Very high-frequency and seasonal cave atmosphere PCO2 variability: Implications for stalagmite growth and oxygen isotope-based paleoclimate records

Cave air P_CO2 at two Irish sites varied dramatically on daily to seasonal timescales, potentially affecting the timing of calcite deposition and consequently climate proxy records derived from stalagmites collected at the same sites. Temperature-dependent biochemical processes in the soil control CO₂ production, resulting in high summer P_CO2 values and low winter values at both sites. Large Large-amplitude, high-frequency variations superimposed on this seasonal cycle reflect cave air circulation. Here we model stalagmite growth rates, which are controlled partly by CO₂ degassing rates from drip water, by considering both the seasonal and high-frequency cave air P_CO2 variations. Modeled hourly growth rates for stalagmite CC-Bil from Crag Cave in SW Ireland reach maxima in late December (0.063 μm h^− 1) and minima in late June/early July (0.033 μm h^− 1). For well-mixed ‘diffuse flow’ cave drips such as those that feed CC-Bil, high summer cave air P_CO2 depresses summer calcite deposition, while low winter P_CO2 promotes degassing and enhances deposition rates. In stalagmites fed by well-mixed drips lacking seasonal variations in δ¹⁸O, integrated annual stalagmite calcite δ¹⁸O is unaffected; however, seasonality in cave air P_CO2 may influence non-conservative geochemical climate proxies (e.g., δ¹³C, Sr/Ca). Stalagmites fed by ‘seasonal’ drips whose hydrochemical properties vary in response to seasonality may have higher growth rates in summer because soil air P_CO2 may increase relative to cave air P_CO2 due to higher soil temperatures. This in turn may bias stalagmite calcite δ¹⁸O records towards isotopically heavier summer drip water δ¹⁸O values, resulting in elevated calcite δ¹⁸O values compared to the ‘equilibrium’ values predicted by calcite–water isotope fractionation equations. Interpretations of stalagmite-based paleoclimate proxies should therefore consider the consequences of cave air P_CO2 variability and the resulting intra-annual variability in calcite deposition rates.     

Functioning of intertidal flats inferred from temporal and spatial dynamics of O<Subscript>2</Subscript>, H<Subscript>2</Subscript>S and pH in their surface sediment

In this article, we describe the dynamics of pH, O₂ and H₂S in the top 5–10 cm of an intertidal flat consisting of permeable sand. These dynamics were measured at the low water line and higher up the flat and during several seasons. Together with pore water nutrient data, the dynamics confirm that two types of transport act as driving forces for the cycling of elements (Billerbeck et al. 2006b): Fast surface dynamics of pore water chemistry occur only during inundation. Thus, they must be driven by hydraulics (tidal and wave action) and are highly dependent on weather conditions. This was demonstrated clearly by quick variation in oxygen penetration depth: Seeps are active at low tide only, indicating that the pore water flow in them is driven by a pressure head developing at low tide. The seeps are fed by slow transport of pore water over long distances in the deeper sediment. In the seeps, high concentrations of degradation products such as nutrients and sulphide were found, showing them to be the outlets of deep-seated degradation processes. The degradation products appear toxic for bioturbating/bioirrigating organisms, as a consequence of which, these were absent in the wider seep areas. These two mechanisms driving advection determine oxygen dynamics in these flats, whereas bioirrigation plays a minor role. The deep circulation causes a characteristic distribution of strongly reduced pore water near the low water line and rather more oxidised sediments in the centre of the flats. The two combined transport phenomena determine the fluxes of solutes and gases from the sediment to the surface water and in this way create specific niches for various types of microorganisms.     

Dust emission by off-road driving: Experiments on 17 arid soil types, Nevada, USA

Field experiments were conducted in Nellis Dunes Recreational Area (Clark County, Nevada, USA) to investigate emission of dust produced by off-road driving. Experiments were carried out with three types of vehicles: 4-wheelers (quads), dirt bikes (motorcycles) and dune buggies, on 17 soil types characteristic for a desert environment. Tests were done at various driving speeds, and emissions were measured for a large number of grain size fractions. This paper reports the results for two size fractions of emissions: PM10 (particles < 10 μm) and PM60 (particles < 60 μm). The latter was considered in this study to be sufficiently representative of the total suspendable fraction (TSP). Off-road driving was found to be a significant source of dust. However, the amounts varied greatly with the type of soil and the characteristics of the top layer. Models predicting emission of dust by off-road driving should thus consider a number of soil parameters and not just one key parameter. Vehicle type and driving speed are additional parameters that affect emission. In general, 4-wheelers produce more dust than dune buggies, and dune buggies, more than dirt bikes. Higher speeds also result in higher emissions. Dust emitted by off-road driving is less coarse than the parent sediment on the road surface. Off-road driving thus results in a progressive coarsening of the top layer. Exceptions to this are silty surfaces with no, or almost no, vegetation. For such surfaces no substantial differences were observed between the grain size distribution of road dust and emitted dust. Typical emission values for off-road driving on dry desert soils are: for sandy areas, 30–40 g km^− 1 (PM10) and 150–250 g km^− 1 (TSP); for silty areas, 100–200 g km^− 1 (PM10) and 600–2000 g km^− 1 (TSP); for drainages, 30–40 g km^− 1 (PM10) and 100–400 g km^− 1 (TSP); and for mixed terrain, 60–100 g km^− 1 (PM10) and 300–800 g km^− 1 (TSP). These values are for the types of vehicles tested in this study and do not refer to cars or trucks, which produce significantly more dust.     

Style and evolution of salt pillows and related structures in the northern part of the Northeast German Basin

The northern part of the Northeast German Basin contains a large number of Late Permian (Zechstein) salt pillows, whereas diapiric structures are almost completely absent. This lack of diapirs facilitated the study of early stages of salt movement in the basin. Salt pillows and related structures were investigated in terms of distribution, geometry and time of initiation of salt flow within the regional geological context. The primary Zechstein thickness in the study area was reconstructed to gain more insight into the relationship between the geometry of the salt layer and the style of the salt-related structures. In this study, no clear spatial relationship between the salt structures and basement faults has been found and the location of the salt structures in this area appears to be highly independent of the underlying structural grain. The overburden is affected by minor faulting. We propose that buckling of the overburden due to regional compression significantly contributed to the initiation of the Late Jurassic to Early Cretaceous salt structures in the basin. Reverse faulting of the Gardelegen and Haldensleben Faults is related to inversion tectonics and exerted a compression on the basin fill. During the deformation, the Late Permian salt layer acted as an efficient detachment and led to a marked decoupling of the Mesozoic overburden from the underlying pre-Zechstein rocks.     

Long-term variability of air temperature and precipitation conditions in the Polish Carpathians

Mountain regions are sensitive to climate changes, which make them good indicators of climate change. The aim of this study is to investigate the spatial and temporal variability of air temperature and precipitation in the Polish Carpathians. This study consists of climatological analyses for the historical period 1851-2010 and future projections for 2021-2100. The results confirm that there has been significant warming of the area and that this warming has been particularly pronounced over the last few decades and will continue in the oncoming years. Climate change is most evident in the foothills; however, these are the highest summits which have experienced the most intensive increases in temperature during the recent period. Precipitation does not demonstrate any substantial trend and has high year-to-year variability. The distribution of the annual temperature contour lines modelled for selected periods provides evidence of the upward shift of vertical climate zones in the Polish Carpathians, which reach approximately 350 meters, on average, what indicates further ecological consequences as ecosystems expand or become extinct and when there are changes in the hydrological cycle.     

Statistical landslide susceptibility assessment in a dynamic environment: A case study for Lanzhou City,Gansu Province,NW China

This study presents a statistical landslide susceptibility assessment (LSA) in a dynamic environment. The study area is located in the eastern part of Lanzhou, NW China. The Lanzhou area has exhibited rapid urbanization rates over the past decade associated with greening, continuous land use change, and geomorphic reshaping activities. To consider the dynamics of the environment in the LSA, multitemporal data for landslide inventories and the corresponding causal factors were collected. The weights of evidence (WofE) method was used to perform the LSA. Three time stamps, i.e., 2000, 2012, and 2016, were selected to assess the state of landslide susceptibility over time. The results show a clear evolution of the landslide susceptibility patterns that was mainly governed by anthropogenic activities directed toward generating safer building grounds for civil infrastructure. The low and very low susceptibility areas increased by approximately 10% between 2000 and 2016. At the same time, areas of medium, high and very high susceptibility zones decreased proportionally. Based on the results, an approach to design the statistical LSA under dynamic conditions is proposed, the issues and limitations of this approach are also discussed. The study shows that under dynamic conditions, the requirements for data quantity and quality increase significantly. A dynamic environment requires greater effort to estimate the causal relations between the landslides and controlling factors as well as for model validation.     

Designation of marine protected areas in Belgium: A legal and ecological success?

In Belgium a long process (1999–2005) led to the designation of several marine protected areas (MPAs). In order to analyse the designation process, the ‘policy arrangement approach’ was used as an analytical tool. Attention was given to four dimensions (actors and coalitions, arguments, rules and resources). Particular attention was paid to the switch from an authoritative to a more deliberated policy style in reaction to conflicts with stakeholders. This switch in policy style contributed to a successful legal designation, but does not guarantee the best protection of marine biodiversity. This case study linked science (setting ecological goals) to policy (analysis of a policy process) and led to some more general conclusions on the designation of MPAs and the role of participation in this process.