An investigation of the SO2 content of the venusian mesosphere using SPICAV-UV in nadir mode

Using the SPICAV-UV spectrometer aboard Venus Express in nadir mode, we were able to derive spectral radiance factors in the middle atmosphere of Venus in the 170-320 nm range at a spectral resolution of R ? 200 during 2006 and 2007 in the northern hemisphere. By comparison with a radiative transfer model of the upper atmosphere of Venus, we could derive column abundance above the visible cloud top for SO₂ using its spectral absorption bands near 280 and 220 nm. SO₂ column densities show large temporal and spatial variations on a horizontal scale of a few hundred kilometers. Typical SO₂ column densities at low latitudes (up to 50°N) were found between 5 and 50 μm-atm, whereas in the northern polar region SO₂ content was usually below 5 μm-atm. The observed latitudinal variations follow closely the cloud top altitude derived by SPICAV-IR and are thought to be of dynamical origin. Also, a sudden increase of SO₂ column density in the whole northern hemisphere has been observed in early 2007, possibly related to a convective episode advecting some deep SO₂ into the upper atmosphere.     

Physical model experiments for sediment supply to the old Rhine through induced bank erosion

A mobile-bed, undistorted physical model （1：40） has been used to investigate different sediment supply strategies to the Old Rhine through bank protection removal and modifications of groyne dimensions and configuration, which cause bank erosion. This trained channel was previously the main bed of the upper Rhine downstream of Basel （Switzerland）, but it has an artificially low flow regime since the construction of the Grand Canal d＇Alsace, a navigation canal, and a flow control dam at Kembs （France）. Training works and subsequent channel incision have also greatly reduced sediment transport rates and created a heavily armoured bed. The modelled pilot site has a groyne field on the left bank. Results show that the currently existing groynes at the site are not effective in creating high bank-side velocities conducive to bank erosion, even for flow rates significantly higher than the mean annual flow rate. The river bank has also proved to be more resistant than previously thought, allowing long stretches of bank protection to be safely removed. The physical model testing process has produced a new configuration for the groyne field, where two higher, larger island groynes are placed further apart than the three existing attached groynes. This innovative approach has proved effective, causing bank erosion for flow rates below the mean annual flow rate, with consistent erosion being observed. It has also been found that such a configuration does not pose a hazard for the Grand Canal d＇Alsace, which is situated next to the Old Rhine, through excessive bank erosion during high flow events.     

CHILDREN'S PERCEPTION OF A DOWNTOWN SHOPPING CENTER

This paper offers an exploratory investigation of the effects of a child's age on three behavioral constructs (awareness space, activity space, and attitude) concerning a downtown shopping center in Bristol, England. The data are elicited from three samples of Bristol school children defined according to age and are analyzed using statistical inferential procedures. The results disclose that awareness space and activity space consistently increase with age. In addition, attitudinal responses to specific features of the shopping center exhibit a gradual change over a long-term period.     

Defining the Potential of Nanoscale Re‐Os Isotope Systematics Using Atom Probe Microscopy

Atom probe microscopy (APM) is a relatively new in situ tool for measuring isotope fractions from nanoscale volumes (< 0.01 μm³). We calculate the theoretical detectable difference of an isotope ratio measurement result from APM using counting statistics of a hypothetical data set to be ± 4δ or 0.4% (2s). However, challenges associated with APM measurements (e.g., peak ranging, hydride formation and isobaric interferences), result in larger uncertainties if not properly accounted for. We evaluate these factors for Re‐Os isotope ratio measurements by comparing APM and negative thermal ionisation mass spectrometry (N‐TIMS) measurement results of pure Os, pure Re, and two synthetic Re‐Os‐bearing alloys from Schwander et al. (2015, Meteoritics and Planetary Science, 50, 893) [the original metal alloy (HSE) and alloys produced by heating HSE within silicate liquid (SYN)]. From this, we propose a current best practice for APM Re‐Os isotope ratio measurements. Using this refined approach, mean APM and N‐TIMS ¹⁸⁷Os/¹⁸⁹Os measurement results agree within 0.05% and 2s (pure Os), 0.6–2% and 2s (SYN) and 5–10% (HSE). The good agreement of N‐TIMS and APM ¹⁸⁷Os/¹⁸⁹Os measurements confirms that APM can extract robust isotope ratios. Therefore, this approach permits nanoscale isotope measurements of Os‐bearing alloys using the Re‐Os geochronometer that could not be measured by conventional measurement principles.     

Modelling fractionation of stable isotopes in stalagmites

High resolution δ¹³C and δ¹⁸O profiles recorded in precisely dated speleothems are widely used proxies for the climate of the past. Both δ¹³C and δ¹⁸O depend on several climate related effects including meteorological processes, processes occurring in the soil zone above the cave and isotope fractionation processes occurring in the solution layer on the stalagmite surface. Here we model the latter using a stalagmite isotope and growth model and determine the relationship between the stable isotope values in speleothem calcite and cave parameters, such as temperature, drip interval, water p_CO2 and a mixing coefficient describing mixing processes between the solution layer and the impinging drop.The evolution of δ¹³C values is modelled as a Rayleigh distillation process and shows a pronounced dependence on the residence time of the solution on the stalagmite surface and the drip interval, respectively. The evolution of δ¹⁸O values, in contrast, is also influenced by buffering reactions between the bicarbonate in the solution and the drip water driving the δ¹⁸O value of the bicarbonate towards the value expected for equilibrium isotope fractionation between drip water and calcite. This attenuates the dependence of the δ¹⁸O values on drip interval. The temperature dependence of δ¹⁸O, however, is more pronounced than for δ¹³C and in a similar range as expected for fractionation under equilibrium conditions.We also investigate the isotopic enrichment of the δ¹³C and δ¹⁸O values along individual growth layers and, thus, the slopes expected for Hendy tests. The results show that a positive Hendy test is only possible if isotope fractionation occurred under disequilibrium conditions. However, a negative Hendy test does not exclude that isotope fractionation occurred under disequilibrium conditions. A more reliable indicator for disequilibrium fractionation is the enrichment of the δ¹³C values along an individual growth layer.     

Microseismicity and faulting geometry in the Gulf of Corinth (Greece)

During the summer of 1993, a network of seismological stations was installed over a period of 7 weeks around the eastern Gulf of Corinth where a sequence of strong earthquakes occurred during 1981. Seismicity lies between the Alepohori fault dipping north and the Kaparelli fault dipping south and is related to both of these antithetic faults. Focal mechanisms show normal faulting with the active fault plane dipping at about 45° for both faults. The aftershocks of the 1981 earthquake sequence recorded by King et al . (1985 ) were processed again and show similar results. In contrast, the observations collected near the western end of the Gulf of Corinth during an experiment conducted in 1991 ( Rigo et al . 1996 ), and during the aftershock studies of the 1992 Galaxidi and the 1995 Aigion earthquakes ( Hatzfeld et al . 1996 ; Bernard et al . 1997 ) show seismicity dipping at a very low angle (about 15°) northwards and normal faulting mechanisms with the active fault plane dipping northwards at about 30°. We suggest that the 8–12 km deep seismicity in the west is probably related to the seismic–aseismic transition and not to a possible almost horizontal active fault dipping north as previously proposed. The difference in the seismicity and focal mechanisms between east and west of the Gulf could be related to the difference in the recent extension rate between the western Gulf of Corinth and the eastern Gulf of Corinth, which rotated the faults dipping originally at 45° (as in the east of the Gulf) to 30° (as in the west of the Gulf).     

The Congo Basin forests in a changing climate: Policy discourses on adaptation and mitigation (REDD+)

This paper discusses the discourses on climate change adaptation and mitigation that are currently at the forefront in the Congo Basin. On mitigation, the forests have enormous opportunities to contribute to the reducing emissions from deforestation and forest degradation (REDD+) mechanism. But the forest itself and its multiple dependent societies and sectors need to adapt to potential climate risks. Hence, actors are debating the design of climate change policy in the forest sector. Theoretically, we combine the agency-focus of frame analysis and discourse theory to analyze how different agents hold frames on climate change adaptation and mitigation policies in the region. This paper draws upon interviews with 103 different actors from government, international organizations, non-governmental organizations, research institutions and private sector in three countries: Cameroon, Central African Republic (CAR) and Democratic Republic of Congo (DRC). Three discourses were found on policy response to climate change in the forest sector: mitigation policy only, separated policy on adaptation and mitigation, and an integrated policy on adaptation and mitigation. The various frames articulated around each discourse by the coalitions include elements of: costs and benefits, scale of operation, effectiveness, financial resources and implementation mechanisms. Overall, the mitigation discourse, through its mix of actors, resources and interests seems to be stronger than the adaptation discourse. The paper finally outlines a number of implications of the discourses for policy design.     

R-mode factor analysis on enstatite chondrite analyses

R-mode factor analysis on 11 specimens of 9 enstatite chondrites, analysed for Ga, Se, Te, Zn, Cd, Bi, Tl, In, Sb, As, Co, showed three factors (rotated) to account for 92 per cent of the elemental variations (variance).Factor 1 dominates the first 8 elements listed, all volatile and mostly chalcophile: factors 2 and 3 express Sb and As variations, respectively, probably dependent on siderophile and less volatile behaviour; factors 1 and 2 contribute to Co.Factor-scores for individual meteorites indicate compositional differences (for these elements) between the E4 as against E5 and E6 stones (which are indistinguishable).Factor analysis of a second suite of 10 specimens analysed for Zn, Cd, Bi, Tl, In, Ag, Rb, Cs showed one factor to account for 93 per cent of the elemental variance. This expresses the association of Ag, Rb, Cs with the volatile-chalcophile factor.     

Estimating masses of selected stars in the Pulkovo program by means of astrometry methods

Stars in the Pulkovo Observatory program are observed with a 65-cm refractor during many years to study their positions and movements. We present examples of two visual binary stars, for which orbits and masses of components were determined, and two astrometric stars, for which masses of their unseen companions were estimated. The first two stars are ADS 14636(61 Cygni) and ADS 7251,and the others are Gliese 623 and ADS 8035(Alpha UMa). Direct astrometric methods are used for estimation of mass-ratio and masses.