731.
Investigation of biogeochemistry and amino acids on a 30-m-long core from Mansar Lake has thrown light on palaeoclimate variability
during the Holocene period. The C/N ratio between 6 and 10 with some deviations and δ13C mostly between −20 and −22‰ in the
shallow core, as well as a C/N ratio greater than 13 reaching from 19 to 20 and correspondingly lower δ13C of –28‰ in the
deeper core suggest an aquatic source of carbon in the former and a cellulose-rich land plant source in the latter. This is
supported by the abrupt increase in organic carbon content in the deeper core compared to the shallow core, which indicates
a hot and wet climatic regime during the early Holocene and dry and cold during the late Holocene period. The amino acid data
AA-C/C% and AA-N/N% are higher in shallow sediments compared to deeper sediments, indicating an aquatic plant source in the
shallow core and greater supply of land plant sources in the deeper core. The lower percentage of the non-protein amino acids
β-alanine (ALA) and γ-amino-butyric acid in the shallow core compared to the deeper core indicates different sources of organic
matter in the lake basin. The higher amino acid ratio Asp/β-Ala (16.99 av.) and Glu/γ-Aba (18.18 av.) in the shallow core
and lower ratios (10.32 and 12.41 av.) in the deeper core, and Asp/Glu (1.52 av.) and β-Ala/γ-Aba (1.61 av.) ratios in the
former, which are potential indicators of the nature of the organic matter, are higher in the shallow core relative to the
deeper core (1.33 and 1.23 av.), indicating relative biodegradation of organic matter in deeper sediments. It has been observed
that the organic matter associated with the dry season is relatively less biodegraded, as evidenced from their higher ratios,
and is more biodegraded in the wet season as their ratios are lower in the river sediments. In the absence of a bacterial
contribution of organic matter from the soil source in this lake, since Mansar Lake is a non-drainage type, it is envisaged
that the climatic variation may be responsible for biodegradation in the deeper core sediments. Therefore, the C/N ratio and
δ13C values supported by amino acid data, the latter being significant in revealing primary productivity and a terrestrial
source of organic matter, suggest a hot and wet climatic regime during the early Holocene (ca. 7580
bp) and a dry and cold in the late Holocene period (ca. 4050
bp).
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