Composition of soluble organic matter in coals: relation to rank and liptinite fluorescence

Study of a series of twenty-six German high volatile bituminous B to low volatile bituminous coals of Upper Carboniferous age by recently refined analytical methods (‘flow-blending’ extraction, medium pressure liquid chromatography, HPLC, glass capillary gas chromatography and spectral fluorescence microscopy) reveals that yield and composition of soluble organic matter are strongly controlled by rank. In particular, the following points of inflection are noted in rank trends around 0.9% vitrinite reflectance: a maximum in yields of total soluble organic matter, aromatic hydrocarbons and n-alkanes; the most pronounced change in aromatic hydrocarbon composition; a trend reversal for pristane/ phytane ratios; a gradient change in the odd/even-predominance of long chain n-alkanes; appearance of a bimodal n-alkane distribution; and a sharp drop in concentration of individual n-, and isoprenoid alkanes. This discontinuity in rank trends around 0.9% Rm is interpreted to reflect a major change in reaction types, i.e. a shift from predominantly hydrocarbon generating to predominantly fragmentation reactions. Rank trends of maceral fluorescence exhibit the following pronounced changes over a similar but broader rank range: Different types of the maceral sporinite show a relatively abrupt shift of the fluorescence colour from yellow towards red between 0.8–0.9% Rm while up to about 1.0% Rm a sharp increase is recorded in the proportion of fluorescent vitrinite. This coincidence at a near-equal rank stage suggests a common cause for changes in yield and composition of the soluble organic matter and the maceral fluorescence of these coals.     

Aircraft-Based Measurements Of Turbulence Structures In The Katabatic Flow Over Greenland

Turbulence structures in the katabatic flow in the stable boundary layer (SBL) over the ice sheet are studied for two case studies with high wind speeds during the aircraft-based experiment KABEG (Katabatic wind and boundary layer front experiment around Greenland) in the area of southern Greenland. The aircraft data allow the direct determination of turbulence structures in the katabatic flow. For the first time, this allows the study of the turbulence structure in the katabatic wind system over the whole boundary layer and over a horizontal scale of 80 km.The katabatic flow is associated with a low-level jet (LLJ), with maximum wind speeds up to 25 m s^-1. Turbulent kinetic energy (TKE) and the magnitude of the turbulent fluxes show a strong decrease below the LLJ. Sensible heat fluxes at the lowest level have values down to -25 W m^-2. Latent heat fluxes are small in general, but evaporation values of up to +13 W m^-2 are also measured. Turbulence spectra show a well-defined inertial subrange and a clear spectral gap around 250-m wavelength. While turbulence intensity decreases monotonously with height above the LLJ for the upper part of the slope, high spectral intensities are also present at upper levels close to the ice edge. Normalized fluxes and variances generally follow power-law profiles in the SBL.Terms of the TKE budget are computed from the aircraft data. The TKE destruction by the negative buoyancy is found to be very small, and the dissipation rate exceeds the dynamical production.     

Characteristics of intermittent turbulence in the upper stable boundary layer over Greenland

The experiment IGLOS (Investigation of the Greenland Boundary Layer Over Summit) was conducted in June and July 2002 in the central plateau of the Greenland inland ice. The German research aircraft Polar2, equipped with the turbulence measurement system Meteopod, was used to investigate turbulence and radiation flux profiles near research station “Summit Camp”. Aircraft measurements are combined with measurements of radiation fluxes and turbulent quantities made from a 50 m tower at Summit Camp operated by Eidgenössische Technische Hochschule (ETH) Zürich. During all six flight missions, well-developed stable boundary layers were found. Even in high-wind conditions, the surface inversion thickness did not exceed roughly 100 m. The turbulent height of the stable boundary layer (SBL) was found to be much smaller than the surface inversion thickness. Above the surface layer, significant turbulent fluxes occurred only intermittently in intervals on the order of a few kilometres. Turbulent event fraction in the upper SBL shows the same dependence on gradient Richardson number as reported for near-surface measurements. Clear-air longwave radiation divergence was always found to contribute significantly to the SBL heat budget. In low-wind cases, radiative cooling even turned out to be dominant.     

On the consideration of mesoscale transports in climate modelling

Summary The dynamical effect of land surface heterogeneity on heat fluxes in the atmospheric boundary layer (ABL) is investigated using numerical simulations with a non-hydrostatic model over a wide range of grid resolutions. It is commonly assumed that mesoscale or dynamical fluxes associated with mesoscale and convective circulations simulated by a high-resolution model (subgrid (SG) model) on the subgrid scale of a climate model (large-scale (LS) model) represent additional processes in the ABL, which are not considered by the turbulence scheme of the LS-model, and which can be parameterized using the SG-model. The present study investigates the usefulness of this methodology for small-scale and large-scale idealized heterogeneities using a SG-model resolving mesoscale or even microscale circulations to compute the mesoscale fluxes on the scale of the LS-model. It is shown that the dynamical transports as derived from the SG-model should not be used to correct the parameterized turbulent fluxes of the LS-model. The reason is that the subgrid circulations simulated by the SG-model interact with the fields of wind and scalars in the ABL, which results in reduced turbulent fluxes in the ABL. Thus the methodology of previous studies to use mesoscale/dynamical fluxes for the correction of flux profiles simulated by climate models seems to be questionable.