Spatial distribution and bonding forms of heavy metals in sediments along the middle course of the River Elbe (km 287ċ390)

Sediments of eight groyne fields along the middle course of the River Elbe (river km 287?390) were geochemically studied. The 78 sediment samples were analysed for pH and grain size distribution. The grain size fraction < 2 μm was used for mineralogical and chemical analysis: semiquantitative clay mineral analysis; total element content (Al, Ca, Fe, K, Mn, Cd, Cr, Cu, Ni, Pb, Zn), total inorganic and organic C, and bonding form fractionation with a six‐step sequential chemical extraction. The latter was performed on selected samples (n = 32). The sediments along the Elbe's course are still contaminated with heavy metals far above the local geogenic background level. An enrichment factor of more than 15 was calculated for zinc. Cr and Ni are the elements with the lowest enrichment. The bonding form analysis of selected heavy metals shows a dominance of relatively immobile bonding forms, e. g. the moderately reducible and the residual fraction, which implies a relative low mobility potential. Only Zn poses a higher potential threat to the environment, since it has a higher percentage of the first three extracted phases: adsorbed, carbonate, and easily reducible fraction.     

Field Signatures of the SE-Asian Mega-Tsunami along the West Coast of Thailand Compared to Holocene Paleo-Tsunami from the Atlantic Region

The Andaman-Sumatra Tsunami of Dec. 26, 2004, was by far the largest tsunami catastrophe in human history. An earthquake of 9 to 9.3 on the Richter scale, the extension of waves over more than 5000 km of ocean and run-ups up to 35 m are its key features. These characteristics suggest significant changes in coastal morphology and high sediment transport rates. A field survey along the west coast of Thailand (Phuket Island, Khao Lak region including some Similan Islands, Nang Pha mangrove areas and Phi Phi Don Islands) seven to nine weeks after the tsunami, however, discovered only small changes in coastal morphology and a limited amount of dislocated sediments, restricted to the lower meters of the tsunami waves. This is in striking contrast to many paleo-tsunami's events of the Atlantic region. Explanations for this discrepancy are sought in: a. Mechanics of the earthquake. A rather slow shock impulse on the water masses over the very long earthquake zone, b. Shallow water in the earthquake zone, and c. Bathymetry of the foreshore zone at the impacted sites. Shallow water west of Thailand has diminished wave energy significantly. The differences in geomorphological and sedimentological signatures of this tsunami compared with many paleo-tsunami worldwide makes it unsuitable to be used as a model for old and future tsunami imprints by an event of this extreme energy and extension.     

Element signatures of subduction-zone fluids. An experimental study of the element partitioning (Dfluid/rock) of natural partly altered igneous rocks from the ODP drilling site 1,256

The trace element signatures of fluids were investigated by leaching experiments on natural samples of partly altered mafic igneous rocks recovered from the drilling site 1,256 of ODP Leg 206 on the Cocos plate (Central America). Experiments with ultrapure water were performed at 400 °C/0.4 GPa and 500 °C/0.7 GPa. Both fluids and residual solids were examined to obtain the partition coefficients (D^fluid/rock) of various trace elements. Element partition coefficients (D^fluid/rock) obtained at 500 °C/0.7 GPa are significantly lower compared to results obtained at 400 °C/0.4 GPa, which is in contrast to observations at higher pressures (2.2–6 GPa) and temperatures between 700 and 1,400 °C (Kessel et al. in Earth Planet Sci Lett 237: 873–892, 2005a; Spandler et al. in Chem Geol 239: 228–249, 2007). This finding may indicate a considerable pressure effect on the leaching processes and strongly divergent fluid–rock interactions in the upper part of a subduction zone at 0.4–0.7 GPa compared to deeper subduction areas with higher pressures. Furthermore, this may be interpreted as one of the earliest fractionation processes during the subduction of crustal material.     

Mesozoic (Late Jurassic) palynomorphs and charcoal from a sandstone pebble from Quaternary glacial deposits of the North Sea

The palynological contents as well as macroscopic charcoal fragments from a calcareous sandstone pebble from Quaternary glacial deposits of the North Sea (80 km SW of the Dogger Bank) are described. The taxonomic composition of the palynoflora points to a Late Jurassic (or Late Jurassic/Early Cretaceous) age of the sandstone. The charcoal is interpreted as direct evidence of palaeo‐wildfire occurring during this period in the source area of the sediments of this particular sandstone. This finding, together with already published data on Mesozoic deposits, allows to conclude that wildfires were obviously widespread during this period in the area of the modern day North Sea and adjacent areas. Copyright © 2012 John Wiley & Sons, Ltd.     

A high‐resolution relative time scale for the Viséan Stage (Carboniferous) of the Kulm Basin (Rhenish Mountains,Germany)

The Viséan (Carboniferous) sedimentary succession of the basinal Kulm facies (Rhenish Mountains) was investigated in detail in order to achieve a high‐resolution stratigraphic subdivision and correlation. Additionally, the ranges of fossil index taxa (ammonoids), fossil marker beds, volcaniclastic horizons and sedimentary features (e.g. colour changes) were integrated in the correlation. As a result, a comprehensive database was compiled, which contains 190 stratigraphic events of the Viséan interval of this area. Several sections are almost completely composed of shales, which are regarded to represent a slow but constant basinal background sedimentation of the Kulm facies. The thickness of lithological homogeneous sections thus indicates an approximately linear record of time and the average thicknesses of biozones and positions of stratigraphic events can easily be calculated from the compiled database. The result is an approximately time‐linear biostratigraphic scale for the Viséan Stage of the Kulm Basin. Given a numerical length of the Viséan Stage of ca. 19 Ma, 190 stratigraphic events give a mean resolution of 100 000 years. This is unique in Palaeozoic stratigraphy. Copyright © 2008 John Wiley & Sons, Ltd.     

Height dependence of diurnal variations of wind velocity and water temperature near the air-sea interface of the tropical Atlantic

From measurements during the Atlantic Trade Wind Experiment (ATEX) 1969, amplitudes and phases of the diurnal harmonic water-temperature variation between the sea surface and 50-m depth and of the semi-diurnal wind variation between 1 and 8 m were obtained. If the vertical diffusion of heat in the ocean is thought to be constant, a coefficient of K= 320 cm² s^–1 in the equation of diffusion fits best the observed data in the mixed layer. However, the measurements point to a decrease of K with depth.The height variation of the semi-diurnal zonal wind wave is caused by the influence of eddy viscosity. Our data are well fitted by results of the equation of diffusion, using the assumption of Lettau (1974) that the transfer coefficient of vertical transport of momentum is not only a function of height but also depends on time because of the semi-diurnal variation of surface stress.     

Tectonics of the Laptev Sea – Moma `Rift' Region: Investigation with Seismologic Broadband Data

Based on teleseismic broadband data, mainly recorded from stationsof the Incorporated Research Institute for Seismology (IRIS) and theGräfenberg (GRF) array in Germany, the focal mechanism and thefocal depth of the largest earthquakes in northeastern Siberia in thetime interval 1976–1996 were determined. For 9 events the relativeanelastic attenuation of the shear wave with respect to the compressionalwave along the travel paths could be calculated. Using the slip vectorsfrom the best constrained focal mechanisms and additional slip vectorsfrom Jemsek et al. (1986) and Parfenov et al. (1988), we obtained the North American–Eurasian pole of rotation west of the Cherskii mountainsat 67.1^° N, 132.3^° E.The investigation shows that the extension of the Arctic Mid-Ocean Ridgeinto the continental shelf acts as a continental graben structure.Actually, the crustal extension is concentrated on the eastern LaptevSea area and the seismicity of the western part of the Laptev Sea canbe explained by the assumption of a separate microplate. In the continentsoutheast of the Laptev Sea a series of northwest trending depressions,known as the Moma `Rift', are observed. Although in this region elevatedheat flow, recent volcanism and a low crustal thickness were found (i.e.Duchkov and Sokolova, 1985; Devyatkin, 1985), there is only a poorcorrelation between the seismicity and the rift valleys. So the Momastructures seem to be related to an aborted rift structure.     

SUJETS A TRAITER POUR L'ASSEMBLÉE DE 1960

ABSTRACT

The present paper reports on some practical experiences gained in computing unit hydrographs (UH) according to the “classical” linear theory. The sizes of the drainage basins varied from 50 to 800 km² of hilly country.     

An interpretation of initial stress and strain methods,and numerical stability

This paper explores similarities and differences between initial stress and initial strain methods of analyses. The author takes the position that both methods, although perhaps conceptually different, are actually numerically the same. A simple approach for providing closed-form stability criteria for explicit and implicit time-marching procedures is described. For the case of associated, non-hardening viscoplasticity the approach provides criteria which are identical to those of Cormeau for explicit schemes. An implicit time-marching scheme which avoids the compliance matrix inversions at the constitutive level is also presented. Like many other implicit methods, this implicit time-marching scheme is unconditionally stable for θ≥½. The connection between initial strain plasticity and an explicit viscoplastic time-marching scheme is also addressed.