南沙地块内破裂不整合与碰撞不整合的构造分析

廷贾断裂以东的南沙地块与南海北部陆缘共轭,因此其构造过程研究对认识整个南海的构造演化具有重要意义.地震资料和区域构造背景分析揭示,破裂不整合面(BU)和碰撞不整合面(CU)是控制南沙地块内盆地演化的骨架界面;为了揭示南沙地块内的主要构造过程,本文利用地震剖面分析和数值模拟的方法,侧重对两个重要界面开展构造分析.结果显示...     

Arsenic uptake by natural calcite: An XAS study

As-bearing travertine rocks from Tuscany (Italy), where previous studies suggested the existence of a CO₃²⁻ ⇔ AsO₃³⁻ substitution in the calcite lattice, were investigated with X-ray Absorption Spectroscopy (XAS) at the As K-edge (11,867 eV). In two of the studied samples, XANES indicates that As is in the 5+ oxidation state only, and EXAFS analysis reveals a local environment typical of arsenate species. For these samples, the lack of detectable second shell signals suggests a poorly ordered environment, possibly corresponding to an adsorption onto oxide and/or silicate phases. On the other hand, in the third sample XANES reveals a mixed As oxidation state (III and V). This sample also presents evident next nearest neighbor coordination shells, attributed to As-Ca and As-As contributions. The occurrence of next neighbor shells is evidence that part of As is incorporated in an ordered lattice. Furthermore, the local structure revealed by EXAFS is compatible with As incorporation in the calcite phase, as further supported by DFT simulations. The observation of next neighbors shells only in the As(III)-rich sample suggests the substitution of the arsenite group in place of the carbonate one (CO₃²⁻ ⇔ AsO₃³⁻). The conclusion of this work is that uptake of As by calcite is in general less favored than adsorption onto iron oxhydroxides, but could become environmentally important wherever the latter phenomenon is hindered.     

基于硫酸盐还原菌作用的油菜秆固定床处理模拟含Cr（Ⅵ）废水

探讨了固定床除Cr工艺以油菜秆为微生物生长的缓释碳源,含SRB的混合微生物和油菜秆对Cr（Ⅵ）的还原和固定的共同作用。动态实验分2阶段开展：初始2周的驯化阶段和梯度增加Cr（Ⅵ）浓度的除Cr实验阶段。除Cr实验中,间歇对固定床出水pH、氧化还原电位、SO42-及硫化物浓度、DOC、Cr（Ⅵ）浓度进行测试,实验结束后对固定床中固体产物进行SEM、EDS和XPS等分析。结果表明,油菜秆固定床处理模拟含Cr（Ⅵ）废水效果明显。当进水Cr（Ⅵ）浓度ρ[Cr（Ⅵ）]〈19.52 mg/L时,出水Cr（Ⅵ）和Cr（Ⅲ）浓度均低于排放标准（0.05 mg/L）;Cr（Ⅵ）被还原为Cr（Ⅲ）,Cr（Ⅲ）以氢氧化物的形式沉淀附着于油菜秆和其它固体物质之上。分析认为,油菜秆在固定床处理模拟含Cr（Ⅵ）废水中所起的作用主要包括3方面（作为微生物生长的缓释碳源;吸附Cr（Ⅵ）,降低其对微生物的毒性;作为Cr（Ⅲ）矿化产物的沉淀附着界面）;Cr（Ⅵ）主要通过SRB的直接作用及H2S的作用被还原为Cr（Ⅲ）;以油菜秆为碳源的固定床处理Cr（Ⅵ）的浓度上限介于15.05～19.52mg/L之间。     

Magnetic properties and cation ordering of nanopowders of the synthetic analogue of kuramite, Cu3SnS4

An extensive characterisation of the magnetic properties of synthetic powders of kuramite, with formal composition Cu₃SnS₄, was performed. Powders were investigated through superconducting quantum interference device (SQUID) magnetometry, electron paramagnetic resonance (EPR) spectroscopy, X-ray powder diffraction (XRPD), scanning and transmission electron microscopies (SEM and TEM) and microanalysis. SEM and TEM reveal the presence of nanodimensioned particles. XRPD clearly shows that Cu₃SnS₄ crystallised in a cubic sphalerite-type structural model, in spite of the stannite-type tetragonal structure described for the natural phase. This difference arises from a full random distribution of cations. Synthetic kuramite nanopowders exhibit a marked paramagnetism, originated by the presence of Cu(II), definitely assessed by EPR measurements. Moreover, the overall magnetic behaviour of the sample cannot be simply ascribed to diluted paramagnetism, and this suggests the presence of strong superexchange interactions among Cu(II) ions even at room temperature. The main consequences of these results are the definitive assessment of the chemical formula Cu(I)₂Cu(II)SnS₄ and of a random distribution of Cu(II), Cu(I) and Sn(IV) ions within the available tetrahedral sites.     

巴里坤盆地晚古生代火山岩年代学及构造演化

与周缘相邻的含油气盆地相比,前人对巴里坤盆地的研究少之又少,对其认识也不够完善;特别是由于缺乏化石及年代学资料,对研究基础的地层划分方案也一直存在争议.本文通过LA-ICP-MS单颗粒锆石U-Pb同位素测年方法对盆内Bal井岩心取样的凝灰岩进行了年代学测定,依据测定结果并结合地震反射同相轴特征对巴里坤盆地的地层重新进行...     

夏季不同天气背景和灌溉条件下绿洲地表辐射和能量平衡特征

利用2005年"绿洲系统能量和水分循环过程"野外观测实验(JTEX)资料,分析了夏季不同天气背景下的金塔绿洲小气候特征、辐射和能量平衡特征的日变化规律.结果表明:不同天气和土壤湿度背景下的辐射和能量平衡特征有较大差异.观测中发现有较大的能量不平衡差额,晴天时的能量亏损大于阴天的.     

塔里木盆地西北缘海相白垩系-古近系界线沉积物环境指标研究

发生于中生代-新生代之间的事件是地质历史上一次重大灾变和异常事件,因此白垩系-古近系之间的界线(K/T界线)就成为全球最重要的地质界线之一.通过对塔里木盆地西北缘乌恰地区库孜贡苏河剖面海相上白垩统-古新统地层的岩性和沉积环境变化以及地球化学特征研究,重点利用沉积物色度、有机碳含量、碳酸钙和碳、氧稳定同位素的明显异常变化...     

Estimation of soil erosion rates in a subtropical mountain watershed using 137Cs radionuclide

The formulation of watershed management strategies to protect water resources threatened by soil erosion and sedimentation requires a thorough understanding of sediment sources and factors that drive soil movement in the watershed. This paper describes a study of medium-term water-driven soil erosion rates in a mountainous watershed of the Shihmen Reservoir in Taiwan. A total of 60 sampling sites were selected along a hillslope. At each sampling site, the inventory ¹³⁷Cs activity was determined and then calculated with the diffusion and migration model to derive soil erosion rates. The rates are one to two orders of magnitude lower than estimates using the Universal Soil Loss Equation, a soil erosion model often used in Taiwan. Results of multiple regression analysis indicate that the spatial variability of soil erosion rates is associated with the relative position of a sampling site to the nearest ridge and soil bulk densities (r ² = 0.33, p < 0.01). Finally, the patterns of soil redistribution rates on the hillslope follow the ¹³⁷Cs hillslope model as soil erosion increases in the downslope direction. No deposition site is found at footslope because soil deposition is swept away by regular flooding along the stream channel. This study is an important first step in using ¹³⁷Cs as a tracer of soil redistribution in mountainous watersheds of Taiwan.     

吐格尔明背斜核部花岗岩的年代学、地球化学与构造环境及其对塔里木地块北缘古生代伸展聚敛旋回的揭示

塔里木盆地北缘库车坳陷东部地区吐格尔明背斜核部花岗岩发育,该套花岗岩侵位于以云母石英片岩为主的元古界基底岩系中,上覆的三叠系以角度不整合与其接触。本区花岗岩的研究对揭示库车地区的基底性质与构造演化历史具有重要意义。对吐格尔明花岗岩锆石的U-Pb年代学和岩石地球化学的研究表明, 吐格尔明背斜核部的花岗岩锆石为典型岩浆成因锆石,其锆石SHRIMP U-Pb定年结果分别为626.4±5.2Ma~643.3±4.0Ma,表明它们的形成时代为新元古代晚期埃迪卡拉纪早期。该套花岗岩的SiO₂ (67.95%~78.59%)和Al₂O₃ (11.81%~16.21%) 含量均很高,A/CNK在1.2~1.6,为硅和铝过饱和类型,属典型的过铝质花岗岩;稀土元素总量为106×10^-6~207×10^-6,稀土元素配分曲线呈右倾型,具有明显的负Eu异常;高场强元素(Ta、Nb、Ti等)具有明显的负异常,大离子亲石元素(Rb、Ba、Sr等) 具有明显的正异常。吐格尔明花岗岩是由地壳物质在底侵热源或构造动力作用下引起的局部熔融形成的,属典型的壳源成因类型,形成于挤压环境向伸展环境转化阶段,推测塔里木北缘在震旦纪已开始伸展,代表了古亚洲洋早期的伸展构造环境。实验测得花岗岩钾长石⁴⁰Ar/³⁹Ar年龄平均为291.4~255.8Ma,代表了花岗岩的隆升剥蚀年龄,反映出吐格尔明花岗岩在二叠纪受到挤压发生剥露的过程。因而从年代学框架上更好地约束了塔里木地块北缘在古生代由伸展裂解到聚敛隆升的构造旋回。     

Data Analysis of Chang’E-1 Gamma-Ray Spectrometer and Global Distribution of U, K, and Th Elemental Abundances

Gamma-ray spectrometer (GRS) is one of the main payloads on the Chang’E-1 (CE-1) lunar probe, mainly aimed to detect the elemental abundances and distributions on the lunar surface. At 03:58 on 28 November 2007, it performed the first observation of the lunar gamma rays. As of 24 October 2008, 2105?h of effective gamma rays spectra had been acquired by CE-1 GRS, which covers the whole surface of the moon. This paper mainly describes the data processing procedures and methods of deriving the elemental abundances by using the CE-1 GRS time series corrected spectra: first, to bin data into pixels for mapping; then, to perform a background deduction of the cumulative spectra and obtain a peak area of the elements; and finally, to use the elemental abundances inversion model to produce the elemental abundances. Based on these processing methods, the global abundance maps of U, K, and Th at a 5°×5° equal-area pixel are acquired by CE-1 GRS data. The paper gives a preliminary analysis of the uncertainties of the elemental abundances