Exploring the impact of diagenesis on (isotope) geochemical and microstructural alteration features in biogenic aragonite

For the Quaternary and Neogene, aragonitic biogenic and abiogenic carbonates are frequently exploited as archives of their environment. Conversely, pre‐Neogene aragonite is often diagenetically altered and calcite archives are studied instead. Nevertheless, the exact sequence of diagenetic processes and products is difficult to disclose from naturally altered material. Here, experiments were performed to understand biogenic aragonite alteration processes and products. Shell subsamples of the bivalve Arctica islandica were exposed to hydrothermal alteration. Thermal boundary conditions were set at 100°C, 175°C and 200°C. These comparably high temperatures were chosen to shorten experimental durations. Subsamples were exposed to different ¹⁸O‐depleted fluids for durations between two and twenty weeks. Alteration was documented using X‐ray diffraction, cathodoluminescence, fluorescence and scanning electron microscopy, as well as conventional and clumped isotope analyses. Experiments performed at 100°C show redistribution and darkening of organic matter, but lack evidence for diagenetic alteration, except in Δ₄₇ which show the effects of annealing processes. At 175°C, valves undergo significant aragonite to calcite transformation and neomorphism. The δ¹⁸O signature supports transformation via dissolution and reprecipitation, but isotopic exchange is limited by fluid migration through the subsamples. Individual growth increments in these subsamples exhibit bright orange luminescence. At 200°C, valves are fully transformed to calcite and exhibit purple‐blue luminescence with orange bands. The δ¹⁸O and Δ₄₇ signatures reveal exchange with the aqueous fluid, whereas δ¹³C remains unaltered in all experiments, indicating a carbonate‐buffered system. Clumped isotope temperatures in high‐temperature experiments show compositions in broad agreement with the measured temperature. Experimentally induced alteration patterns are comparable with individual features present in Pleistocene shells. This study represents a significant step towards sequential analysis of diagenetic features in biogenic aragonites and sheds light on reaction times and threshold limits. The limitations of a study restricted to a single test organism are acknowledged and call for refined follow‐up experiments.     

Redistribution of HFSE elements during rutile replacement by titanite

Titanite growth at the expense of rutile during retrograde hydration of eclogite into amphibolite is a common phenomenon. We investigated an amphibolite sample from the Tromsø eclogite facies terrain in Northern Norway to gain insight into the trace element distribution between rutile and titanite during incomplete resorption of the rutile by titanite. Patchy compositional zoning of Al, Ti, and F in titanite relates to the presence of a fluid with variable Ti/Al and/or F during its growth. Laser ablation ICP–MS and electron microprobe data for high field strength elements (HFSE: Nb, Zr, Ta, and Hf) of rutile resorbed by titanite indicate a pronounced enrichment of these elements in the rim of a large single rutile crystal (~8 mm) and a systematic decrease towards uniform HFSE contents in the large core. HFSE contents of smaller rutile grains (~0.5 mm) and rutile inclusions (<100 μm) in the titanite overgrowth are similar or higher than in the rims of large rutile crystals. Element profiles from the rim inward demonstrate that HFSE enrichment in rutile is controlled by diffusion. HFSE ratios in diffusion-altered rutile show systematic variations compared with the uniform core composition of the large rutile. Modelling of Zr and Nb diffusion in rutile indicates that diffusion coefficients in rutile in fluid-dominated natural systems must be considerably higher than those determined experimentally at 1 bar in dry systems. Variations of HFSE contents in the newly formed titanite show no systematic spatial distribution. HFSE ratios in titanite and the rims of rutile are different, indicating different solid/fluid distribution coefficients in these minerals. Element fractionation by diffusion into the relict rutile and during fluid-mediated growth of new titanite could substantially change the HFSE budget of these minerals and could affect their use for geochemical tracing and other applications, such as Zr-based geothermobarometry.     

The tropospheric distribution of formaldehyde during TROPOZ II

A series of 149 measurements of the HCHO mixing ratio were made between 0 and 10 km altitude and 70° N to 60° S latitude during TROPOZ II. The data show a vertical decrease of the HCHO mixing ratio with altitude at all latitudes and a broad latitudinal maximum in the HCHO mixing ratio between 30° N and 30° S at all altitudes. The measured mixing ratios of HCHO are considerably higher than those expected from CH₄ oxidation alone, but agree broadly with the average latitude by altitude distribution of HCHO derived by a 2D model including emissions of C₁–C₇ hydrocarbons. A number of the regional scale deviations of the measured HCHO distribution from the average modelled one can be explained in terms of the local wind field.     

The general non-LRS-BDT-Bianchi type-V radiation solution

We present the most general triaxial BDT-Bianchi type-V radiation solution. The solution is the simplest generalization of the GRT solution first given by Ruban.     

Comment on the inhomogeneous Bianchi type-VI0 solution

The inhomogeneous Bianchi type-VI₀ perfect fluid solution given recently by Roy and Narain (1985) is shown to be identical with the solution first given by Tomita (1978).     

Magnetic reconnection in plasmas

A review of the present status of the theory of magnetic reconnection is given. In strongly collisional plasmas reconnection proceeds via resistive current sheets, i.e. quasi-stationary macroscopic Sweet-Parker sheets at intermediate values of the magnetic Reynolds numberR _m , or mirco-current sheets in MHD turbulence, which develops at highR _m . In hot, dilute plasmas the reconnection dynamics is dominated by nondissipative effects, mainly the Hall term and electron inertia. Reconnection rates are found to depend only on the ion mass, being independent of the electron inertia and the residual dissipation coefficients. Small-scale whistler turbulence is readily excited giving rise to an anomalous electron viscosity. Hence reconnection may be much more rapid than predicted by conventional resistive theory.     

Comment on the BDT-Bianchi type-VI0 stiff matter solution

We wish to point out that the Brans-Dicke-Bianchi type-VI₀ stiff matter solution recently given by Ram and Singh is not the most general solution of the corresponding field equations. Moreover, this solution has no vacuum limit and the general relativistic limit is obtained only after making an asymptotic expansion. In this paper we rediscuss the entire problem in a different way. In the limit =const., , we obtain both the stiff matter and the vacuum relativistic limit first given by Ellis and MacCallum (1969) in analytic form.     

The structure of the lower crust at the Argentine continental margin, South Atlantic at 44°S

It is well established that the Argentine passive margin is of the rifted volcanic margin type. This classification is based primarily on the presence of a buried volcanic wedge beneath the continental slope, manifested by seismic data as a seaward dipping reflector sequence (SDRS). Here, we investigate the deep structure of the Argentine volcanic margin at 44°S over 200 km from the shelf to the deep oceanic Argentine Basin. We use wide-angle reflection/refraction seismic data to perform a joint travel time inversion for refracted and reflected travel times. The resulting P-wave velocity-depth model confirms the typical volcanic margin structure. An underplated body is resolved as distinctive high seismic velocity (v_p up to 7.5 km/s) feature in the lower crust in the prolongation of a seaward dipping reflector sequence. A remarkable result is that a second, isolated body of high seismic velocity (v_p up to 7.3 km/s) exists landward of the first high-velocity feature. The centres of both bodies are 60 km apart. The high-velocity lower-crustal bodies likely were emplaced during transient magmatic–volcanic events accompanying the late rifting and initial drifting stages. The lateral variability of the lower crust may be an expression of a multiple rifting process in the sense that the South Atlantic rift evolved by instantaneous breakup of longer continental margin segments. These segments are confined by transfer zones that acted as rift propagation barriers. A lower-crustal reflector was detected at 3 to 5 km above the modern Moho and probably represents the lower boundary of stretched continental crust. With this finding we suggest that the continent–ocean boundary is situated 70 km more seaward than in previous interpretations.     

THE ADVERSE IMPACT OF HUMAN ACTIVITIES ON FLOOD CONTROL IN THE HUAIHE BASIN

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Magmatic evolution of the Easter microplate-Crough Seamount region (South East Pacific)

The Easter microplate-Crough Seamount region located between 25° S–116° W and 25° S–122° W consists of a chain of seamounts forming isolated volcanoes and elongated (100–200 km in length) en echelon volcanic ridges oriented obliquely NE (N 065°), to the present day general spreading direction (N 100°) of the Pacific-Nazca plates. The extension of this seamount chain into the southwestern edge of the Easter microplate near 26°30 S–115° W was surveyed and sampled. The southern boundary including the Orongo fracture zone and other shallow ridges (< 2000 m high) bounding the Southwest Rift of the microplate consists of fault scarps where pillow lava, dolerite, and metabasalts are exposed. The degree of rock alternation inferred from palagonitization of glassy margins suggests that the volcanic ridges are as old as the shallow ridges bounding the Southwest Rift of the microplate. The volcanics found on the various structures west of the microplate consist of depleted (K/Ti < 0.1), transitional (K/Ti = 0.11–0.25) and enriched (K/Ti > 0.25) MORBs which are similar in composition to other more recent basalts from the Southwest and East Rifts spreading axes of the Easter microplate. Incompatible element ratios normalized to chondrite values [(Ce/Yb)_N = 1–2.5}, {(La/Sm)_N = 0.4–1.2} and {(Zr/Y)_N = 0.7–2.5} of the basalts are also similar to present day volcanism found in the Easter microplate. The volcanics from the Easter microplate-Crough region are unrelated to other known South Pacific intraplate magmatism (i.e. Society, Pitcairn, and Salas y Gomez Islands). Instead their range in incompatible element ratios is comparable to the submarine basalts from the recently investigated Ahu and Umu volcanic field (Easter hotspot) (Scientific Party SO80, 1993) and centered at about 80 km west of Easter Island. The oblique ridges and their associated seamounts are likely to represent ancient leaky transform faults created during the initial stage of the Easter microplate formation ( 5 Ma). It appears that volcanic activity on seamounts overlying the oblique volcanic ridges has continued during their westward drift from the microplate as shown by the presence of relatively fresh lava observed on one of these structures, namely the first Oblique Volcanic Ridge near 25° S–118° W at about 160 km west of the Easter microplate West Rift. Based on a reconstruction of the Easter microplate, it is suggested that the Crough seamount (< 800 m depth) was formed by earlier (7–10 Ma) hotspot magmatic activity which also created Easter Island.