The solar system abundances of phosphorus and titanium and the nebular volatility of phosphorus

Abstract— The bulk chemical composition of Orgueil and 25 other carbonaceous chondrites was determined by x‐ray fluorescence analysis. The sample sizes of the analyzed meteorites were in all cases 120 mg. The abundances of P and Ti in Orgueil and Ivuna were precisely determined by the standard addition method. The new P CI abundance is 926 ± 65 ppm. Excluding the low P of Ivuna and one Orgueil sample with unusual chemistry gives a CI P content of 930 ± 23 ppm. A CI abundance of 926 ppm corresponds to a P/Si wt ratio of 8.66 times 10^?3 (atomic ratio 7.85 times 10^?3). For Ti a CI content of 458 ± 18 ppm and a Ti/Si wtratio of 4.28 times 10^?3 (atomic ratio 2.51 times 10^?3) were found. A Si content of 10.69% was obtained for average CI. The new P CI abundance is 20 to 30% below earlier estimates, while the Ti CI abundance is in agreement with earlier determinations. From the results of the analyses of bulk carbonaceous chondrites it is concluded: (1) Refractory element/Mg ratios increase from CI through CM and C3O to C3V, but ratios among Al, Ca and Ti are constant, except for low Ca/Al ratios in the reduced subgroup of C3V. (2) The Si/Mg ratios are constant in all groups of carbonaceous chondrites. (3) There is a volatility related depletion of Cr and Fe, but the Cr/Fe ratios are constant. (4) The sequence of volatility related depletions of the moderately volatile elements P, Au, As, Mn, and Zn follows condensation temperatures (except for As), if in condensation calculations non‐ideal solid solution in the host phase is considered.     

A nonlinear analysis of the moon's physical libration in longitude

The Euler equations for the forced physical librations of the Moon have already been solved by using a digital computer to perform the semi-literal mathematical manipulations. Very near resonance, the computer solution for the physical libration in longitude is complemented by the solution of the appropriate Duffing equation with a dissipation term. Because of its apparent proximity to a resonant frequency, the term whose argument is 2 - twice the mean angular distance of the Moon's perigee from the ascending node of its orbit - is especially important. Its phase, which soon should be measurable, is related to the Moon's anelasticity. The term's frequency, in units of the sidereal month, increases as the semi-major axis of the Moon's orbit about the Earth increases. Using the Moon's mechanical ellipticity of Koziel and the rate of increase of the semi-major axis of MacDonald, it is estimated that the 2 term will cross the resonant frequency in 130 million years and, if the rate of energy dissipation is sufficiently low, a transient libration will be induced.     

Announcement Internatioal Society for Diatom Research and Nederlands-Vlaamse Kring van Diatomisten

Announcement Internatioal Society for Diatom Research and Nederlands-Vlaamse Kring van Diatomisten     

Enhancement of ionizing radiation during a solar flare

Measurements of electron concentrations in the ionosphere, between 100 and 250 km altitude, were used to compute the increase in solar ionizing radiation during two flares on 21 and 23 May 1967. Since the altitude of maximum absorption of the solar energy (approximately unit optical depth) depends on the wavelength of the radiation, it is possible to estimate separately the energy enhancement in different portions of the spectrum. An ionizing energy flux increase of nearly 5 erg cm^–2 sec^–1 was observed on 21 May, while on the 23rd, the increase was over 7 erg cm^–2 sec^–1. In both flares, most of the absolute increase occurred in the 20–205 Å region of the spectrum, although the relative increase was much larger at the shorter wavelengths.     

Comment on the Brans-Dicke-Bianchi type-III vacuum solution

We wish to point out that the Brans-Dicke-Bianchi type-III vacuum solution recently given by Tiwari and Singh (1984) is not new. Moreover, the solution given has no correct Einstein limit, contrary to what is claimed by these authors. The Ellis-MacCallum vacuum solution in the Einstein case can be obtained from the Brans-Dicke solution first given by Lorenz-Petzold (1984a).     

Nebular drag and capture into spin-orbit resonance

The majority of planetary satellites whose spin period is known are observed to be in synchronous spin-orbit resonance. The commonly accepted explanation for this observation is that it is due to the effects of tidal evolution. However, cosmogonic theories state that the formation of planetary and satellite systems occurs within a primordial solar nebula and circumplanetary nebulae, respectively. In this paper the influence of nebular drag on the capture into spin-orbit resonance is analysed. The results show that the torques generated are important for these resonances in a wide range of cases. Using the protojovian nebula model by Lunine and Stevenson (1982), conservative estimates of the despinning time scales for the Galilean satellites are computed. In comparison the despinning time scale from tidal effects are several orders of magnitude larger.on leave of absence from Departamento de Matemática, Faculdade de Engenharia de Guaratinguetá, UNESP, CP 205, 12500-000, Guaratinguetá, SP, Brazil     

Palaeosecular variation and the current loop model of the geomagnetic field

Summary. The geomagnetic palaeosecular variation has been studied in terms of two current loops which change their positions and orientations with time. The results broadly agree with the observed data. Comparison with the existing models is made.     

Late Glacial and Holocene history of former Salziger See, Central Germany, and its climatic and environmental implications

An 8.40 m long sediment sequence from the Salziger See basin, Central Germany, was investigated by a multi-disciplinary approach including chronological, sedimentological, geo- and biogeochemical methods. Radiocarbon dating, conducted on ten samples of aquatic and terrestrial fossil remains, and the occurrence of the Laacher See Tephra (LST) reveal that the sediment sequence comprises the Late Glacial and Holocene lake history since ca. 13,800 cal. year BP. This onset of lacustrine sedimentation is almost 7,000 years earlier as assumed so far. The geo- and biogeochemical data indicate distinct variations throughout the Late Glacial, which can be correlated with cold and warm periods, such as the Oldest Dryas, the Bølling, the Allerød, and the Younger Dryas. During most of the Holocene, minor variations in the geo- and biogeochemical data and a high carbonate content due to the formation and precipitation of autochthonous carbonate in the lake indicate relatively stable lacustrine conditions. A slight change in the sedimentary conditions between 6,700 and 4,000 cal. year BP, with lower deposition of carbonate and fine material, can be traced back to enhanced subrosion in the basin. Increased deposition of coarser sediments and a high accumulation of heavy metals document intensive human activity in the region during the past ca. 1,000 years.This revised version was published online in March 2005 with corrections to Table 1.     

The occurrence of potentially hazardous trace elements in five Highveld coals, South Africa

Permian coals of the southern hemisphere are generally considered to contain lower concentrations of sulfides, halogens, and trace elements when compared to northern hemisphere Carboniferous coals. Few studies have considered the trace element content in South African coals, and little or no work has been published for Highveld coals. Of the nineteen coal fields in South Africa, the Highveld coal field is one of the nine currently producing, and is second largest in terms of production. Five run of mine samples and a high ash middlings product from the Number 4 Lower seam were analyzed, totaling six sample sets. Fourteen trace elements (As, Cd, Co, Cr, Cu, Hg, Mn, Mo, Ni, Pb, Sb, Se, V, and Zn) were selected for this study based on the global perception that these elements may be hazardous to human health and/or the environment when they are released during coal utilization. Several sample preparation techniques were tested using certified reference materials (SARMs 18, 19 and 20) to determine the most repeatable technique for these coals. The samples were analyzed by ICP-AES and CVAA (Hg only). Microwave digestion proved to be generally unreliable despite the utilization of several different methods. A slurry direct injection method into the ICP-AES provided good correlations with the reference material, but requires further development to enhance the confidence level in this relatively unexplored technique. Samples prepared based on three ASTM standards for the determination of trace elements in coal provided repeatable results in most instances, and were the preparation methods utilized for the Highveld coals.The trace element values determined for the Highveld coals are generally in good agreement with values available in literature for South African coals, with the exception of Hg, Mn and Cr. Hg values reported here are lower, Cr and Mn higher. Results generally agree well with analyses on the same samples conducted by the United States Geological Survey. When considering the global ranges for trace elements, the Highveld range values are within Swaine's range boundaries with the exception of Cr. Compared to the cited global average values for the fourteen trace elements determined, the values obtained for the Highveld coals generally fall below or well below these average values, with the exception of Cr and Mn. Concentrations of Cd and Cu are lower compared to global average values, and As, Mo, Pb, Se, Sb, and Zn can be considered low to very low. Arsenic is ten times lower compared to typical USA values. Concentrations of Co and Ni are similar to global averages, with V and Hg being very slightly higher. The middlings samples reported higher concentrations of most elements, related to the higher ash content of these samples. Of interest, the chalcophile elements determined are all depleted in the Highveld coals compared to global averages, and the siderophile elements are enriched or comparable to global averages.Risk-based health studies in the USA on coals with similar or higher Hg and significantly higher As contents have not reported negative health effects, and therefore it could be assumed that the mobilization of these trace elements from the five Highveld coals are unlikely to cause human health problems. Work is ongoing to determine the modes of occurrence of these HAPs and to address the partitioning behaviors and speciation states of these elements during coal utilization.