全文获取类型
收费全文 | 231篇 |
免费 | 18篇 |
国内免费 | 3篇 |
专业分类
测绘学 | 4篇 |
大气科学 | 25篇 |
地球物理 | 47篇 |
地质学 | 127篇 |
海洋学 | 11篇 |
天文学 | 24篇 |
自然地理 | 14篇 |
出版年
2023年 | 3篇 |
2022年 | 2篇 |
2021年 | 4篇 |
2020年 | 7篇 |
2019年 | 13篇 |
2018年 | 6篇 |
2017年 | 3篇 |
2016年 | 14篇 |
2015年 | 19篇 |
2014年 | 11篇 |
2013年 | 12篇 |
2012年 | 10篇 |
2011年 | 13篇 |
2010年 | 18篇 |
2009年 | 18篇 |
2008年 | 17篇 |
2007年 | 7篇 |
2006年 | 11篇 |
2005年 | 7篇 |
2004年 | 8篇 |
2003年 | 7篇 |
2002年 | 6篇 |
2001年 | 4篇 |
2000年 | 3篇 |
1999年 | 4篇 |
1998年 | 3篇 |
1997年 | 2篇 |
1995年 | 2篇 |
1994年 | 1篇 |
1993年 | 2篇 |
1992年 | 1篇 |
1991年 | 2篇 |
1990年 | 1篇 |
1987年 | 1篇 |
1986年 | 2篇 |
1985年 | 1篇 |
1983年 | 2篇 |
1979年 | 1篇 |
1978年 | 2篇 |
1974年 | 1篇 |
1969年 | 1篇 |
排序方式: 共有252条查询结果,搜索用时 44 毫秒
51.
The highly aromatic structure of the macromolecular organic matter (OM) of the Murchison and Orgueil meteorites was recently shown to contain free organic radicals which are concentrated in micro-regions in contrast with terrestrial samples which always show an homogeneous distribution of radicals. An additional signature is revealed, in the present study, by the evolution of the radical concentration with temperature. Whereas in terrestrial samples, this concentration is independent of temperature (Curie magnetism), a significant increase is observed above 150 K in the two meteorites. Based on the electronic structure of organic radicals, calculated by Extended Hückel and Density Functional methods, this behavior was assigned to the occurrence of diradicaloid moieties hosted by aromatic structures of 10 to 15 rings and having a quinoidal structure. They represent 40 and 25% of the total radicals in Orgueil and Murchison, respectively. The search for the cosmochemical interpretation of this unique observation should open a new field of experimental investigations. 相似文献
52.
Olgeir Sigmarsson Didier Laporte Marion Carpentier Bertrand Devouard Jean-Luc Devidal Joan Marti 《Contributions to Mineralogy and Petrology》2013,165(3):601-622
Phonolite and trachyte are the felsic magmas of the alkaline magma suites, which characterize the Canary Islands. The October 2011 submarine eruption off El Hierro, the westernmost island, nevertheless, produced a small volume of rhyolitic magma. The rhyolite occurred as highly vesicular, white coloured pumices enveloped in and mingled with darker coloured basanitic pumice. The basanitic pumice is relatively crystal poor with a few euhedral olivines (mostly Fo77–79), clinopyroxenes and Fe-rich spinels, whereas very rare olivine of same composition is found together with equally rare Fe-sulphide and FeTi-rich oxides in the rhyolite. The Fe–Mg exchange equilibrium in the oxides permits to calculate an equilibrium temperature of 970–890 °C for the rhyolite, in agreement with quartz-melt equilibrium at ca. 930 °C. A striking mineralogical feature of the rhyolite is the presence of rounded to contorted grains of milky quartz, which are xenocrysts incorporated and partly dissolved into the magma. Analyses of residual volatile concentrations in the glasses show that the rhyolite melt was highly degassed, whereas the basanitic glass still has important halogen concentrations. Trace element patterns of the mafic glasses and their elevated incompatible element concentrations are typical of the western Canary Island basanites. In contrast, the trace element composition of the rhyolite shows surprisingly low concentrations for all elements except the most incompatible ones (e.g. Rb, Ba, K and Th). All other measured LILE, HFSE and REE have significantly lower concentration than the basanitic counterpart that can be explained by fractionation of accessory phases (1 % apatite, 1 % sphene and 0.1 % zircon). Surprisingly, low U concentration is presumably related to elevated oxygen fugacity in the rhyolite, causing U to be in a hexavalent state, and fluxing of F-rich gas leading to volatilization of UF6, known to emanate at low temperature. The results suggest that a gas-rich basanitic melt remobilized a small volume of stagnant rhyolitic melt formed by incorporation of approximately 10 % quartz-rich sediment into a late differentiate of trachytic composition. Sediments at the interface of an old oceanic crust adjacent to a continental shield and younger volcanic island are likely to act as magma traps were sediment assimilation may alter the mantle-derived magma composition. Quartz assimilation thus explains the production of rhyolite magma in a volcanic island characterized by an alkaline magma series from primitive basanites to trachytes. 相似文献
53.
Vinícius dos SANTOS Peter MARSHALL FLEMING Luís HENRIQUE MANCINI Stela DALVA SANTOS COTA Graziele Beatriz de LIMA Rafaela RODRIGUES GOMES Roberto Eduardo KIRCHHEIM Ricardo SANCHéZ-MURILLO Didier GASTMANS 《大气科学进展》2022,39(10):1693-1708
Precipitation isotope ratios (O and H) record the history of water phase transitions and fractionation processes during moisture transport and rainfall formation. Here, we evaluated the isotopic composition of precipitation over the central-southeastern region of Brazil at different timescales. Monthly isotopic compositions were associated with classical effects (rainfall amount, seasonality, and continentality), demonstrating the importance of vapor recirculation processes and different regional atmospheric systems (South American Convergence Zone-SACZ and Cold Fronts-CF). While moisture recycling and regional atmospheric processes may also be observed on a daily timescale, classical effects such as the amount effect were not strongly correlated (δ18O-precipitation rate r ≤ –0.37). Daily variability revealed specific climatic features, such as δ18O depleted values (~ –6‰ to –8‰) during the wet season were associated with strong convective activity and large moisture availability. Daily isotopic analysis revealed the role of different moisture sources and transport effects. Isotope ratios combined with d-excess explain how atmospheric recirculation processes interact with convective activity during rainfall formation processes. Our findings provide a new understanding of rainfall sampling timescales and highlight the importance of water isotopes to decipher key hydrometeorological processes in a complex spatial and temporal context in central-southeastern Brazil. 相似文献
54.
Johanna Lomax Markus Fuchs Pierre Antoine Denis‐Didier Rousseau France Lagroix Christine Hatt Samuel N. Taylor Jessica L. Till Maxime Debret Olivier Moine Diana Jordanova 《Boreas: An International Journal of Quaternary Research》2019,48(1):179-194
The Harletz loess‐palaeosol sequence is located in northwestern Bulgaria and represents an important link between well‐studied loess sequences in eastern Romania and further sites to the west of the Carpathians (e.g. Serbia and Hungary). The aim of this study was to establish a chronostratigraphy of the deposits, using various methods of luminescence dating, together with basic stratigraphical field observations as well as magnetic properties. Luminescence dating was carried out using the quartz fine grain fraction and a SAR protocol, and the feldspar coarse grain fraction, applying the MET‐pIRIR protocol. Due to underestimation of the quartz fine grain fraction in the lower parts of the sequence, the resulting chronology is mainly based on the feldspar ages, which are derived from the stimulation temperature at 150 °C. A comparison with nearby sequences from Serbia, Hungary and Romania, and interpretations obtained through the stratigraphical and sedimentological signature of the sequence, supports the established chronology. Our data suggest that the prominent palaeosol (soil complex) in the upper quarter of the sequence was formed during MIS 5. It would follow that large parts of the Last Glacial loess overlying this palaeosol were probably eroded, and that the thick loess accumulation underlying this soil complex can be allocated to the penultimate glacial (MIS 6). A prominent MIS 6 tephra, which has been reported from other sequences in the area, is also present at Harletz. 相似文献
55.
56.
Amine Ait-Ouahmed Didier Josselin Fen Zhou 《International journal of geographical information science》2018,32(2):367-398
Car-sharing system with electric cars is a very convenient service for urban transportation: it allows users to pick up a vehicle at a station and rent it during a short time. To manage this kind of system in the best way, it is necessary to solve the critical problem of vehicle stock imbalance across the stations. Several decision levels must be considered to balance the car distribution by taking into account the quality of service and the system operation cost. To this end, a linear programming model is proposed to formalize the problem in a mathematical framework, which allows the computation of optimal vehicle distribution strategies. To make our solution time efficient and usable for solving large problems, a greedy algorithm and a tabu search algorithm are proposed. These two algorithms are applied to the Auto Bleue network in Nice and its surrounding (France) using extensive simulations. Besides, an integrated mapping method is provided within the Geographical Information System QGIS to estimate flows and their locations. Numerical results demonstrate that the tabu search algorithm is able to find near-optimal solutions and good compromises between client satisfaction, number of staff agents and vehicles used, and computing time. 相似文献
57.
Mayeul Mathias Fen Zhou Juan-Manuel Torres-Moreno Didier Josselin Marie-Sylvie Poli Andréa Carneiro Linhares 《International journal of geographical information science》2017,31(3):591-616
This article describes a method to provide adapted visit tours in art museums according to the preferences expressed by the visitor and exhibits prestige. It is based on a dual approach with, on the one hand an automatic textual analysis of the official information available online (labels of exhibits) that allows to rank the exhibit attractiveness for a standard museum visitor. On the other hand, individual preferences are also taken into account to adapt the visit according to the personal cultural awareness of the visitor. We use operations research to solve a routing optimization problem, aiming at finding a visit tour with time constraints and maximization of the visitor satisfaction. Depending on the instance size and the problem scale, an integer linear programming (ILP) model and a greedy algorithm are proposed to recommend personalized visit tours and applied on two museums: ‘Musée de l’Orangerie’ in Paris and ‘National Gallery’ in London. The obtained results show that it is possible to recommend a good tour to visitors of an art museum by taking into account the common prestige of the exhibits and the individual interests, joining automatic text summarization and routing optimization in a limited geographical space. 相似文献
58.
The temperature-dependent ultraviolet absorption cross-sections of CF3-CHFCI (HCFC-124) have been measured between 170 and 230 nm for temperatures ranging from 295 to 210 K, with uncertainties between 2 and 4%. These results are compared with other available sets of determinations. Temperature effects are discussed and the photodissociation coefficients, presented with their temperature dependence, are calculated. Implication of the temperature dependences on the stratospheric chemistry is also discussed. Parametrical formulae are proposed to compute absorption crosssection values for wavelengths and temperatures useful in modelling calculations. 相似文献
59.
60.