Arsenic in sediments, groundwater, and streamwater of a glauconitic Coastal Plain terrain, New Jersey, USA—Chemical “fingerprints” for geogenic and anthropogenic sources

Glauconite-bearing deposits are found worldwide, but As levels have been determined for relatively few. The As content of glauconites in sediments of the Inner Coastal Plain of New Jersey can exceed 100 mg/kg, and total As concentrations (up to 5.95 μg/L) found historically and recently in streamwaters exceed the State standard. In a major watershed of the Inner Coastal Plain, chemical “fingerprints” were developed for streambed sediments and groundwater to identify contributions of As to the watershed from geologic and anthropogenic sources. The fingerprint for streambed sediments, which included Be, Cr, Fe and V, indicated that As was predominantly of geologic origin. High concentrations of dissolved organic C, nutrients (and Cl⁻) in shallow groundwater indicated anthropogenic inputs that provided an environment where microbial activity released As from minerals to groundwater discharging to the stream. Particulates in streamwater during high flow constituted most of the As load; the chemical patterns for these particulates resembled the geologic fingerprint of the streambed sediments. The As/Cr ratio of these suspended particles likely indicates they derived not only from runoff, but from groundwater inputs, because As contributed by groundwater is sequestered on streambed sediments. Agricultural inputs of As were not clearly identified, although chemical characteristics of some sediments indicated vehicle-related inputs of metals. Sediment sampling during dry and wet years showed that, under differing hydrologic conditions, local anthropogenic fingerprints could be obscured but the geologic fingerprint, indicating glauconitic sediments as an As source, was robust.     

Model initialization in a tidally energetic regime: A dynamically adjusted objective analysis

A simple improvement to objective analysis of hydrographic data is proposed to eliminate spatial aliasing effects in tidally energetic regions. The proposed method consists of the evaluation of anomalies from observations with respect to circulation model fields. The procedure is run iteratively to achieve convergence. The method is applied in the Bay of Fundy and compared with traditional objective analysis procedures and dynamically adjusted climatological fields. The hydrographic skill (difference between observed and model temperature and salinity) of the dynamically adjusted objective analysis is significantly improved by reducing bias and correcting the vertical structure. Representation of the observed velocities is also improved. The resulting flow is consistent with the known circulation in the Bay.     

Otolith Microchemistry Reveals Substantial Use of Freshwater by Southern Flounder in the Northern Gulf of Mexico

Southern flounder Paralichthys lethostigma is a recreationally and commercially important species along the western Atlantic and northern Gulf of Mexico coasts that can exhibit complex early-life habitat-use patterns. Herein, we used an otolith microchemical approach to test the conventional wisdom that juvenile southern flounder spend most of their early life in low-salinity areas of estuaries, focusing on the largely unstudied population in the Mobile-Tensaw Delta, AL. Analysis of strontium/calcium concentrations in otolith cores of age 0 juveniles demonstrated that 68% of these individuals hatched in high-salinity waters before moving into freshwater habitats, with the remaining individuals being spawned in or near freshwater habitat. Further, otolith edge Sr/Ca concentrations revealed that even juveniles used freshwater habitats, particularly during freshwater/oligohaline conditions in our study system. Otolith edge Sr/Ca ratios for fish collected during high-salinity periods differed significantly among collection regions, suggesting seasonal differences in patterns of habitat use between individuals collected upstream (i.e., freshwater habitats) vs. downstream (i.e., euryhaline habitats). These data support the hypothesis that early-life stages of a substantial portion of a coastal southern flounder population use freshwater habitat.     

Charting thermal emission variability at Pele,Janus Patera and Kanehekili Fluctus with the Galileo NIMS Io Thermal Emission Database (NITED)

Using the NIMS Io Thermal Emission Database (NITED), a collection of over 1000 measurements of radiant flux from Io’s volcanoes (Davies, A.G. et al. [2012]. Geophys. Res. Lett. 39, L01201. doi:10.1029/2011GL049999), we have examined the variability of thermal emission from three of Io’s volcanoes: Pele, Janus Patera and Kanehekili Fluctus. At Pele, the 5-μm thermal emission as derived from 28 night time observations is remarkably steady at 37 ± 10 GW μm^?1, re-affirming previous analyses that suggested that Pele an active, rapidly overturning silicate lava lake. Janus Patera also exhibits relatively steady 5-μm thermal emission (≈20 ± 3 GW μm^?1) in the four observations where Janus is resolved from nearby Kanehekili Fluctus. Janus Patera might contain a Pele-like lava lake with an effusion rate (Q_F) of ≈40–70 m³ s^?1. It should be a prime target for a future mission to Io in order to obtain data to determine lava eruption temperature. Kanehekili Fluctus has a thermal emission spectrum that is indicative of the emplacement of lava flows with insulated crusts. Effusion rate at Kanehekili Fluctus dropped by an order of magnitude from ≈95 m³ s^?1 in mid-1997 to ≈4 m³ s^?1 in late 2001.     

Very High-Resolution Solar X-Ray Imaging Using Diffractive Optics

This paper describes the development of X-ray diffractive optics for imaging solar flares with better than 0.1 arcsec angular resolution. X-ray images with this resolution of the ???10?MK plasma in solar active regions and solar flares would allow the cross-sectional area of magnetic loops to be resolved and the coronal flare energy release region itself to be probed. The objective of this work is to obtain X-ray images in the iron-line complex at 6.7?keV observed during solar flares with an angular resolution as fine as 0.1 arcsec ?C over an order of magnitude finer than is now possible. This line emission is from highly ionized iron atoms, primarily Fe xxv, in the hottest flare plasma at temperatures in excess of ???10 MK. It provides information on the flare morphology, the iron abundance, and the distribution of the hot plasma. Studying how this plasma is heated to such high temperatures in such short times during solar flares is of critical importance in understanding these powerful transient events, one of the major objectives of solar physics. We describe the design, fabrication, and testing of phase zone plate X-ray lenses with focal lengths of ???100 m at these energies that would be capable of achieving these objectives. We show how such lenses could be included on a two-spacecraft formation-flying mission with the lenses on the spacecraft closest to the Sun and an X-ray imaging array on the second spacecraft in the focal plane ???100 m away. High-resolution X-ray images could be obtained when the two spacecraft are aligned with the region of interest on the Sun. Requirements and constraints for the control of the two spacecraft are discussed together with the overall feasibility of such a formation-flying mission.     

Iron deficiency in pyrrhotite of suevites from the Chesapeake Bay impact crater,USA—A consequence of shock metamorphism?

Abstract– Pyrrhotite from suevite of the 35 Ma Chesapeake Bay impact structure (CBIS) shows a shock metamorphism and we report on several mineralogical and magnetic features. Pyrrhotite shows strong brittle deformation with a high density of stacking faults, twinning parallel to the hexagonal (001) planes and average fault distances in the order of 10 nm. Although the determination of a superstructure was not possible due to the lattice defects, the reflections of the NiAs subcell, which is typical of all pyrrhotite modifications, were clearly detected. This phase is ferrimagnetic with a Curie temperature (T_C) between 350 and 365 °C, and suevite with this phase does not show the 34 K transition. The most peculiar feature is the low metal/sulfur ratio of 0.81, which indicates a distinctly higher vacancy concentration than for 4C pyrrhotite and a composition close to smythite (Fe₉S₁₁). This phase carries a stable natural remanent magnetization and is relatively hard magnetic. Steep inclinations of the natural remanent magnetization vector, however, suggest that this phase has been remagnetized by the drilling process. A possible explanation is the magnetic domain size of faultless areas of about 10 nm in diameter, which is at the lower limit of the single domain size near the threshold, below which superparamagnetic behavior occurs. The low thermal stability of this phase excludes postshock heating above 300 °C for the suevite of the CBIS. Our results imply that the iron‐deficient pyrrhotite is produced by shock metamorphism, although an iron loss due to shock has never been reported before for pyrrhotite.     

Assessing hyporheic exchange and associated travel times by hydraulic, chemical, and isotopic monitoring at the Steinlach Test Site, Germany

First results of a multi-disciplinary hyporheic monitoring study are presented from the newly established Steinlach Test Site in Southern Germany. The site is located in a bend of the River Steinlach (mean discharge of 1.8 m³/s) underlain by an alluvial sandy gravel aquifer connected to the stream. The overall objective is a better understanding of hyporheic exchange processes at the site and their interrelations with microbial community dynamics and biochemical reactions at the stream–groundwater interface. The present paper focuses on the distribution of lateral hyporheic exchange fluxes and their associated travel times at the Steinlach Test Site. Water level dynamics in various piezometers correspond to the different domains of hydraulic conductivity in the shallow aquifer and confirms hyporheic exchange of infiltrated stream water across the test site. Hydrochemical compositions as well as increased damping of continuous time series of electrical conductivity (EC) and temperature at the respective piezometers confirmed the inferred distribution of hyporheic flowpaths. Mean travel times ranging from 0.5 days close to the stream to more than 8 days in the upstream part of the test site could be estimated from deconvolution of EC and δ¹⁸O–H₂O data. The travel times agree well with the presumed flowpaths. Mg/Ca ratios as well as model fits to the EC and δ¹⁸O data indicate the presence of an additional water component in the western part of the test site which most likely consists of hillslope water or groundwater. Based on the mean travel times, the total lateral hyporheic exchange flux at the site was estimated to be of the order of 1–2 L/s.     

Spatial Mismatch and Determinants of Foreign and Domestic Information and Communication Technology Firms in Urban China

Studies on foreign direct investment locations in China have been conducted mainly at interregional and interprovincial scales, and little attention has been paid to the intraurban scale where location decisions of foreign firms can differ from domestic firms. This article explores the intraurban locations of information and communication technology (ICT) firms in Suzhou, a city experiencing rapid globalization. We have found that the distribution of ICT firms in Suzhou exhibits distinctive spatial patterns characterized by a geographically based, institutionally created spatial mismatch between foreign and domestic firms. Foreign firms are concentrated in national-level development zones—China–Singapore Suzhou Industrial Park in the east and Suzhou New and Hi-Tech District in the west—whereas domestic firms tend to agglomerate in the inner city and the provincial-level development zone in the north. Poisson and negative binomial analyses further reveal that the locations of foreign firms are strongly correlated to development zones, and the agglomeration economies derived from the stock of foreign investment rather than domestic firms. The case of Suzhou highlights the challenges that Chinese cities face in industrial upgrading and technological development through embedding transnational corporations.     

A double continuous approach to visualization and analysis of categorical maps

A method to visualize multiple membership maps, called ‘Colour mixture’ (CM) is described and compared with alternative techniques: defuzzification and Pixel mixture. Six landform parameters were used to derive the landform classes using supervised fuzzy k-means classification. The continuous categorical map is derived by GIS calculations with colours, where colour values are considered to represent the taxonomic space spanned by the attribute variables. Coordinates of the nine class centres (landform facets) were first transformed from multivariate to two-dimensional attribute space using factor analysis, and then projected on the Hue Saturation Intensity (HSI) colourwheel. The taxonomic value was coded with the Hue and confusion with Saturation. To improve visual impression, saturation was replaced with whiteness. Classes that were closer in attribute space were merged into similar generic colours. The CM technique limits the derived mixed-colour map to seven generic hues independently of the total number of classes, which provides a basis for automated generalization. The confusion index derived from the mixed-colour map was used to derive primary boundaries and to locate areas of higher taxonomic confusion.