.但对该类灰岩储层的形成条件、沉积环境因缺乏可靠的相标志而认识不一,从而影响了对该类储层的油气勘探.通过对该套灰岩发育的遗迹化石研究,共识别出Ophiomorpha,Ast...