Dissolution and depletion of ferromagnesian minerals from Holocene tephra layers in an acid bog,New Zealand,and implications for tephra correlation

This study examines the depletion of ferromagnesian silicate minerals from a sequence of thin, distal, mainly rhyolitic tephra layers of Holocene age preserved in an acid peat bog (Kopouatai), North Island, New Zealand. The rate of such depletion has been fast, as indicated by the complete loss of biotite from one tephra layer (Kaharoa Tephra), in which it is normally dominant, in only ca. 770 yr. Chemical dissolution is advocated as the likely cause for the depletion, with amphiboles and other mineral grains commonly showing etch pits, microcaves, and other characteristic surface solution features. Theoretical thermodynamic and kinetic models show a marked increase in the rate of dissolution of all ferromagnesian minerals under conditions of low pH (< 4), but that where silica concentrations in solution are high the relative proportions of minerals remaining are unaffected. However, where concentrations of dissolved silica are low, as in most bog environments, the relative proportions of ferromagnesian minerals are affected as well as absolute amounts being decreased. Amphiboles are depleted relative to pyroxenes, consistent with kinetic studies. The results show that the identification and correlation of tephras on the basis of relative abundances of ferromagnesian minerals alone may be unreliable, and emphasise the need to use multiple criteria in such studies.     

Kinematics of Gas and Stars in 20 Disc Galaxies

In this paper we present the kinematics of the gas and/or the stars of a sample of 20 disc galaxies. We investigate whether there is any relation between the kinematics of the gas and stars and the classical morphological type of the galaxies in the sample. We deduce that, in most of the late-type spirals we have studied, the stars and the ionized gas are moving with virtually circular velocity, except when the spectroscopic slit crosses a bar region. On the other hand, we found in the central parts of early-type disc galaxies a wider variety of different behaviour of stars and gas. We find many possible factors that complicate the classification of the kinematical properties of the galaxies by their morphological type: the presence of counter-rotations (star vs. stars or star vs. gas), misalignment between the different kinematic components present in the galaxy, the presence of a bar structure and its orientation with respect to the line of nodes of the galaxy, and interactions and mergers or external accretion processes are some of the problems we find in the study of the kinematics of a galaxy.     

Abundances of [WC] central stars and their planetary nebulaee

We review elemental abundances derived for planetary nebula (PN) WCcentral stars and for their nebulae. Uncertainties in the abundances of[WC] stars are still too large to enable an abundance sequenceto be constructed. In particular it is not clear why the hotter [WCE]stars have C and O abundances which are systematically lower than those oftheir supposed precursors, the [WCL] stars. This abundance differencecould be real or it may be due to unaccounted-for systematic effects inthe analyses. Hydrogen might not be present in [WC] star winds asoriginallysuggested, since broad pedestals observed at the base of nebular lines canplausibly be attributed to high velocity nebular components. It isrecommended that stellar abundance analyses should be carried out withnon-LTE model codes, although recombination line analyses can provideuseful insights. In particular, C II dielectronic recombinationlines provide a unique means to determine electron temperatures in cool[WC] star winds. We then compare the abundances found for PNe which have [WC] central starswith those that do not. Numerous abundance analyses of PNe have beenpublished, but comparisons based on non-uniform samples and methods arelikely to lack reliability. Nebular C/H ratios, which might be expected todistinguish between PNe around H-poor and H-rich stars, are rather similarfor the two groups, with only a small tendency towards larger values fornebulae around H-deficient stars. Nebular abundances should be obtainedwith photoionization models using the best-fitting non-LTE modelatmosphere for the central star as the input. Heavy-metal line blanketingstill needs to be taken into consideration when modeling the central star,as its omission can significantly affect the ionizing fluxes as well asthe abundance determinations. We discuss the discrepancies between nebularabundances derived from collisionally excited lines and thosederived from optical recombination lines, a phenomenon that may havelinks with the presence of H-deficient central stars.     

Some New Observed Properties of Elliptical Galaxies

We suggest that elliptical galaxies, as stellar systems in a stage of quasi-equilibrium, may have a specific entropy. We use the Sérsic law to describe the light profile. The specific entropy (the Boltzmann–Gibbs definition) is then calculated assuming that the galaxy behaves as a spherical, isotropic, one-component system. We predict a relation between the three parameters of the Sérsic law linked to the specific entropy, defining a surface in the parameter space, an ‘entropic plane’. We have analysed a sample of simulated merging elliptical galaxies (virtual) and a sample of galaxies belonging to the Coma Cluster (real). Both virtual and realgalaxies are: 1) located in their own ‘entropic plane‘ and 2) in this plane, they are located on a straight line, indicating constant entropy: another physical property A careful examination of the value of the specific entropy indicates a very small increase in the specific entropy with the generation after merging (virtual sample). Although one cannot distinguish between various generations for real galaxies, the distribution of specific entropy in this sample is very similar to that in the virtual sample. This revised version was published online in July 2006 with corrections to the Cover Date.     

On the survivability of an enantiomeric excess of amino acids in comet nuclei during the decay of26Al and other radionuclides

We present a computer model calculation for the racemization of a possible excess of amino acids in the icy fraction of comet nuclei bring about by ionizing radiation released during the decay of²⁶Al,⁴⁰K,²³⁵U,²³⁸U and²³²Th. The model takes into account a total of 110 chemical reactions, of which 91 are needed to explain the radiation chemical processing of the major constituents of comet nuclei (Navarro-Gonzálezet al., 1992) and 19 are necessary to simulate the radiolysis of glycine/alanine mixtures in aqueous solutions (Navarro-Gonzálezet al., 1994 and 1996). It is predicted that an enantiomeric excess of alanine would not be destroyed by radioracemization during the decay of embedded radionuclides. Nevertheless, this enantiomeric excess could be attenuated by the formation of racemic amino acids in the interior of comet nuclei as a result of the radiation-induced polymerization of HCN.     

Optical and X-Ray Observations of the Symbiotic System Ag Draconis During Quiescence and Outburst

We review the main characteristics of the symbiotic system AG Draconis, with special emphasis on its optical and X-ray variations. We also discuss the X-ray to visual energy distribution during quiescence and outburst and describe our spectroscopic and X-ray observations during the 2003 outburst. Based on X-ray observations collected with the XMM–Newton Observatory, on INES data from the IUE satellite, and on optical spectra collected with the Asiago–Cima Ekar, Bologna–Loiano and La Palma–Galileo Italian telescopes.     

Semi-Classical Cosmological Models with Scalar, Dirac and Electromagnetic Fields

Exact solutions of the semi-classical Einstein equations for conformally invariant free quantum fields in an homogeneous and isotropic space-time, with cosmological constant and containing a classical scalar field, dust matter, an unquantised Dirac field and electromagnetic radiation are found. The initial behaviour of the semiclassical models is investigated. Some of the solutions found avoid the singularity and do not have particle horizons. This revised version was published online in July 2006 with corrections to the Cover Date.     

Fracture energy release and size effect in borehole breakout

The paper presents a simple approximate analytical solution of the remote stresses that cause the collapse of a borehole or other circular cylindrical cavity in an infinite elastic space. Regions of parallel equidistant splitting cracks are assumed to form on the sides of the cavity. Their boundary is assumed to be an ellipse of a growing horizontal axis, the other axis remaining equal to the borehole diameter. The slabs of rock between the splitting cracks are assumed to buckle as slender columns, and their post-critical stress is considered as the residual stress in the cracked rock. The buckling of these slab columns is assumed to be resisted not only by their elastic bending stiffness but also shear stresses produced on rough crack faces by relative shear displacements. The energy release from the infinite medium caused by the growth of the elliptical cracking region is evaluated according to Eschelby's theorem. This release is set equal to the energy dissipated by the formation of all the splitting cracks, which is calculated under the assumption of constant fracture energy. This yields the collapse stress as a function of the elastic moduli, fracture energy, ratio of the remote principal stresses, crack shear resistance characteristic and borehole diameter. The collapse stress as a function of crack spacing is found to have a minimum, and the correct crack spacing is determined from this minimum. For small enough diameters, the crack spacing increases as the (4/5)-power of the borehole diameter, while for large enough diameters a constant spacing is approached. In contrast to plastic solutions, the breakout stress exhibits a size effect, such that for small enough diameters the breakout stress decreases as the (? 2/5)-power of the borehole diameter, while for large enough diameters a constant limiting value is approached. Finally, some numerical estimates are given and the validity of various simplifying assumptions made is discussed.