A luminescence‐based chronology for the Harletz loess sequence,Bulgaria

The Harletz loess‐palaeosol sequence is located in northwestern Bulgaria and represents an important link between well‐studied loess sequences in eastern Romania and further sites to the west of the Carpathians (e.g. Serbia and Hungary). The aim of this study was to establish a chronostratigraphy of the deposits, using various methods of luminescence dating, together with basic stratigraphical field observations as well as magnetic properties. Luminescence dating was carried out using the quartz fine grain fraction and a SAR protocol, and the feldspar coarse grain fraction, applying the MET‐pIRIR protocol. Due to underestimation of the quartz fine grain fraction in the lower parts of the sequence, the resulting chronology is mainly based on the feldspar ages, which are derived from the stimulation temperature at 150 °C. A comparison with nearby sequences from Serbia, Hungary and Romania, and interpretations obtained through the stratigraphical and sedimentological signature of the sequence, supports the established chronology. Our data suggest that the prominent palaeosol (soil complex) in the upper quarter of the sequence was formed during MIS 5. It would follow that large parts of the Last Glacial loess overlying this palaeosol were probably eroded, and that the thick loess accumulation underlying this soil complex can be allocated to the penultimate glacial (MIS 6). A prominent MIS 6 tephra, which has been reported from other sequences in the area, is also present at Harletz.     

Relocation optimization of electric cars in one-way car-sharing systems: modeling,exact solving and heuristics algorithms

Car-sharing system with electric cars is a very convenient service for urban transportation: it allows users to pick up a vehicle at a station and rent it during a short time. To manage this kind of system in the best way, it is necessary to solve the critical problem of vehicle stock imbalance across the stations. Several decision levels must be considered to balance the car distribution by taking into account the quality of service and the system operation cost. To this end, a linear programming model is proposed to formalize the problem in a mathematical framework, which allows the computation of optimal vehicle distribution strategies. To make our solution time efficient and usable for solving large problems, a greedy algorithm and a tabu search algorithm are proposed. These two algorithms are applied to the Auto Bleue network in Nice and its surrounding (France) using extensive simulations. Besides, an integrated mapping method is provided within the Geographical Information System QGIS to estimate flows and their locations. Numerical results demonstrate that the tabu search algorithm is able to find near-optimal solutions and good compromises between client satisfaction, number of staff agents and vehicles used, and computing time.     

Personalized sightseeing tours: a model for visits in art museums

This article describes a method to provide adapted visit tours in art museums according to the preferences expressed by the visitor and exhibits prestige. It is based on a dual approach with, on the one hand an automatic textual analysis of the official information available online (labels of exhibits) that allows to rank the exhibit attractiveness for a standard museum visitor. On the other hand, individual preferences are also taken into account to adapt the visit according to the personal cultural awareness of the visitor. We use operations research to solve a routing optimization problem, aiming at finding a visit tour with time constraints and maximization of the visitor satisfaction. Depending on the instance size and the problem scale, an integer linear programming (ILP) model and a greedy algorithm are proposed to recommend personalized visit tours and applied on two museums: ‘Musée de l’Orangerie’ in Paris and ‘National Gallery’ in London. The obtained results show that it is possible to recommend a good tour to visitors of an art museum by taking into account the common prestige of the exhibits and the individual interests, joining automatic text summarization and routing optimization in a limited geographical space.     

Temperature-dependence of ultraviolet absorption cross-sections of alternative chlorofluoroethanes: 2. The 2-chloro-1,1,1,2-tetrafluoro ethane -HCFC-124

The temperature-dependent ultraviolet absorption cross-sections of CF₃-CHFCI (HCFC-124) have been measured between 170 and 230 nm for temperatures ranging from 295 to 210 K, with uncertainties between 2 and 4%. These results are compared with other available sets of determinations. Temperature effects are discussed and the photodissociation coefficients, presented with their temperature dependence, are calculated. Implication of the temperature dependences on the stratospheric chemistry is also discussed. Parametrical formulae are proposed to compute absorption crosssection values for wavelengths and temperatures useful in modelling calculations.     

Sedimentary record of redox-sensitive elements (U, Mn, Mo) in a transitory anoxic basin (the Thau lagoon, France)

In order to further document the relation between redox conditions and the sedimentary record of Mn, U and Mo in a transitory anoxic water basin, their distribution has been studied along two profiles in the Thau lagoon (France). Sediments and pore-water have been sampled at two contrasting sites located, respectively, in the shellfish-farming area and in the centre of the lagoon. In the shellfish-farming area, the particulate organic carbon (POC) data indicate a more rapid organic matter mineralisation compared to the centre of the lagoon. This results in a sharper redox gradient characterized by the appearance of H₂S in pore-water a few millimetres below the sediment–water interface. In the centre of the lagoon, H₂S appears at a depth of 35 cm.In both cores, sedimentary Mn is relatively depleted through out the whole sedimentary column and varies with the proportion of clay minerals. After an initial release into solution at the sediment–water interface in relation to Mn-oxide reductive dissolution, authigenic U is immobilized when sulphides appear. Despite the occurrence of anoxic conditions at the sediment–water interface at the site influenced by shellfish farming, the burial of U is reduced by bioturbation, which raises reducing sediments to the surface. In the centre of the lagoon, Mo profiles reflect continuous diffusion into pore water and immobilization at 15 cm probably in anoxic microenvironments. At shellfish farms, dissolved Mo undergoes removal with sulphides but contrary to U, sedimentary Mo does not appear to be strongly affected by bioturbation. The profile indicates an increase in the frequency of anoxia crises during the second half of the 20th century.