Heat flow in the southern Chile forearc controlled by large-scale tectonic processes

Between 33°S and 47°S, the southern Chile forearc is affected by the subduction of the aseismic Juan Fernandez Ridge, several major oceanic fracture zones on the subducting Nazca Plate, the active Chile Ridge spreading centre, and the underthrusting Antarctic Plate. The heat flow through the forearc was estimated using the depth of the bottom simulating reflector obtained from a comprehensive database of reflection seismic profiles. On the upper and middle continental slope along the whole forearc, heat flow is about 30–60 mW m^–2, a range of values common for the continental basement and overlying slope sediments. The actively deforming accretionary wedge on the lower slope, however, in places shows heat flow reaching about 90 mW m^–2. This indicates that advecting pore fluids from deeper in the subduction zone may transport a substantial part of the heat there. The large size of the anomalies suggests that fluid advection and outflow at the seafloor is overall diffuse, rather than being restricted to individual fault structures or mud volcanoes and mud mounds. One large area with very high heat flow is associated with a major tectonic feature. Thus, above the subducting Chile Ridge at 46°S, values of up to 280 mW m^–2 indicate that the overriding South American Plate is effectively heated by subjacent zero-age oceanic plate material.     

Assessing global Sentinel-2 coverage dynamics and data availability for operational Earth observation (EO) applications using the EO-Compass

ABSTRACT

Sentinel-2 scenes are increasingly being used in operational Earth observation (EO) applications at regional, continental and global scales, in near-real time applications, and with multi-temporal approaches. On a broader scale, they are therefore one of the most important facilitators of the Digital Earth. However, the data quality and availability are not spatially and temporally homogeneous due to effects related to cloudiness, the position on the Earth or the acquisition plan. The spatio-temporal inhomogeneity of the underlying data may therefore affect any big remote sensing analysis and is important to consider. This study presents an assessment of the metadata for all accessible Sentinel-2 Level-1C scenes acquired in 2017, enabling the spatio-temporal coverage and availability to be quantified, including scene availability and cloudiness. Spatial exploratory analysis of the global, multi-temporal metadata also reveals that higher acquisition frequencies do not necessarily yield more cloud-free scenes and exposes metadata quality issues, e.g. systematically incorrect cloud cover estimation in high, non-vegetated altitudes. The continuously updated datasets and analysis results are accessible as a Web application called EO-Compass. It contributes to a better understanding and selection of Sentinel-2 scenes, and improves the planning and interpretation of remote sensing analyses.     

Determination of Antibiotic Residues in Manure,Soil, and Surface Waters

In the last years more and more often detections of antimicrobially active compounds (“antibiotics”) in surface waters have been reported. As a possible input pathway in most cases municipal sewage has been discussed. But as an input from the realm of agriculture is conceivable as well, in this study it should be investigated if an input can occur via the pathway application of liquid manure on fields with the subsequent mechanisms surface run‐off/interflow, leaching, and drift. For this purpose a series of surface waters, soils, and liquid manures from North Rhine‐Westphalia (Northwestern Germany) were sampled and analyzed for up to 29 compounds by HPLC‐MS/MS. In each of the surface waters antibiotics could be detected. The highest concentrations were found in samples from spring (300 ng/L of erythromycin). Some of the substances detected (e.g., tylosin), as well as characteristics in the landscape suggest an input from agriculture in some particular cases. In the investigation of different liquid manure samples by a fast immunoassay method sulfadimidine could be detected in the range of 1…2 mg/kg. Soil that had been fertilized with this liquid manure showed a content of sulfadimidine extractable by accelerated solvent extraction (ASE) of 15 μg/kg dry weight even 7 months after the application. This indicates the high stability of some antibiotics in manure and soil.     

Authigenic gypsum found in gas hydrate-associated sediments from Hydrate Ridge, the eastern North Pacific

Hydrate Ridge is located at the second accretion-ary ridge along the Cascadia margin of Oregon in the eastern North Pacific (fig. 1). The Bottom Simulating Reflector (BSR) underlies the entire Hydrate Ridge[1]. The Ocean Drilling Program (ODP) in 1992 at Site 892 and the TECFLUX99 and 2000 showed that the gas hydrate occurs just beneath the thin sediment- covered surface and at the horizon of around 64 meter below seafloor (mbsf) on Hydrate Ridge[25]. The col-lision of the Juan de …     

On the role of diffractions in velocity model building: a full-waveform inversion example

Studia Geophysica et Geodaetica - Imaging of small-scale heterogeneities is important for the geological exploration in complex environments. It requires a processing sequence tuned to...     

Bestimmung der Schweredifferenz Zwischen Potsdam und Bad Harzburg mit Askania-Gravimetern

Ohne Zusammenfassung Dr. rer. nat. C. Elstner, Geod. Inst. Potsdam und Dipl.-Ing. W. Torge, Geod. Inst. TH Hannover.     

Correlation between microbiological and chemical parameters of some hydrothermal springs in New Mexico, USA

Discharge areas of hydrothermal springs are known to be inhabited by diverse types of microorganisms including archaea, prokaryotes and eukaryotes. A total of 11 hydrothermal samples from the Rio Grande rift and the Valles caldera in New Mexico were analyzed to investigate the correlation between chemical and microbiological parameters of hydrothermal waters. The sampled fluids are categorized into three chemical groups: (I) steam-condensing acid sulfate waters, (II) deep geothermal and derivative waters and (III) thermal meteoric waters. Analyses of the microbial phospholipid fatty acids and denaturing gradient gel electrophoresis of DNA show that acid sulfate waters were populated by thermoacidophilic organisms and had high biomass content. Mineralized deep geothermal and derivative waters exhibited a high degree of microbial diversity, but had low biomass content. Thermal meteoric waters are low in total dissolved solids, and exhibit very low biomass content and microbial diversity. DNA sequences from several previously unknown microbial species were detected. The results of this study support the hypothesis that microbes can be used as tracers for specific types of subsurface environments.     

Effect of soil crusting on the emission and transport of wind-eroded sediment: field measurements on loamy sandy soil

Field data are reported for the horizontal and vertical flux of wind-eroded sediment on an agricultural field in northern Germany. Measurements were made during a windstorm that hit the region on 18 May 1999. The magnitude of both fluxes was significantly affected by the presence of a surface crust covering the test field. Measuring the physical crust strength at 45 locations with a torvane, the relationships between crust strength (τ) and the horizontal (F_h) and vertical (F_v) sediment fluxes were investigated. Both fluxes decreased as the surface crust became stronger. The decay behaved as an exponential function for both types of flux. The horizontal sediment flux over a crusted surface can be accurately predicted by completing Marticorena and Bergametti's [Journal of Geophysical Research 100 (1995) 16415] erosion model with a crust function. The vertical particle flux over crusted soil can be calculated by adding a similar function to Alfaro and Gomes's [Journal of Geophysical Research 106D (2001) 18075] dust production model. The study also suggests that the gradual bombardment of a surface crust by impacting particles does not immediately result in a decay of the crust's protective effect, provided that the crust has a minimum thickness. However, once the crust becomes perforated, its protective effect disappears very quickly, leading to much higher horizontal and vertical sediment fluxes than predicted for undamaged crusted soil.     

Thermochemistry of jarosite-alunite and natrojarosite-natroalunite solid solutions

The thermochemistry of jarosite-alunite and natrojarosite-natroalunite solid solutions was investigated. Members of these series were either coprecipitated or synthesized hydrothermally and were characterized by XRD, FTIR, electron microprobe analysis, ICP-MS, and thermal analysis. Partial alkali substitution and vacancies on the Fe/Al sites were observed in all cases, and the solids studied can be described by the general formula K_1-x-yNa_y(H₃O)_xFe_zAl_w(SO₄)₂(OH)_6-3(3-z-w)(H₂O)_3(3-z-w). A strong preferential incorporation of Fe over Al in the jarosite/alunite structure was observed. Heats of formation from the elements, ΔH°_f, were determined by high-temperature oxide melt solution calorimetry. The solid solutions deviate slightly from thermodynamic ideality by exhibiting positive enthalpies of mixing in the range 0 to +11 kJ/mol. The heats of formation of the end members of both solid solutions were derived. The values ΔH°_f = −3773.6 ± 9.4 kJ/mol, ΔH°_f = −4912.2 ± 24.2 kJ/mol, ΔH°_f = −3734.6 ± 9.7 kJ/mol and ΔH°_f = −4979.7 ± 7.5kJ/mol were found for K_0.85(H₃O)_0.15Fe_2.5(SO₄)₂(OH)_4.5(H₂O)_1.5, K_0.85(H₃O)_0.15Al_2.5(SO₄)₂(OH)_4.5(H₂O)_1.5, Na_0.7(H₃O)_0.3Fe_2.7(SO₄)₂(OH)_5.1(H₂O)_0.9, and Na_0.7(H₃O)_0.3Al_2.7(SO₄)₂(OH)_5.1(H₂O)_0.9 respectively. To our knowledge, this is the first experimentally-based report of ΔH°_f for such nonstoichiometric alunite and natroalunite samples. These thermodynamic data should prove helpful to study, under given conditions, the partitioning of Fe and Al between the solids and aqueous solution.