Late Cenozoic transpression in southwestern Mongolia and the Gobi Altai-Tien Shan connection

The Gobi Altai region of southwestern Mongolia is a natural laboratory for studying processes of active, transpressional, intracontinental mountain building at different stages of development. The region is structurally dominated by several major E—W left-lateral strike-slip fault systems. The North Gobi Altai fault system is a seismically active, right-stepping, left-lateral, strike-slip fault system that can be traced along the surface for over 350 km. The eastern two-thirds of the fault system ruptured during a major earthquake (M = 8.3) in 1957, whereas degraded fault scarps cutting alluvial deposits along the western third of the system indicate that this segment did not rupture during the 1957 event but has been active during the Quaternary. The highest mountains in the Gobi Altai are restraining bend uplifts along the length of the fault system. Detailed transects across two of the restraining bends indicate that they have asymmetric flower structure cross-sectional geometries, with thrust faults rooting into oblique-slip and strike-slip master faults. Continued NE-directed convergence across the fault system, coupled with left-lateral strike-slip displacements, will lead to growth and coalescence of the restraining bends into a continuous sublinear range, possibly obscuring the original strike-slip fault system; this may be a common mountain building process.

The largely unknown Gobi-Tien Shan fault system is a major left-lateral strike-slip fault system (1200 km + long) that links the southern ranges of the Gobi Altai with the Barkol Tagh and Bogda Shan of the easternmost Tien Shan in China. Active scarps cutting alluvial deposits are visible on satellite imagery along much of its central section, indicating Quaternary activity. The total displacement is unknown, but small parallel splays have apparent offsets of 20 + km, suggesting that the main fault zone has experienced significantly more displacement. Field investigations conducted at two locations in southwestern Mongolia indicate that late Cenozoic transpressional uplift is still active along the fault system. The spatial relationship between topography and active faults in the Barkol Tagh and Bogda Shan strongly suggests that these ranges are large, coalescing, restraining bends that have accommodated the fault's left-lateral motion by thrusting, oblique-slip displacement and uplift. Thus, from a Mongolian perspective, the easternmost Tien Shan formed where it is because it lies at the western termination zone of the Gobi-Tien Shan fault system. The Gobi-Tien Shan fault system is one of the longest fault systems in central Asia and, together with the North Gobi Altai and other, smaller, subparallel fault systems, is accommodating the eastward translation of south Mongolia relative to the Hangay Dome and Siberia. These displacements are interpreted to be due to eastward viscous flow of uppermost mantle material in the topographically low, E–W trending corridor between the northern edge of the Tibetan Plateau and the Hangay Dome, presumably in response to the Indo-Eurasian collision 2500 km to the south.     

Influence of small-scale gold mining and toxic element concentrations in Bonsa river,Ghana: a potential risk to water quality and public health

A preliminary assessment of toxic element pollution caused by artisanal and small-scale gold mining in the Bonsa river of Ghana as well as the influence of TOC and SO₄ ^2? concentration on these traces in the sediment has been determined. With the exception of mercury (Hg), manganese (Mn), and arsenic (As), the concentration of aluminum (Al) in filtered river water exceeded the WHO guideline limit of 0.1 mg L^?1 in drinking water. Analyses of toxic element in sediment using Canadian Sediment Quality Criteria, contamination factor, geoaccumulation index, and enrichment factor indicate that river sediment is severely contaminated with Hg confirming the negative impact of the amalgamation technique in gold beneficiation in Ghana. The level of Hg in the surface water exceeded reported values from some rivers in Africa, Asia, and South America. The ranking order of the mean element concentration in both matrices followed the conservative order of traces found in the Earth crust except copper, which was below the detection limit of 0.01 mg kg^?1. A Pearson correlation matrix of the toxic element and geology of the river bedrock indicates that the Hg contamination is of anthropogenic origin whilst As, Mn, and Al are the result of natural enrichment. The partitioning of elements in the sediment compartments is independent of TOC and SO₄ ^2? concentration. Health-risk assessment based on average daily dose, hazard quotient, and cancer risk indicates that Hg is a health risk to the human population. In conclusion, the study has shown that there is a likely anthropic affection of the river and that this situation has worsened since earlier studies. In order to sustain aquatic life and to prevent future human health hazard, an immediate mercury remediation in the river is recommended.     

The stability and reproducibility of Tris buffers in synthetic seawater

The equimolal Tris buffer (0.04 mol/kg-H₂O Tris + 0.04 mol/kg-H₂O Tris-HCl) prepared in synthetic seawater of salinity 35 has been shown to be stable when sealed in a borosilicate glass bottle with a greased ground-glass stopper (drift rate ≤ 0.0005 in pH per year). The error in pH of such buffers resulting from uncertainties in the preparation of such buffers is typically less than 0.002 in pH (relative to the results of DelValls and Dickson, 1998 [DelValls, T.A., Dickson, A.G., 1998. The pH of buffers based on 2-amino-2-hydroxymethyl-1,3-propanediol (‘tris’) in synthetic sea water. Deep-Sea Research I, 45, 1541–1554]).     

Fate and transport of volatile organic compounds in glacial till and groundwater at an industrial site in Northern Ireland

Volatile organic compound (VOC) contamination of subsurface geological material and groundwater was discovered on the Nortel Monkstown industrial site, Belfast, Northern Ireland. The objectives of this study were to (1) investigate the characteristics of the geological material and its influences on contaminated groundwater flow across the site using borehole logs and hydrological evaluations, and (2) identify the contaminants and examine their distribution in the subsurface geological material and groundwater using chemical analysis. This report focuses on the eastern car park (ECP) which was a former storage area associated with trichloroethene (TCE) degreasing operations. This is where the greatest amount of volatile organic compounds (VOCs), particularly TCE, were detected. The study site is on a complex deposit of clayey glacial till with discontinuous coarser grained lenses, mainly silts, sands and gravel, which occur at 0.45–7.82 m below ground level (bgl). The lenses overall form an elongated formation that acts as a small unconfined shallow aquifer. There is a continuous low permeable stiff clayey till layer beneath the lenses that performs as an aquitard to the groundwater. Highest concentrations of VOCs, mainly TCE, in the geological material and groundwater are in these coarser lenses at ∼4.5–7 m bgl. Highest TCE measurements at 390,000 μg L⁻¹ for groundwater and at 39,000 μg kg⁻¹ at 5.7 m for geological material were in borehole GA19 in the coarse lens zone. It is assumed that TCE gained entrance to the subsurface near this borehole where the clayey till was thin to absent above coarse lenses which provided little retardation to the vertical migration of this dense non-aqueous phase liquid (DNAPL) into the groundwater. However, TCE is present in low concentrations in the geological material overlying the coarse lens zone. Additionally, VOCs appear to be associated with poorly drained layers and in peat <3.0 m bgl in the ECP. Some indication of natural attenuation as VOCs degradation products vinyl chloride (VC) and dichloromethane (DCM) also occur on the site.     

Hydrodynamic constraints and storm wave characteristics on a sub‐horizontal shore platform

Few studies of wave processes on shore platforms have addressed the hydrodynamic thresholds that control wave transformation and energy dissipation, especially under storm conditions. We present results of a field experiment conducted during a storm on a sub‐horizontal shore platform on the east coast of Auckland, New Zealand. Small (<0.5 m) locally generated waves typically occur at the field site, whereas during the experiment the offshore wave height reached 2.3 m. Our results illustrate the important control that platform morphology has on wave characteristics. At the seaward edge of the platform a scarp abruptly descends beneath low tide level. Wave height immediately seaward of the platform was controlled by the incident conditions, but near the cliff toe wave height on the platform was independent of incident conditions. Results show that a depth threshold at the seaward platform edge > 2.5 times the gravity wave height (0.05–0.33 Hz) is necessary for waves to propagate onto the platform without breaking. On the platform surface the wave height is a direct function of water depth, with limiting maximum wave height to water depth ratios of 0.55 and 0.78 at the centre of the platform and cliff toe, respectively. A relative ‘platform edge submergence’ (water depth/water height ratio) threshold of 1.1 is identified, below which infragravity (<0.05 Hz) wave energy dominates the platform energy spectra, and above which gravity waves are dominant. Infragravity wave height transformation across the platform is governed by the relative platform edge submergence. Finally, the paper describes the first observations of wave setup on a shore platform. During the peak of the storm, wave setup on the platform at low tide (0.21 m) is consistent with measurements from planar sandy beaches, but at higher tidal stages the ratio between incident wave height and maximum setup was lower than expected. Copyright © 2014 John Wiley & Sons, Ltd.     

Intercalibration of Bruevich’s method to determine the total alkalinity in seawater

In 2000, the Carbon Dioxide in the Ocean working group of the North Pacific Marine Science Organization (PICES) performed an international experiment on the intercalibration of the measurements of the total alkalinity in seawater using certified reference materials (CRM). Taking part in this experiment, Russian specialists presented the method by Bruevich. The results of the intercalibration showed that the alkalinity values obtained by Bruevich’s method using modern burettes, an Na₂CO₃ reactant of high purity as a standard to ascertain the acid titre, and corrections for the acid density and for the weights of the acid and seawater samples in vacuum are in agreement with the standard within ±1 μ M/kg.     

The effect of spontaneous gas expansion and mobilization on the aqueous-phase concentrations above a dense non-aqueous phase liquid pool

The spontaneous expansion and mobilization of discontinuous gas above dense non-aqueous-phase liquid (DNAPL) pools can affect the aqueous-phase concentrations of the DNAPL constituents above the pool. The results of an intermediate-scale, two-dimensional flow cell experiment showed that the discontinuous gas flow produced by spontaneous expansion, driven by the partitioning of 1,1,1-TCA from the surface of a DNAPL pool, resulted in detectable aqueous-phase concentrations of 1,1,1-TCA well above the pool surface. In comparison to a conventional model for DNAPL pool dissolution in the absence of a discontinuous gas phase, these concentrations were greater than expected, and were present at greater than expected elevations. Additionally, this study showed that the discontinuous gas flow produced transient behavior in the aqueous-phase concentrations, where the elevated concentrations occurred as short-term, pulse-like events. These results suggest that the spontaneous expansion and mobilization of discontinuous gas in DNAPL source zones could lead to the misdiagnosis of source zone architecture using aqueous concentration data, and that the transient nature of the elevated concentrations could further complicate the difficult task of source zone characterization.